| R64 | 120 | Daniel BrandsClay | 79 | Victor CrivoiClay | 4-6 6-4 6-1 | 3 | 99 | 10 | 2 | 65.0% | 76.9% | 46.4% | 6/9 |
| R64 | 145 | Pere RibaClay | 93 | Evgeny KorolevClay | 7-6(3) 6-2 | 3 | 105 | 5 | 3 | 50.6% | 71.8% | 42.1% | 8/11 |
| R64 | 74 | Teymuraz GabashviliClay | 46 | Andreas SeppiClay | 6-3 6-1 | 3 | 103 | 3 | 3 | 54.1% | 60.0% | 64.7% | 12/12 |
| R64 | 56 | Guillermo Garcia-LopezClay | 58 | Christophe RochusClay | 6-4 6-2 | 3 | 70 | 5 | 1 | 73.1% | 71.1% | 42.9% | 1/3 |
| R64 | 72 | Fabio FogniniClay | 62 | Ivo MinarClay | 6-4 6-2 | 3 | 68 | 1 | 1 | 68.0% | 82.4% | 56.3% | 0/0 |
| R64 | 101 | Marcel GranollersClay | 50 | Martin Vassallo ArguelloClay | 6-4 6-4 | 3 | 90 | 1 | 3 | 66.2% | 62.8% | 59.1% | 6/9 |
| R64 | 107 | Pablo CuevasClay | 60 | Bjorn PhauClay | 7-6(0) 6-4 | 3 | 93 | 4 | 1 | 80.3% | 79.2% | 53.8% | 0/0 |
| R64 | 94 | Potito StaraceClay | 97 | Maximo GonzalezClay | 5-7 6-4 6-3 | 3 | 149 | 2 | 3 | 75.2% | 62.0% | 42.3% | 3/8 |
| R64 | 150 | Florian MayerClay | 81 | Rainer SchuettlerClay | 6-7(3) 6-3 6-3 | 3 | 140 | 3 | 6 | 66.3% | 78.5% | 45.5% | 6/8 |
| R64 | 48 | Juan MonacoClay | 67 | Mikhail YouzhnyClay | 7-6(4) 6-3 | 3 | 112 | 0 | 2 | 69.3% | 61.5% | 56.5% | 4/7 |
| R64 | 76 | Simon GreulClay | 70 | Janko TipsarevicClay | 2-6 6-3 6-3 | 3 | 125 | 7 | 3 | 47.1% | 72.7% | 62.2% | 3/6 |
| R64 | 103 | Ivan NavarroClay | 98 | Steve DarcisClay | 6-4 6-4 | 3 | 77 | 5 | 0 | 64.9% | 75.7% | 60.0% | 1/2 |
| R64 | 68 | Julien BenneteauClay | 168 | Juan Ignacio ChelaClay | 6-4 1-6 6-1 | 3 | 106 | 4 | 4 | 62.8% | 65.3% | 37.9% | 4/9 |
| R64 | 89 | Jan HernychClay | - | Kevin KrawietzClay | 6-0 4-6 6-3 | 3 | 78 | 7 | 1 | 70.8% | 70.6% | 52.4% | 1/4 |
| R64 | 52 | Andreas BeckClay | 73 | Oscar HernandezClay | 6-7(3) 6-4 6-4 | 3 | 171 | 4 | 3 | 59.0% | 76.3% | 53.7% | 5/7 |
| R64 | 49 | Philipp PetzschnerClay | 51 | Florent SerraClay | 7-6(3) 6-2 | 3 | 83 | 6 | 2 | 58.5% | 72.9% | 47.1% | 10/12 |
| R32 | 120 | Daniel BrandsClay | 7 | Gilles SimonClay | 3-6 6-4 6-3 | 3 | 131 | 7 | 4 | 67.5% | 65.4% | 38.5% | 8/12 |
| R32 | 39 | Paul-Henri MathieuClay | 145 | Pere RibaClay | 6-1 2-6 7-6(3) | 3 | 131 | 5 | 3 | 46.8% | 75.0% | 52.0% | 2/5 |
| R32 | 26 | Viktor TroickiClay | 74 | Teymuraz GabashviliClay | 3-6 6-2 6-4 | 3 | 161 | 11 | 4 | 47.3% | 71.2% | 46.6% | 13/17 |
| R32 | 56 | Guillermo Garcia-LopezClay | 18 | Stan WawrinkaClay | 6-2 6-4 | 3 | 86 | 0 | 4 | 66.1% | 63.4% | 66.7% | 6/7 |
| R32 | 11 | Robin SoderlingClay | 72 | Fabio FogniniClay | 6-3 6-7(3) 6-3 | 3 | 128 | 5 | 4 | 57.7% | 71.4% | 53.7% | 6/9 |
| R32 | 40 | Nicolas AlmagroClay | 101 | Marcel GranollersClay | 4-6 6-3 6-4 | 3 | 106 | 10 | 2 | 59.6% | 69.8% | 58.3% | 6/8 |
| R32 | 107 | Pablo CuevasClay | 33 | Jurgen MelzerClay | 7-6(5) 6-3 | 3 | 95 | 11 | 1 | 69.4% | 74.4% | 73.7% | 2/3 |
