| R16 | 34 |  Igor AndreevClay | 77 |  Florent SerraClay | 7-5 6-4 | 3 | 70 | 12 | 5 | 52.6% | 86.7% | 63.0% | 3/4 |
| R32 | 137 |  Stephane BohliClay | 588 | Robin RoshardtClay | 6-2 4-6 6-4 | 3 | 106 | 9 | 2 | 53.3% | 80.0% | 51.4% | 1/4 |
| R32 | 121 |  Kristof VliegenClay | 82 |  Martin Vassallo ArguelloClay | 6-3 6-4 | 3 | 83 | 5 | 2 | 57.8% | 78.4% | 63.0% | 1/1 |
| R32 | 54 | Guillermo CanasClay | 86 |  Ivo MinarClay | 7-6(9) 6-3 | 3 | 105 | 4 | 4 | 48.9% | 74.4% | 53.3% | 1/2 |
| R32 | 80 |  Victor HanescuClay | 161 | Olivier PatienceClay | 7-6(4) 6-2 | 3 | 76 | 3 | 1 | 65.1% | 75.6% | 72.7% | 1/1 |
| R32 | 103 | Jeremy ChardyClay | 74 |  Luis HornaClay | 7-6(5) 6-7(6) 7-5 | 3 | 151 | 22 | 10 | 57.0% | 83.6% | 47.3% | 6/7 |
| R32 | 162 |  Dominik MeffertClay | 27 |  Andreas SeppiClay | 6-2 5-7 6-4 | 3 | 137 | 8 | 6 | 65.8% | 67.1% | 44.7% | 10/13 |
| R32 | 32 | Nicolas KieferClay | 244 | Gianluca NasoClay | 6-3 6-2 | 3 | 78 | 7 | 2 | 47.4% | 81.5% | 56.7% | 2/3 |
| R32 | 88 |  Guillermo Garcia-LopezClay | 351 | Michael LammerClay | 5-7 6-3 6-2 | 3 | 146 | 5 | 6 | 65.1% | 66.7% | 48.6% | 4/7 |
| R32 | 131 | Flavio CipollaClay | 90 | Jiri VanekClay | 5-7 6-4 6-4 | 3 | 149 | 1 | 2 | 68.0% | 64.3% | 45.5% | 7/11 |
| R32 | 34 | Igor AndreevClay | 78 |  Marcos DanielClay | 6-4 7-5 | 3 | 84 | 6 | 5 | 63.1% | 87.8% | 50.0% | 5/5 |
| R32 | 77 | Florent SerraClay | 113 | Daniel Gimeno-TraverClay | 7-6(2) 7-6(5) | 3 | 103 | 1 | 2 | 57.8% | 72.9% | 54.3% | 4/6 |
| R32 | 43 |  Marin CilicClay | 211 | Josselin OuannaClay | 6-3 6-4 | 3 | 67 | 13 | 3 | 50.0% | 88.9% | 66.7% | 1/1 |
| R16 | 10 | Stan WawrinkaClay | 137 | Stephane BohliClay | 7-6(6) 5-7 7-6(3) | 3 | 165 | 13 | 5 | 61.3% | 79.4% | 60.5% | 3/4 |
| R16 | 54 | Guillermo CanasClay | 121 | Kristof VliegenClay | W/O | 3 | - | 13 | 5 | 61.3% | 79.4% | 60.5% | 3/4 |
| R16 | 80 | Victor HanescuClay | 21 | Ivo KarlovicClay | 6-7(4) 7-6(3) 7-6(11) | 3 | 152 | 9 | 0 | 71.1% | 84.0% | 78.8% | 1/1 |
| R16 | 103 | Jeremy ChardyClay | 162 | Dominik MeffertClay | 6-7(1) 7-6(5) 7-6(4) | 3 | 166 | 19 | 9 | 50.0% | 89.2% | 47.7% | 6/8 |
| R16 | 88 | Guillermo Garcia-LopezClay | 32 | Nicolas KieferClay | W/O | 3 | - | 19 | 9 | 50.0% | 89.2% | 47.7% | 6/8 |
| R16 | 16 | Mikhail YouzhnyClay | 131 | Flavio CipollaClay | 6-3 6-2 | 3 | 92 | 6 | 8 | 58.4% | 71.2% | 43.2% | 12/13 |
| R16 | 43 | Marin CilicClay | 18 | Paul-Henri MathieuClay | 6-3 6-4 | 3 | 84 | 11 | 4 | 43.4% | 91.3% | 66.7% | 3/3 |
| QF | 10 | Stan WawrinkaClay | 54 | Guillermo CanasClay | 4-6 6-4 7-6(2) | 3 | 152 | 6 | 6 | 65.9% | 73.3% | 51.6% | 2/6 |
| QF | 80 | Victor HanescuClay | 103 | Jeremy ChardyClay | 6-3 7-6(3) | 3 | 77 | 4 | 1 | 75.4% | 82.6% | 80.0% | 3/3 |
| QF | 88 | Guillermo Garcia-LopezClay | 16 | Mikhail YouzhnyClay | 4-6 7-5 6-3 | 3 | 128 | 4 | 4 | 55.1% | 75.9% | 54.5% | 7/9 |
| QF | 34 | Igor AndreevClay | 43 | Marin CilicClay | 7-6(4) 6-3 | 3 | 85 | 6 | 4 | 64.6% | 80.4% | 50.0% | 4/4 |
| SF | 80 | Victor HanescuClay | 10 | Stan WawrinkaClay | 6-3 3-6 6-4 | 3 | 124 | 12 | 2 | 65.0% | 73.1% | 50.0% | 2/4 |
| SF | 34 | Igor AndreevClay | 88 | Guillermo Garcia-LopezClay | 7-6(2) 5-7 7-6(5) | 3 | 182 | 8 | 3 | 62.3% | 83.3% | 62.5% | 3/4 |
| F | 80 | Victor HanescuClay | 34 | Igor AndreevClay | 6-3 6-4 | 3 | 70 | 1 | 1 | 71.2% | 78.4% | 73.3% | 0/0 |
