| R64 | 61 |  Florent SerraClay | 74 |  Evgeny KorolevClay | 7-6(7) 6-3 | 3 | 99 | 6 | 0 | 58.6% | 65.5% | 56.1% | 10/11 |
| R64 | 82 | Andrey GolubevClay | 155 |  Mischa ZverevClay | 7-5 6-1 | 3 | 73 | 2 | 0 | 57.7% | 76.7% | 72.7% | 1/2 |
| R64 | 121 | Julian ReisterClay | 68 | Daniel BrandsClay | 6-2 7-6(10) | 3 | 88 | 5 | 2 | 72.7% | 81.3% | 66.7% | 1/2 |
| R64 | 59 |  Denis IstominClay | 187 |  Lukas RosolClay | 3-6 6-4 6-3 | 3 | 125 | 8 | 3 | 73.3% | 72.7% | 58.3% | 9/10 |
| R64 | 195 |  Maximo GonzalezClay | 65 |  Olivier RochusClay | 6-4 5-7 6-2 | 3 | 145 | 3 | 2 | 72.7% | 75.0% | 37.5% | 8/11 |
| R64 | 54 | Florian MayerClay | 62 |  Pablo CuevasClay | 6-4 6-1 | 3 | 70 | 2 | 0 | 71.1% | 78.1% | 46.2% | 1/2 |
| R64 | 60 |  Jarkko NieminenClay | 160 | Christophe RochusClay | 6-3 7-6(6) | 3 | 98 | 12 | 3 | 76.7% | 65.2% | 55.0% | 6/8 |
| R64 | 84 | Jan HajekClay | 80 | Andreas BeckClay | 6-3 4-6 7-5 | 3 | 133 | 6 | 0 | 70.2% | 60.6% | 57.1% | 4/8 |
| R64 | 79 |  Pere RibaClay | 52 | Paul-Henri MathieuClay | 1-6 6-0 6-3 | 3 | 114 | 3 | 3 | 67.6% | 66.0% | 45.8% | 2/5 |
| R64 | 72 |  Potito StaraceClay | 98 | Bjorn PhauClay | 7-5 6-0 | 3 | 78 | 1 | 1 | 77.8% | 76.2% | 50.0% | 1/2 |
| R64 | 73 | Jeremy ChardyClay | 63 |  Marco ChiudinelliClay | 6-4 6-1 | 3 | 64 | 7 | 3 | 62.5% | 88.0% | 66.7% | 0/0 |
| R64 | 50 | Eduardo SchwankClay | 100 | Tobias KamkeClay | 6-3 6-4 | 3 | 86 | 2 | 0 | 58.5% | 60.5% | 63.0% | 5/7 |
| R64 | 111 | Simone BolelliClay | 69 | Simon GreulClay | 7-6(4) 7-6(4) | 3 | 119 | 9 | 1 | 72.5% | 79.3% | 50.0% | 3/4 |
| R64 | 53 | Juan Ignacio ChelaClay | 48 |  Sergiy StakhovskyClay | 6-2 6-3 | 3 | 62 | 1 | 0 | 84.6% | 84.8% | 66.7% | 0/0 |
| R64 | 70 | Andreas SeppiClay | 78 | Stephane RobertClay | 6-4 6-3 | 3 | 65 | 7 | 2 | 69.4% | 79.4% | 46.7% | 2/3 |
| R64 | 97 | Fabio FogniniClay | 91 | Ruben Ramirez HidalgoClay | 7-6(4) 6-4 | 3 | 113 | 4 | 6 | 61.4% | 68.6% | 46.9% | 5/8 |
| R32 | 6 |  Nikolay DavydenkoClay | 61 | Florent SerraClay | 6-3 6-1 | 3 | 57 | 1 | 3 | 73.2% | 80.0% | 72.7% | 0/0 |
| R32 | 82 | Andrey GolubevClay | 86 | Marcel GranollersClay | 6-4 7-5 | 3 | 96 | 4 | 1 | 62.9% | 72.7% | 57.7% | 9/10 |
| R32 | 121 | Julian ReisterClay | 43 |  Victor HanescuClay | 7-6(4) 6-4 | 3 | 99 | 4 | 1 | 70.3% | 75.6% | 52.6% | 2/4 |
| R32 | 59 | Denis IstominClay | 18 | Nicolas AlmagroClay | 7-6(5) 7-6(7) | 3 | 119 | 9 | 2 | 65.3% | 82.3% | 45.5% | 4/5 |
| R32 | 195 | Maximo GonzalezClay | 140 | Albert Ramos-VinolasClay | 7-6(5) 6-7(3) 6-2 | 3 | 188 | 2 | 2 | 77.6% | 66.7% | 30.8% | 6/10 |
| R32 | 54 | Florian MayerClay | 39 | Alexandr DolgopolovClay | 4-6 7-6(2) 6-3 | 3 | 110 | 5 | 0 | 74.7% | 71.0% | 57.1% | 2/5 |
| R32 | 60 | Jarkko NieminenClay | 33 | Gilles SimonClay | 6-4 3-6 7-5 | 3 | 126 | 5 | 1 | 71.6% | 63.2% | 63.0% | 8/11 |
