| R32 | 110 |  Kenny De SchepperClay | 119 |  Filippo VolandriClay | 6-3 7-6(3) | 3 | 75 | 7 | 6 | 55.4% | 80.6% | 65.5% | 0/0 |
| R32 | 71 |  Pablo AndujarClay | 36 | Gilles SimonClay | 6-2 3-2 RET | 3 | 63 | 4 | 1 | 68.2% | 53.3% | 64.3% | 4/6 |
| R32 | 80 | SLOBlaz RolaClay | 458 |  Fabiano De PaulaClay | 6-4 6-4 | 3 | 70 | 2 | 2 | 66.7% | 75.0% | 68.8% | 1/3 |
| R32 | 212 |  Yann MartiClay | 89 | Daniel Gimeno-TraverClay | 5-7 7-6(7) 7-6(5) | 3 | 179 | 2 | 5 | 65.0% | 55.9% | 60.0% | 23/29 |
| R32 | 319 | Henri LaaksonenClay | 399 | Gianni MinaClay | 7-6(5) 7-6(3) | 3 | 125 | 1 | 10 | 68.4% | 69.2% | 36.7% | 6/9 |
| R32 | 51 |  Robin HaaseClay | 99 |  Aleksandr NedovyesovClay | 6-4 6-7(3) 6-3 | 3 | 111 | 3 | 5 | 55.2% | 77.4% | 67.4% | 3/4 |
| R32 | 105 |  Juan MonacoClay | 129 |  Victor HanescuClay | 6-4 7-5 | 3 | 84 | 0 | 2 | 65.1% | 68.3% | 63.6% | 2/4 |
| R32 | 93 | Thomaz BellucciClay | 148 |  Gerald MelzerClay | 6-3 6-4 | 3 | 74 | 4 | 2 | 60.0% | 86.1% | 54.2% | 3/3 |
| R32 | 56 | Federico DelbonisClay | 90 |  Dustin BrownClay | 6-3 6-3 | 3 | 54 | 5 | 3 | 69.6% | 87.5% | 35.7% | 0/1 |
| R32 | 847 |  Viktor TroickiClay | 47 | Dominic ThiemClay | 7-6(4) 6-4 | 3 | 95 | 8 | 1 | 46.6% | 73.5% | 53.8% | 5/8 |
| R32 | 59 | Andrey GolubevClay | 330 | Inigo CervantesClay | 3-6 6-3 7-6(4) | 3 | 123 | 3 | 2 | 67.0% | 69.3% | 54.1% | 10/12 |
| R32 | 78 |  Jan-Lennard StruffClay | 109 | Andreas Haider-MaurerClay | 6-2 1-0 RET | 3 | 42 | 0 | 0 | 66.7% | 85.7% | 85.7% | 0/0 |
| R16 | 19 |  Mikhail YouzhnyClay | 110 | Kenny De SchepperClay | 6-3 6-4 | 3 | 70 | 1 | 4 | 64.3% | 80.6% | 65.0% | 0/0 |
| R16 | 51 | Robin HaaseClay | 319 | Henri LaaksonenClay | 6-4 1-6 7-5 | 3 | 138 | 1 | 4 | 59.4% | 55.0% | 53.7% | 4/9 |
| R16 | 105 | Juan MonacoClay | 32 | Guillermo Garcia-LopezClay | 6-2 2-6 6-4 | 3 | 127 | 4 | 1 | 71.6% | 63.0% | 44.8% | 8/12 |
| R16 | 93 | Thomaz BellucciClay | 56 | Federico DelbonisClay | 6-4 6-4 | 3 | 84 | 2 | 4 | 45.2% | 82.1% | 61.8% | 3/3 |
| R16 | 847 | Viktor TroickiClay | 59 | Andrey GolubevClay | 6-3 6-4 | 3 | 67 | 7 | 2 | 62.5% | 75.0% | 54.2% | 6/7 |
| R16 | 38 | Fernando VerdascoClay | 78 | Jan-Lennard StruffClay | 3-6 6-3 7-6(3) | 3 | 130 | 7 | 2 | 51.7% | 80.0% | 69.0% | 3/4 |
| R16 | 71 | Pablo AndujarClay | 80 | SLOBlaz RolaClay | 6-3 6-3 | 3 | 76 | 1 | 4 | 60.7% | 78.4% | 54.2% | 3/3 |
| R16 | 28 | Marcel GranollersClay | 212 | Yann MartiClay | 6-1 6-4 | 3 | 74 | 7 | 2 | 57.4% | 74.2% | 52.2% | 0/2 |
| QF | 51 | Robin HaaseClay | 19 | Mikhail YouzhnyClay | 3-6 6-1 6-4 | 3 | 117 | 7 | 4 | 50.5% | 72.9% | 46.8% | 6/9 |
| QF | 105 | Juan MonacoClay | 93 | Thomaz BellucciClay | 7-6(1) 6-1 | 3 | 91 | 1 | 0 | 68.9% | 76.2% | 57.9% | 1/2 |
| QF | 38 | Fernando VerdascoClay | 847 | Viktor TroickiClay | 6-4 6-7(7) 6-1 | 3 | 125 | 1 | 4 | 56.5% | 71.2% | 67.5% | 3/4 |
| QF | 71 | Pablo AndujarClay | 28 | Marcel GranollersClay | 7-5 6-3 | 3 | 76 | 0 | 0 | 77.4% | 73.2% | 83.3% | 0/2 |
| SF | 105 | Juan MonacoClay | 51 | Robin HaaseClay | 6-3 7-6(4) | 3 | 104 | 0 | 1 | 80.9% | 65.5% | 53.8% | 3/5 |
| SF | 71 | Pablo AndujarClay | 38 | Fernando VerdascoClay | 6-3 6-7(2) 6-1 | 3 | 135 | 0 | 2 | 68.4% | 64.2% | 48.4% | 8/10 |
| F | 71 | Pablo AndujarClay | 105 | Juan MonacoClay | 6-3 7-5 | 3 | 92 | 1 | 2 | 58.3% | 69.0% | 56.7% | 3/5 |
