| R32 | 57 |  Gael MonfilsClay | 5 |  Nikolay DavydenkoClay | 3-6 6-4 7-5 | 3 | 118 | 12 | 8 | 53.6% | 76.3% | 47.1% | 16/19 |
| R32 | 120 |  Jiri VanekClay | 84 | Florent SerraClay | 6-4 6-1 | 3 | 61 | 7 | 2 | 63.6% | 78.6% | 56.3% | 0/1 |
| R32 | 61 |  Feliciano LopezClay | 1511 |  Michel KratochvilClay | 6-2 6-3 | 3 | 80 | 10 | 4 | 41.4% | 87.5% | 55.9% | 4/4 |
| R32 | 28 | Paul-Henri MathieuClay | 76 |  Sergio RoitmanClay | 7-6(4) 6-4 | 3 | 106 | 5 | 3 | 50.0% | 79.5% | 51.3% | 3/4 |
| R32 | 34 |  Philipp KohlschreiberClay | 113 | Jan HernychClay | 7-6(0) 7-6(3) | 3 | 104 | 4 | 3 | 51.4% | 78.9% | 61.1% | 3/5 |
| R32 | 127 | Radek StepanekClay | 101 |  Marin CilicClay | 7-5 6-3 | 3 | 128 | 6 | 1 | 62.3% | 84.8% | 65.0% | 0/0 |
| R32 | 64 |  Werner EschauerClay | 225 | Michael LammerClay | 6-2 4-6 6-2 | 3 | 113 | 5 | 4 | 66.3% | 67.8% | 46.7% | 8/10 |
| R32 | 41 | Marc GicquelClay | 88 | Diego HartfieldClay | 6-3 7-6(5) | 3 | 89 | 3 | 5 | 56.9% | 80.5% | 58.1% | 2/2 |
| R32 | 46 |  Potito StaraceClay | 146 | Jan HajekClay | 7-6(4) 6-1 | 3 | 72 | 3 | 2 | 70.9% | 82.1% | 68.8% | 1/2 |
| R32 | 59 | Igor AndreevClay | 47 | Albert MontanesClay | 3-6 6-3 6-4 | 3 | 111 | 3 | 2 | 74.3% | 78.2% | 68.4% | 3/4 |
| R32 | 75 |  Kristof VliegenClay | 103 | Gaston GaudioClay | 6-4 6-7(3) 6-4 | 3 | 143 | 12 | 2 | 57.4% | 71.2% | 53.1% | 4/6 |
| R32 | 7 | Richard GasquetClay | 93 | Ruben Ramirez HidalgoClay | 6-3 6-4 | 3 | 77 | 9 | 2 | 66.7% | 65.4% | 38.5% | 7/10 |
| R32 | 97 | Martin Vassallo ArguelloClay | 50 | Stan WawrinkaClay | 7-5 1-6 6-4 | 3 | 129 | 0 | 6 | 67.1% | 56.4% | 59.3% | 7/12 |
| R32 | 58 |  Nicolas LapenttiClay | 49 | Jose AcasusoClay | 7-5 6-1 | 3 | 92 | 5 | 3 | 51.4% | 77.8% | 55.9% | 7/7 |
| R32 | 111 | Andreas SeppiClay | 340 | Bartolome Salva-VidalClay | 6-4 6-0 | 3 | 70 | 3 | 3 | 50.0% | 67.9% | 57.1% | 6/7 |
| R32 | 65 | Stefan KoubekClay | 14 | Mikhail YouzhnyClay | 6-4 6-3 | 3 | 70 | 4 | 1 | 53.6% | 78.4% | 56.3% | 9/9 |
| R16 | 28 | Paul-Henri MathieuClay | 61 | Feliciano LopezClay | 4-6 6-4 7-6(4) | 3 | 132 | 9 | 0 | 50.5% | 78.4% | 58.0% | 8/10 |
| R16 | 127 | Radek StepanekClay | 34 | Philipp KohlschreiberClay | 7-5 6-3 | 3 | 85 | 10 | 0 | 63.5% | 77.5% | 69.6% | 1/1 |
| R16 | 41 | Marc GicquelClay | 64 | Werner EschauerClay | 6-2 7-6(4) | 3 | 80 | 11 | 2 | 51.6% | 90.6% | 50.0% | 0/0 |
| R16 | 59 | Igor AndreevClay | 46 | Potito StaraceClay | 6-3 7-5 | 3 | 73 | 10 | 4 | 68.3% | 83.7% | 45.0% | 0/1 |
| R16 | 7 | Richard GasquetClay | 75 | Kristof VliegenClay | 6-3 6-4 | 3 | 59 | 6 | 1 | 55.8% | 82.8% | 65.2% | 0/1 |
| R16 | 97 | Martin Vassallo ArguelloClay | 58 | Nicolas LapenttiClay | 6-4 3-6 6-4 | 3 | 144 | 3 | 5 | 66.7% | 69.2% | 57.7% | 3/6 |
| R16 | 111 | Andreas SeppiClay | 65 | Stefan KoubekClay | 1-6 7-6(4) 7-6(6) | 3 | 139 | 4 | 6 | 56.4% | 79.0% | 41.7% | 7/11 |
| QF | 28 | Paul-Henri MathieuClay | 57 | Gael MonfilsClay | 6-1 4-6 6-3 | 3 | 99 | 4 | 2 | 53.6% | 75.7% | 68.8% | 0/1 |
| R16 | 57 | Gael MonfilsClay | 120 | Jiri VanekClay | 6-1 6-4 | 3 | 51 | 15 | 4 | 59.1% | 96.2% | 61.1% | 0/0 |
| QF | 127 | Radek StepanekClay | 41 | Marc GicquelClay | 6-3 6-3 | 3 | 70 | 11 | 4 | 54.7% | 89.7% | 62.5% | 4/4 |
| QF | 59 | Igor AndreevClay | 7 | Richard GasquetClay | 7-5 6-2 | 3 | 76 | 3 | 0 | 61.2% | 90.0% | 68.4% | 0/0 |
| QF | 111 | Andreas SeppiClay | 97 | Martin Vassallo ArguelloClay | 6-4 6-0 | 3 | 70 | 1 | 2 | 51.2% | 81.0% | 60.0% | 1/2 |
| SF | 28 | Paul-Henri MathieuClay | 127 | Radek StepanekClay | 6-3 6-4 | 3 | 72 | 4 | 2 | 64.8% | 82.9% | 68.4% | 0/0 |
| SF | 111 | Andreas SeppiClay | 59 | Igor AndreevClay | 6-4 3-6 7-6(5) | 3 | 127 | 5 | 3 | 70.5% | 77.6% | 53.6% | 2/3 |
| F | 28 | Paul-Henri MathieuClay | 111 | Andreas SeppiClay | 6-7(1) 6-4 7-5 | 3 | 161 | 8 | 1 | 48.1% | 74.5% | 56.4% | 6/9 |