| R32 | 21 | Juan Carlos FerreroClay | 84 | Jan HajekClay | 7-6(4) 6-1 | 3 | 75 | 4 | 0 | 69.5% | 78.0% | 61.1% | 1/2 |
| R32 | 79 | Pere RibaClay | 24 | Albert MontanesClay | 6-4 5-7 7-6(4) | 3 | 152 | 7 | 2 | 56.0% | 64.3% | 61.4% | 5/9 |
| R32 | 72 | Potito StaraceClay | 36 | Tommy RobredoClay | 7-6(10) 5-7 6-1 | 3 | 132 | 3 | 2 | 82.6% | 73.7% | 43.8% | 1/4 |
| R32 | 73 | Jeremy ChardyClay | 37 | Philipp PetzschnerClay | 6-3 6-3 | 3 | 70 | 6 | 0 | 64.6% | 80.6% | 64.7% | 0/0 |
| R32 | 15 |  Jurgen MelzerClay | 50 | Eduardo SchwankClay | 6-4 6-1 | 3 | 56 | 7 | 2 | 45.0% | 94.4% | 59.1% | 0/1 |
| R32 | 22 |  Thomaz BellucciClay | 111 | Simone BolelliClay | 6-1 3-6 6-3 | 3 | 117 | 5 | 1 | 56.6% | 88.4% | 48.5% | 3/5 |
| R32 | 35 | Philipp KohlschreiberClay | 53 | Juan Ignacio ChelaClay | 2-6 6-2 6-4 | 3 | 116 | 5 | 1 | 69.0% | 67.2% | 53.8% | 8/10 |
| R32 | 70 | Andreas SeppiClay | 44 | Michael BerrerClay | 6-2 7-6(4) | 3 | 94 | 2 | 1 | 65.5% | 86.1% | 78.9% | 0/0 |
| R32 | 97 | Fabio FogniniClay | 144 | Marc GicquelClay | 6-4 6-4 | 3 | 89 | 2 | 1 | 64.7% | 59.1% | 50.0% | 6/9 |
| R16 | 82 | Andrey GolubevClay | 6 | Nikolay DavydenkoClay | 6-4 6-4 | 3 | 89 | 3 | 1 | 70.6% | 72.9% | 50.0% | 3/4 |
| R16 | 59 | Denis IstominClay | 121 | Julian ReisterClay | 3-6 6-3 7-6(3) | 3 | 129 | 11 | 0 | 75.0% | 73.6% | 50.0% | 8/10 |
| R16 | 54 | Florian MayerClay | 195 | Maximo GonzalezClay | 7-6(1) 6-0 | 3 | 88 | 2 | 0 | 65.5% | 73.7% | 55.0% | 4/5 |
| R16 | 21 | Juan Carlos FerreroClay | 60 | Jarkko NieminenClay | 6-2 3-6 6-4 | 3 | 106 | 3 | 0 | 67.6% | 77.1% | 60.9% | 0/1 |
| R16 | 72 | Potito StaraceClay | 79 | Pere RibaClay | 4-6 6-4 6-4 | 3 | 126 | 1 | 0 | 86.7% | 69.2% | 90.0% | 4/7 |
| R16 | 15 | Jurgen MelzerClay | 73 | Jeremy ChardyClay | 7-5 7-6(4) | 3 | 115 | 7 | 0 | 60.3% | 68.1% | 67.7% | 6/8 |
| R16 | 22 | Thomaz BellucciClay | 35 | Philipp KohlschreiberClay | 7-5 6-4 | 3 | 112 | 8 | 4 | 56.8% | 69.0% | 46.9% | 2/4 |
| R16 | 70 | Andreas SeppiClay | 97 | Fabio FogniniClay | 6-4 6-4 | 3 | 91 | 4 | 3 | 57.1% | 72.5% | 46.7% | 7/9 |
| QF | 82 | Andrey GolubevClay | 59 | Denis IstominClay | 6-4 6-1 | 3 | 71 | 4 | 0 | 76.7% | 75.8% | 60.0% | 5/6 |
| QF | 54 | Florian MayerClay | 21 | Juan Carlos FerreroClay | 6-7(3) 6-2 6-3 | 3 | 152 | 7 | 1 | 65.3% | 71.0% | 57.6% | 2/3 |
| QF | 15 | Jurgen MelzerClay | 72 | Potito StaraceClay | 6-4 6-1 | 3 | 68 | 8 | 2 | 72.5% | 75.9% | 72.7% | 0/1 |
| QF | 70 | Andreas SeppiClay | 22 | Thomaz BellucciClay | 7-6(0) 5-7 7-5 | 3 | 192 | 3 | 3 | 55.0% | 70.4% | 55.2% | 5/8 |
| SF | 82 | Andrey GolubevClay | 54 | Florian MayerClay | 7-6(6) 6-4 | 3 | 102 | 2 | 4 | 58.1% | 76.7% | 54.8% | 3/4 |
| SF | 15 | Jurgen MelzerClay | 70 | Andreas SeppiClay | 6-4 6-2 | 3 | 80 | 5 | 1 | 59.4% | 63.2% | 73.1% | 5/5 |
| F | 82 | Andrey GolubevClay | 15 | Jurgen MelzerClay | 6-3 7-5 | 3 | 90 | 7 | 3 | 59.2% | 77.8% | 58.1% | 5/5 |
