| R32 | 4 |  Ivan LjubicicClay | 126 |  Albert PortasClay | 6-3 7-6(5) | 3 | 100 | 10 | 3 | 55.7% | 84.6% | 61.3% | 1/1 |
| R32 | 341 |  Marco ChiudinelliClay | 64 |  Davide SanguinettiClay | 6-3 6-2 | 3 | 75 | 4 | 2 | 61.2% | 63.4% | 57.7% | 7/9 |
| R32 | 62 | Ruben Ramirez HidalgoClay | 744 | Robin RoshardtClay | 6-1 6-4 | 3 | 66 | 3 | 4 | 63.0% | 86.2% | 41.2% | 3/4 |
| R32 | 68 | Feliciano LopezClay | 56 | Filippo VolandriClay | 6-4 6-4 | 3 | 63 | 12 | 0 | 48.1% | 100.0% | 57.1% | 4/4 |
| R32 | 425 |  Dusan VemicClay | 33 |  Paul-Henri MathieuClay | 3-6 7-5 7-6(6) | 3 | 139 | 12 | 5 | 62.3% | 72.7% | 57.5% | 8/10 |
| R32 | 316 | Marin CilicClay | 63 | Andreas SeppiClay | 6-3 7-6(6) | 3 | 95 | 4 | 3 | 47.1% | 72.7% | 56.8% | 1/3 |
| R32 | 79 |  Andrei PavelClay | 69 | Stan WawrinkaClay | 6-4 1-6 7-6(4) | 3 | 138 | 3 | 1 | 61.7% | 65.2% | 61.0% | 3/5 |
| R32 | 131 |  Jiri NovakClay | 42 | Carlos MoyaClay | 6-3 6-2 | 3 | 56 | 4 | 0 | 59.6% | 85.7% | 73.7% | 1/1 |
| R32 | 72 |  Philipp KohlschreiberClay | 89 | Alessio Di MauroClay | 6-3 6-1 | 3 | 58 | 9 | 2 | 50.0% | 95.5% | 31.8% | 0/2 |
| R32 | 50 | Daniele BraccialiClay | 103 |  Flavio SarettaClay | 5-7 6-1 6-4 | 3 | 124 | 10 | 1 | 43.0% | 79.1% | 52.6% | 6/8 |
| R32 | 24 | Fernando VerdascoClay | 122 |  Dick NormanClay | 6-4 6-3 | 3 | 60 | 3 | 4 | 71.2% | 73.0% | 60.0% | 1/2 |
| R32 | 60 | Richard GasquetClay | 80 | Simon GreulClay | 6-3 6-3 | 3 | 70 | 5 | 4 | 61.0% | 75.0% | 60.9% | 2/2 |
| R32 | 73 | Robin VikClay | 638 | Roman VogeliClay | 6-2 6-1 | 3 | 60 | 2 | 1 | 65.0% | 84.6% | 57.1% | 2/2 |
| R32 | 65 | Christophe RochusClay | 98 | Fernando VicenteClay | 6-1 4-6 6-2 | 3 | 107 | 1 | 3 | 69.0% | 65.0% | 44.4% | 10/13 |
| R32 | 14 |  Gaston GaudioClay | 81 | Marcos DanielClay | 7-6(4) 6-2 | 3 | 103 | 2 | 4 | 56.5% | 77.1% | 55.6% | 1/3 |
| R16 | 4 | Ivan LjubicicClay | 341 | Marco ChiudinelliClay | 6-7(6) 6-3 6-2 | 3 | 133 | 13 | 5 | 51.9% | 97.5% | 59.5% | 0/0 |
| R16 | 68 | Feliciano LopezClay | 62 | Ruben Ramirez HidalgoClay | 6-7(5) 6-3 7-6(3) | 3 | 133 | 16 | 2 | 66.0% | 90.3% | 62.5% | 0/0 |
| R16 | 316 | Marin CilicClay | 425 | Dusan VemicClay | 2-6 6-3 6-4 | 3 | 109 | 3 | 5 | 46.3% | 70.3% | 55.8% | 2/5 |
| R16 | 79 | Andrei PavelClay | 52 |  Max MirnyiClay | 6-2 6-4 | 3 | 141 | 4 | 1 | 74.5% | 82.9% | 75.0% | 2/2 |
| R16 | 72 | Philipp KohlschreiberClay | 131 | Jiri NovakClay | 3-6 7-6(5) 6-1 | 3 | 111 | 8 | 0 | 53.3% | 72.9% | 54.8% | 5/7 |
| R16 | 24 | Fernando VerdascoClay | 50 | Daniele BraccialiClay | 6-3 6-1 | 3 | 52 | 4 | 3 | 78.3% | 83.3% | 50.0% | 3/3 |
| R16 | 60 | Richard GasquetClay | 73 | Robin VikClay | 6-1 6-1 | 3 | 53 | 5 | 1 | 59.0% | 82.6% | 56.3% | 1/2 |
| R16 | 14 | Gaston GaudioClay | 65 | Christophe RochusClay | 6-0 6-4 | 3 | 68 | 1 | 4 | 56.1% | 82.6% | 61.1% | 0/1 |
| QF | 68 | Feliciano LopezClay | 4 | Ivan LjubicicClay | 7-6(4) 6-3 | 3 | 82 | 10 | 1 | 51.4% | 80.6% | 64.7% | 4/4 |
| QF | 316 | Marin CilicClay | 79 | Andrei PavelClay | 6-7(5) 6-3 7-5 | 3 | 145 | 11 | 3 | 59.2% | 77.5% | 49.0% | 6/6 |
| QF | 72 | Philipp KohlschreiberClay | 24 | Fernando VerdascoClay | 6-3 4-6 6-4 | 3 | 133 | 4 | 4 | 51.5% | 68.6% | 54.2% | 7/10 |
| QF | 60 | Richard GasquetClay | 14 | Gaston GaudioClay | 6-3 6-2 | 3 | 82 | 8 | 6 | 60.9% | 73.8% | 51.9% | 8/8 |
| SF | 68 | Feliciano LopezClay | 316 | Marin CilicClay | 7-6(2) 6-7(5) 6-3 | 3 | 157 | 27 | 6 | 66.4% | 76.6% | 46.2% | 4/6 |
| SF | 60 | Richard GasquetClay | 72 | Philipp KohlschreiberClay | 6-1 1-6 6-2 | 3 | 92 | 7 | 3 | 62.3% | 78.9% | 47.8% | 1/3 |
| F | 60 | Richard GasquetClay | 68 | Feliciano LopezClay | 7-6(4) 6-7(3) 6-3 6-3 | 5 | 185 | 9 | 2 | 68.3% | 81.7% | 71.1% | 2/2 |
| R32 | 52 | Max MirnyiClay | 105 | Carlos BerlocqClay | 6-3 7-5 | 3 | 80 | 5 | 0 | 60.8% | 90.3% | 80.0% | 0/0 |
