| R32 | 102 |  Somdev DevvarmanClay | 64 |  Matthew EbdenClay | 6-2 6-3 | 3 | 73 | 3 | 0 | 44.9% | 63.6% | 70.4% | 3/4 |
| R32 | 76 |  Lukasz KubotClay | 52 |  Teymuraz GabashviliClay | 6-3 7-5 | 3 | 97 | 2 | 3 | 66.3% | 65.5% | 50.0% | 4/6 |
| R32 | 62 |  Carlos BerlocqClay | 190 |  Taro DanielClay | 6-3 6-2 | 3 | 82 | 8 | 2 | 60.4% | 71.9% | 38.1% | 2/5 |
| R32 | 161 |  Pablo CuevasClay | 73 |  Aleksandr NedovyesovClay | 4-6 6-3 6-4 | 3 | 113 | 3 | 1 | 55.7% | 63.6% | 65.7% | 3/7 |
| R32 | 61 | Andrey GolubevClay | 92 |  Adrian MannarinoClay | 6-3 3-6 6-4 | 3 | 123 | 2 | 6 | 54.1% | 65.2% | 53.8% | 3/8 |
| R32 | 88 | Leonardo MayerClay | 40 |  Joao SousaClay | 3-6 6-1 6-2 | 3 | 118 | 5 | 10 | 50.6% | 81.4% | 45.2% | 7/9 |
| R32 | 179 | Gastao EliasClay | 84 |  Filippo VolandriClay | 6-4 6-3 | 3 | 105 | 8 | 4 | 46.7% | 62.9% | 55.0% | 7/9 |
| R32 | 93 |  Victor HanescuClay | 178 |  Radu AlbotClay | 3-6 6-4 6-4 | 3 | 126 | 3 | 4 | 69.2% | 61.9% | 42.9% | 7/12 |
| R32 | 60 |  Pablo Carreno BustaClay | 59 | Mikhail KukushkinClay | 6-1 7-6(3) | 3 | 76 | 6 | 4 | 58.9% | 75.8% | 56.5% | 1/4 |
| R32 | 243 | Rui MachadoClay | 32 |  Dmitry TursunovClay | 6-0 6-0 | 3 | 48 | 3 | 1 | 68.4% | 65.4% | 83.3% | 0/0 |
| R32 | 98 | Daniel Gimeno-TraverClay | 80 |  Alejandro GonzalezClay | 6-4 6-1 | 3 | 70 | 4 | 4 | 57.1% | 77.8% | 48.1% | 2/3 |
| R32 | 57 | Albert MontanesClay | 188 | Roberto Carballes BaenaClay | 7-6(4) 6-3 | 3 | 99 | 4 | 2 | 57.1% | 75.0% | 56.7% | 1/3 |
| R16 | 6 |  Tomas BerdychClay | 102 | Somdev DevvarmanClay | 6-3 6-2 | 3 | 76 | 6 | 4 | 63.0% | 85.3% | 50.0% | 3/3 |
| R16 | 88 | Leonardo MayerClay | 61 | Andrey GolubevClay | 6-1 7-6(3) | 3 | 94 | 1 | 3 | 46.2% | 73.3% | 71.4% | 4/5 |
| R16 | 179 | Gastao EliasClay | 39 | Guillermo Garcia-LopezClay | 6-4 3-6 6-2 | 3 | 124 | 2 | 4 | 43.4% | 75.0% | 48.9% | 2/5 |
| R16 | 93 | Victor HanescuClay | 60 | Pablo Carreno BustaClay | 6-3 4-6 6-3 | 3 | 129 | 2 | 2 | 67.0% | 64.4% | 62.1% | 5/8 |
| R16 | 98 | Daniel Gimeno-TraverClay | 243 | Rui MachadoClay | 6-3 7-6(2) | 3 | 97 | 7 | 4 | 47.5% | 81.6% | 52.4% | 5/6 |
| R16 | 31 | Marcel GranollersClay | 57 | Albert MontanesClay | 3-6 7-6(5) 6-2 | 3 | 139 | 6 | 2 | 50.5% | 74.0% | 51.0% | 7/10 |
| R16 | 62 | Carlos BerlocqClay | 76 | Lukasz KubotClay | 6-4 6-3 | 3 | 79 | 5 | 2 | 70.0% | 85.7% | 53.3% | 2/2 |
| R16 | 9 |  Milos RaonicClay | 161 | Pablo CuevasClay | 6-3 6-2 | 3 | 68 | 6 | 5 | 57.4% | 85.2% | 65.0% | 0/0 |
| QF | 6 | Tomas BerdychClay | 88 | Leonardo MayerClay | 3-6 6-4 6-4 | 3 | 129 | 5 | 2 | 60.5% | 73.1% | 38.2% | 1/6 |
| QF | 93 | Victor HanescuClay | 179 | Gastao EliasClay | 6-1 7-5 | 3 | 82 | 2 | 0 | 67.7% | 68.2% | 47.6% | 3/5 |
| QF | 98 | Daniel Gimeno-TraverClay | 31 | Marcel GranollersClay | 6-1 6-2 | 3 | 73 | 2 | 1 | 48.3% | 75.0% | 63.3% | 2/2 |
| QF | 62 | Carlos BerlocqClay | 9 | Milos RaonicClay | 7-5 6-4 | 3 | 86 | 2 | 2 | 73.7% | 73.8% | 53.3% | 1/3 |
| SF | 6 | Tomas BerdychClay | 93 | Victor HanescuClay | 6-2 6-2 | 3 | 63 | 5 | 2 | 65.1% | 85.7% | 60.0% | 1/1 |
| SF | 62 | Carlos BerlocqClay | 98 | Daniel Gimeno-TraverClay | 7-6(6) 6-2 | 3 | 94 | 2 | 4 | 75.0% | 80.4% | 41.2% | 2/3 |
| F | 62 | Carlos BerlocqClay | 6 | Tomas BerdychClay | 0-6 7-5 6-1 | 3 | 130 | 0 | 3 | 71.4% | 58.2% | 27.3% | 6/12 |