| R32 | 24 | Philipp KohlschreiberClay | 94 | Potito StaraceClay | 6-2 4-6 6-4 | 3 | 118 | 6 | 0 | 75.9% | 72.7% | 47.6% | 0/1 |
| R32 | 23 | David FerrerClay | 150 | Florian MayerClay | 6-3 6-2 | 3 | 70 | 0 | 1 | 59.2% | 75.9% | 75.0% | 2/2 |
| R32 | 48 | Juan MonacoClay | 41 | Jose AcasusoClay | 6-1 1-1 RET | 3 | 42 | 1 | 0 | 71.4% | 73.3% | 66.7% | 0/1 |
| R32 | 76 | Simon GreulClay | 47 | Mischa ZverevClay | 0-6 7-5 6-1 | 3 | 107 | 3 | 3 | 56.8% | 70.0% | 52.6% | 7/10 |
| R32 | 103 | Ivan NavarroClay | 16 | Tommy RobredoClay | 7-5 7-6(2) | 3 | 117 | 2 | 1 | 58.9% | 76.7% | 66.7% | 1/2 |
| R32 | 68 | Julien BenneteauClay | 28 | Igor AndreevClay | 6-4 6-3 | 3 | 96 | 3 | 1 | 60.0% | 61.5% | 61.5% | 5/7 |
| R32 | 31 | Victor HanescuClay | 89 | Jan HernychClay | 6-2 6-3 | 3 | 63 | 3 | 0 | 89.1% | 78.0% | 60.0% | 3/4 |
| R32 | 32 | Jeremy ChardyClay | 52 | Andreas BeckClay | 7-6(2) 7-6(6) | 3 | 109 | 22 | 3 | 61.8% | 85.1% | 65.5% | 2/3 |
| R32 | 12 | Nikolay DavydenkoClay | 49 | Philipp PetzschnerClay | 6-3 6-2 | 3 | 70 | 1 | 1 | 72.4% | 73.8% | 75.0% | 3/3 |
| R16 | 39 | Paul-Henri MathieuClay | 120 | Daniel BrandsClay | 7-5 7-5 | 3 | 103 | 7 | 0 | 50.0% | 74.4% | 64.1% | 3/3 |
| R16 | 26 | Viktor TroickiClay | 56 | Guillermo Garcia-LopezClay | 6-7(2) 6-4 7-6(6) | 3 | 172 | 11 | 2 | 65.8% | 65.8% | 57.9% | 4/7 |
| R16 | 40 | Nicolas AlmagroClay | 11 | Robin SoderlingClay | 7-5 6-3 | 3 | 172 | 11 | 2 | 65.8% | 65.8% | 57.9% | 4/7 |
| R16 | 107 | Pablo CuevasClay | 24 | Philipp KohlschreiberClay | 6-4 7-6(8) | 3 | 114 | 8 | 0 | 68.3% | 80.4% | 53.8% | 4/4 |
| R16 | 23 | David FerrerClay | 48 | Juan MonacoClay | 4-6 7-5 6-2 | 3 | 136 | 4 | 3 | 66.3% | 67.9% | 51.9% | 0/4 |
| R16 | 76 | Simon GreulClay | 103 | Ivan NavarroClay | 7-5 7-6(7) | 3 | 123 | 3 | 1 | 62.2% | 72.5% | 58.1% | 0/1 |
| R16 | 31 | Victor HanescuClay | 68 | Julien BenneteauClay | 3-6 6-3 6-3 | 3 | 113 | 7 | 2 | 66.3% | 69.1% | 57.1% | 11/13 |
| R16 | 12 | Nikolay DavydenkoClay | 32 | Jeremy ChardyClay | 6-3 6-3 | 3 | 72 | 4 | 1 | 78.6% | 90.9% | 66.7% | 0/0 |
| QF | 39 | Paul-Henri MathieuClay | 26 | Viktor TroickiClay | 3-0 RET | 3 | 21 | 1 | 0 | 37.5% | 83.3% | 60.0% | 2/2 |
| QF | 107 | Pablo CuevasClay | 40 | Nicolas AlmagroClay | 6-2 6-4 | 3 | 74 | 4 | 1 | 65.5% | 80.6% | 57.9% | 5/5 |
| QF | 23 | David FerrerClay | 76 | Simon GreulClay | 6-2 6-3 | 3 | 65 | 0 | 0 | 69.6% | 87.5% | 57.1% | 0/0 |
| QF | 12 | Nikolay DavydenkoClay | 31 | Victor HanescuClay | 6-3 4-6 6-3 | 3 | 140 | 3 | 1 | 71.3% | 76.1% | 44.4% | 2/3 |
| SF | 39 | Paul-Henri MathieuClay | 107 | Pablo CuevasClay | 4-6 6-3 7-5 | 3 | 172 | 2 | 2 | 58.4% | 64.4% | 59.5% | 6/10 |
| SF | 12 | Nikolay DavydenkoClay | 23 | David FerrerClay | 7-5 7-6(2) | 3 | 133 | 4 | 2 | 68.2% | 67.2% | 40.7% | 3/6 |
| F | 12 | Nikolay DavydenkoClay | 39 | Paul-Henri MathieuClay | 6-4 6-2 | 3 | 89 | 3 | 1 | 78.0% | 61.5% | 72.7% | 4/6 |