| R32 | 24 | Stan WawrinkaClay | 363 | Federico DelbonisClay | 6-4 7-5 | 3 | 95 | 4 | 7 | 58.4% | 68.9% | 50.0% | 6/9 |
| R32 | 119 | Thomaz BellucciClay | 188 | Michael LammerClay | 6-7(5) 7-6(5) 6-4 | 3 | 190 | 2 | 6 | 57.6% | 68.1% | 47.2% | 10/15 |
| R32 | 116 | Ivan NavarroClay | 511 | Farrukh DustovClay | 7-6(2) 4-6 6-2 | 3 | 128 | 4 | 3 | 67.9% | 81.8% | 65.4% | 0/1 |
| R32 | 128 | Nicolas KieferClay | 48 | Jose AcasusoClay | 7-6(5) 6-2 | 3 | 86 | 9 | 6 | 53.3% | 93.8% | 53.6% | 4/5 |
| R32 | 27 | Igor AndreevClay | 125 | Diego JunqueiraClay | 7-5 6-4 | 3 | 95 | 4 | 1 | 61.8% | 59.5% | 73.1% | 3/5 |
| R32 | 84 | Jan HernychClay | 109 | Flavio CipollaClay | 6-1 6-0 | 3 | 52 | 4 | 0 | 62.3% | 69.7% | 65.0% | 1/1 |
| R32 | 70 | Mikhail YouzhnyClay | 313 | Gaston GaudioClay | 6-3 5-7 6-4 | 3 | 167 | 5 | 3 | 61.5% | 58.3% | 55.6% | 10/14 |
| R32 | 33 | Jeremy ChardyClay | 261 | Thierry AscioneClay | 6-3 6-3 | 3 | 60 | 12 | 4 | 49.0% | 83.3% | 56.0% | 1/2 |
| R32 | 73 | Marcos DanielClay | 28 | Paul-Henri MathieuClay | 7-6(3) 7-6(6) | 3 | 118 | 13 | 0 | 63.0% | 70.6% | 66.7% | 4/6 |
| R32 | 58 | Julien BenneteauClay | 145 | Stephane BohliClay | 7-6(4) 7-5 | 3 | 116 | 10 | 4 | 70.1% | 77.8% | 65.2% | 3/3 |
| R32 | 50 | Florent SerraClay | 49 | Martin Vassallo ArguelloClay | 6-3 6-2 | 3 | 61 | 1 | 1 | 53.3% | 83.3% | 76.2% | 0/0 |
| R32 | 31 | Victor HanescuClay | 65 | Ivo MinarClay | 6-2 6-2 | 3 | 51 | 4 | 0 | 76.2% | 81.3% | 70.0% | 0/0 |
| R32 | 53 | Guillermo Garcia-LopezClay | 39 | Feliciano LopezClay | 6-4 6-7(4) 6-3 | 3 | 138 | 2 | 7 | 65.3% | 65.6% | 58.8% | 3/6 |
| R32 | 51 | Andreas BeckClay | 172 | Marco ChiudinelliClay | 4-6 7-6(7) 6-4 | 3 | 155 | 6 | 9 | 58.5% | 73.9% | 51.0% | 4/5 |
| R32 | 76 | Teymuraz GabashviliClay | 83 | Paul CapdevilleClay | 1-6 7-6(3) 6-3 | 3 | 129 | 7 | 7 | 60.4% | 65.6% | 52.4% | 7/12 |
| R32 | 81 | Victor CrivoiClay | 23 | Philipp KohlschreiberClay | 6-4 6-0 | 3 | 65 | 4 | 0 | 40.8% | 65.0% | 75.9% | 2/2 |
| R16 | 119 | Thomaz BellucciClay | 24 | Stan WawrinkaClay | 6-4 6-4 | 3 | 75 | 3 | 2 | 66.0% | 77.1% | 77.8% | 0/0 |
| R16 | 128 | Nicolas KieferClay | 116 | Ivan NavarroClay | 6-3 6-7(3) 6-2 | 3 | 143 | 8 | 3 | 58.2% | 73.7% | 63.4% | 4/4 |
| R16 | 27 | Igor AndreevClay | 84 | Jan HernychClay | 6-4 6-1 | 3 | 62 | 3 | 3 | 60.8% | 87.1% | 55.0% | 3/3 |
| R16 | 33 | Jeremy ChardyClay | 70 | Mikhail YouzhnyClay | 6-3 5-7 6-3 | 3 | 121 | 8 | 6 | 60.0% | 75.4% | 34.2% | 2/7 |
| R16 | 73 | Marcos DanielClay | 58 | Julien BenneteauClay | 6-3 7-6(8) | 3 | 118 | 3 | 1 | 62.0% | 70.2% | 65.7% | 7/7 |
| R16 | 50 | Florent SerraClay | 31 | Victor HanescuClay | 6-4 RET | 3 | 31 | 1 | 1 | 71.4% | 80.0% | 62.5% | 2/2 |
| R16 | 51 | Andreas BeckClay | 53 | Guillermo Garcia-LopezClay | 7-6(3) 1-6 7-6(3) | 3 | 168 | 3 | 10 | 55.1% | 75.9% | 45.5% | 5/10 |
| R16 | 81 | Victor CrivoiClay | 76 | Teymuraz GabashviliClay | 6-4 6-4 | 3 | 71 | 8 | 3 | 62.7% | 87.5% | 68.4% | 2/2 |
| QF | 119 | Thomaz BellucciClay | 128 | Nicolas KieferClay | 3-6 1-0 RET | 3 | 53 | 2 | 3 | 46.4% | 84.6% | 40.0% | 0/1 |
| QF | 27 | Igor AndreevClay | 33 | Jeremy ChardyClay | 6-3 6-3 | 3 | 67 | 2 | 2 | 64.2% | 70.6% | 68.4% | 1/1 |
| QF | 73 | Marcos DanielClay | 50 | Florent SerraClay | 6-4 7-6(1) | 3 | 109 | 6 | 2 | 60.3% | 72.7% | 48.3% | 8/11 |
| QF | 51 | Andreas BeckClay | 81 | Victor CrivoiClay | 6-4 7-6(5) | 3 | 105 | 8 | 6 | 51.2% | 70.7% | 46.2% | 7/10 |
| SF | 119 | Thomaz BellucciClay | 27 | Igor AndreevClay | 6-4 7-5 | 3 | 98 | 2 | 2 | 68.9% | 74.5% | 52.2% | 1/1 |
| SF | 51 | Andreas BeckClay | 73 | Marcos DanielClay | 7-6(3) 6-3 | 3 | 85 | 7 | 2 | 60.0% | 88.9% | 66.7% | 0/0 |
| F | 119 | Thomaz BellucciClay | 51 | Andreas BeckClay | 6-4 7-6(2) | 3 | 100 | 7 | 1 | 71.6% | 83.3% | 52.6% | 1/1 |