| R32 | 89 |  Jaume MunarClay | 103 |  Malek JaziriClay | 5-7 6-3 6-4 | 3 | 127 | 3 | 0 | 71.8% | 85.2% | 54.2% | 1/2 |
| R32 | 265 |  Gian Marco MoroniClay | 167 | Tommy RobredoClay | 6-2 6-2 | 3 | 70 | 1 | 2 | 67.3% | 78.8% | 56.3% | 1/1 |
| R32 | 49 |  Joao SousaClay | 198 |  Steve DarcisClay | 6-4 6-4 | 3 | 60 | 3 | 0 | 63.6% | 82.9% | 65.0% | 2/2 |
| R32 | 90 | Thomas FabbianoClay | 386 |  Sandro EhratClay | 6-4 7-5 | 3 | 113 | 1 | 5 | 60.0% | 64.9% | 50.0% | 10/12 |
| R32 | 142 |  Jiri VeselyClay | 130 |  Ernests GulbisClay | 7-5 7-5 | 3 | 92 | 5 | 3 | 64.2% | 72.1% | 62.5% | 4/6 |
| R32 | 455 |  Cedrik-Marcel StebeClay | 80 |  Corentin MoutetClay | 6-4 6-4 | 3 | 80 | 0 | 1 | 67.2% | 76.9% | 52.6% | 3/5 |
| R32 | 79 | Pablo AndujarClay | 120 |  Dennis NovakClay | 6-1 3-6 6-3 | 3 | 108 | 4 | 2 | 74.7% | 73.2% | 36.8% | 1/3 |
| R32 | 111 |  Taro DanielClay | 149 | Filippo BaldiClay | 6-4 6-4 | 3 | 74 | 1 | 1 | 74.5% | 73.2% | 71.4% | 1/2 |
| R32 | 107 |  Denis IstominClay | 271 | Marc-Andrea HueslerClay | 6-3 7-6(0) | 3 | 87 | 5 | 2 | 64.3% | 71.1% | 64.0% | 3/4 |
| R32 | 74 | Roberto Carballes BaenaClay | 114 | Paolo LorenziClay | 6-7(1) 6-3 6-2 | 3 | 153 | 8 | 6 | 61.5% | 76.6% | 57.5% | 4/5 |
| R32 | 98 | Stefano TravagliaClay | 215 |  Daniel Elahi GalanClay | 7-6(7) 6-3 | 3 | 80 | 9 | 1 | 57.7% | 80.5% | 60.0% | 3/4 |
| R32 | 85 | Albert Ramos-VinolasClay | 112 | Henri LaaksonenClay | 6-0 6-3 | 3 | 62 | 2 | 3 | 59.6% | 85.7% | 63.2% | 4/4 |
| R16 | 13 | Roberto Bautista AgutClay | 89 | Jaume MunarClay | 7-6(7) 6-4 | 3 | 113 | 2 | 3 | 61.1% | 77.3% | 57.1% | 2/3 |
| R16 | 49 | Joao SousaClay | 265 | Gian Marco MoroniClay | 6-4 6-4 | 3 | 92 | 1 | 1 | 64.6% | 81.0% | 47.8% | 2/2 |
| R16 | 90 | Thomas FabbianoClay | 52 | Lorenzo SonegoClay | 7-6(2) 3-6 6-1 | 3 | 125 | 1 | 3 | 62.8% | 79.6% | 58.6% | 3/5 |
| R16 | 455 | Cedrik-Marcel StebeClay | 142 | Jiri VeselyClay | 7-6(3) 4-6 6-3 | 3 | 134 | 3 | 3 | 63.3% | 74.2% | 63.9% | 3/5 |
| R16 | 79 | Pablo AndujarClay | 111 | Taro DanielClay | 6-1 3-6 7-6(2) | 3 | 140 | 4 | 3 | 65.0% | 71.2% | 57.1% | 2/5 |
| R16 | 26 |  Dusan LajovicClay | 107 | Denis IstominClay | 6-4 6-7(2) 7-6(2) | 3 | 143 | 6 | 5 | 65.7% | 73.2% | 51.4% | 5/8 |
| R16 | 74 | Roberto Carballes BaenaClay | 98 | Stefano TravagliaClay | 6-2 6-4 | 3 | 79 | 1 | 3 | 63.2% | 77.8% | 57.1% | 3/3 |
| R16 | 85 | Albert Ramos-VinolasClay | 30 | Fernando VerdascoClay | 6-4 7-6(4) | 3 | 102 | 4 | 0 | 71.6% | 70.8% | 73.7% | 1/2 |
| QF | 49 | Joao SousaClay | 13 | Roberto Bautista AgutClay | 4-6 6-3 7-5 | 3 | 123 | 5 | 0 | 72.9% | 77.4% | 39.1% | 2/5 |
| QF | 455 | Cedrik-Marcel StebeClay | 90 | Thomas FabbianoClay | 6-4 2-6 6-4 | 3 | 121 | 5 | 4 | 60.9% | 73.6% | 50.0% | 3/6 |
| QF | 79 | Pablo AndujarClay | 26 | Dusan LajovicClay | 7-6(4) 6-4 | 3 | 126 | 1 | 2 | 68.8% | 75.5% | 50.0% | 5/6 |
| QF | 85 | Albert Ramos-VinolasClay | 74 | Roberto Carballes BaenaClay | 6-2 6-1 | 3 | 76 | 4 | 0 | 63.5% | 75.8% | 57.9% | 3/3 |
| SF | 455 | Cedrik-Marcel StebeClay | 49 | Joao SousaClay | 3-6 6-1 6-2 | 3 | 119 | 2 | 3 | 62.5% | 58.0% | 53.3% | 4/8 |
| SF | 85 | Albert Ramos-VinolasClay | 79 | Pablo AndujarClay | 7-6(3) 6-4 | 3 | 113 | 6 | 1 | 67.1% | 70.2% | 57.1% | 6/8 |
| F | 85 | Albert Ramos-VinolasClay | 455 | Cedrik-Marcel StebeClay | 6-3 6-2 | 3 | 81 | 0 | 0 | 64.9% | 70.3% | 60.0% | 4/5 |
