| R32 | 28 |  Marc RossetClay | 5 |  Yevgeny KafelnikovClay | 6-4 6-3 | 3 | 59 | 6 | 1 | 61.5% | 87.5% | 55.0% | 3/3 |
| R32 | 43 |  Dominik HrbatyClay | 112 |  Martin SinnerClay | 6-7(9) 7-6(4) 6-4 | 3 | 140 | 8 | 7 | 50.8% | 78.3% | 56.9% | 5/7 |
| R32 | 135 |  Fernando VicenteClay | 52 | MARKarim AlamiClay | 6-2 6-1 | 3 | 48 | 2 | 2 | 53.8% | 78.6% | 58.3% | 2/2 |
| R32 | 26 |  Wayne FerreiraClay | 37 | Francisco ClavetClay | 3-6 6-4 6-4 | 3 | 112 | 8 | 4 | 46.8% | 77.3% | 38.0% | 6/11 |
| R32 | 7 | Sergi BrugueraClay | 386 |  Pat CashClay | 6-3 6-1 | 3 | 65 | 3 | 1 | 61.2% | 76.7% | 63.2% | 2/2 |
| R32 | 42 | Javier SanchezClay | 473 |  Bertrand MadsenClay | 3-6 6-3 6-3 | 3 | 84 | 7 | 3 | 56.9% | 83.8% | 78.6% | 2/3 |
| R32 | 75 | Galo BlancoClay | 27 |  Bohdan UlihrachClay | 6-3 6-2 | 3 | 59 | 5 | 1 | 52.5% | 83.9% | 64.3% | 7/7 |
| R32 | 16 | Felix MantillaClay | 136 |  Lucas Arnold KerClay | 7-5 6-1 | 3 | 65 | 1 | 4 | 66.1% | 64.1% | 45.0% | 1/4 |
| R32 | 54 |  Richey RenebergClay | 14 | Albert CostaClay | 6-2 1-6 6-4 | 3 | 87 | 12 | 7 | 49.4% | 86.0% | 36.4% | 3/6 |
| R32 | 68 | Nicolas KieferClay | 121 |  Thierry ChampionClay | 2-6 7-6(0) 6-4 | 3 | 124 | 6 | 7 | 46.9% | 75.6% | 47.1% | 6/10 |
| R32 | 67 | Juan Albert Viloca-PuigClay | 188 | Ivo HeubergerClay | 6-3 6-4 | 3 | 83 | 4 | 1 | 62.1% | 75.6% | 60.0% | 5/5 |
| R32 | 9 |  Marcelo RiosClay | 125 |  Jaime OncinsClay | 6-4 6-2 | 3 | 71 | 5 | 4 | 55.2% | 65.6% | 53.8% | 4/6 |
| R32 | 19 | Alberto BerasateguiClay | 61 | Daniel VacekClay | 6-3 6-4 | 3 | 63 | 1 | 7 | 71.9% | 73.9% | 55.6% | 6/7 |
| R32 | 73 |  Renzo FurlanClay | 38 | Marc-Kevin GoellnerClay | 5-7 6-0 6-4 | 3 | 109 | 7 | 3 | 61.8% | 72.7% | 61.8% | 6/7 |
| R32 | 23 | Cedric PiolineClay | 55 | Fabrice SantoroClay | 3-6 6-2 7-6(7) | 3 | 133 | 5 | 2 | 68.0% | 72.7% | 51.6% | 4/7 |
| R32 | 6 | Alex CorretjaClay | 60 | Jiri NovakClay | 6-3 7-5 | 3 | 74 | 3 | 3 | 49.1% | 85.2% | 53.6% | 1/3 |
| R16 | 28 | Marc RossetClay | 43 | Dominik HrbatyClay | 7-6(4) 6-3 | 3 | 83 | 9 | 3 | 60.9% | 94.9% | 52.0% | 0/0 |
| R16 | 26 | Wayne FerreiraClay | 135 | Fernando VicenteClay | 2-6 6-3 6-4 | 3 | 82 | 12 | 3 | 40.2% | 84.8% | 49.0% | 3/7 |
| R16 | 42 | Javier SanchezClay | 7 | Sergi BrugueraClay | 7-6(3) 6-2 | 3 | 77 | 1 | 1 | 63.8% | 70.3% | 66.7% | 0/1 |
| R16 | 16 | Felix MantillaClay | 75 | Galo BlancoClay | 7-6(5) 6-2 | 3 | 75 | 3 | 1 | 71.7% | 88.4% | 41.2% | 0/0 |
| R16 | 68 | Nicolas KieferClay | 54 | Richey RenebergClay | 7-5 6-3 | 3 | 77 | 7 | 5 | 46.3% | 83.9% | 44.4% | 3/5 |
| R16 | 67 | Juan Albert Viloca-PuigClay | 9 | Marcelo RiosClay | 6-3 7-6(3) | 3 | 86 | 8 | 2 | 56.6% | 76.6% | 47.2% | 5/7 |
| R16 | 19 | Alberto BerasateguiClay | 73 | Renzo FurlanClay | 7-6(2) 1-6 7-5 | 3 | 126 | 2 | 6 | 67.7% | 61.5% | 61.3% | 9/14 |
| R16 | 6 | Alex CorretjaClay | 23 | Cedric PiolineClay | 6-2 3-2 RET | 3 | 51 | 2 | 1 | 63.6% | 78.6% | 62.5% | 3/3 |
| QF | 26 | Wayne FerreiraClay | 28 | Marc RossetClay | 7-5 7-6(10) | 3 | 113 | 7 | 3 | 48.6% | 71.2% | 52.7% | 6/7 |
| QF | 16 | Felix MantillaClay | 42 | Javier SanchezClay | 6-4 6-3 | 3 | 71 | 0 | 0 | 72.9% | 60.5% | 56.3% | 4/7 |
| QF | 67 | Juan Albert Viloca-PuigClay | 68 | Nicolas KieferClay | 6-4 6-3 | 3 | 67 | 4 | 2 | 58.8% | 80.0% | 57.1% | 4/5 |
| QF | 6 | Alex CorretjaClay | 19 | Alberto BerasateguiClay | 6-4 6-0 | 3 | 65 | 2 | 5 | 56.6% | 76.7% | 47.8% | 2/3 |
| SF | 16 | Felix MantillaClay | 26 | Wayne FerreiraClay | 6-3 6-4 | 3 | 65 | 2 | 3 | 75.5% | 70.0% | 69.2% | 3/5 |
| SF | 67 | Juan Albert Viloca-PuigClay | 6 | Alex CorretjaClay | 3-6 7-6(5) 6-4 | 3 | 152 | 6 | 4 | 54.4% | 76.8% | 51.1% | 9/11 |
| F | 16 | Felix MantillaClay | 67 | Juan Albert Viloca-PuigClay | 6-1 6-4 6-4 | 5 | 98 | 3 | 0 | 66.7% | 79.6% | 66.7% | 3/3 |
