| R32 | 73 |  Edouard Roger-VasselinClay | 67 |  Gilles MullerClay | 6-1 RET | 3 | 32 | 0 | 0 | 68.8% | 81.8% | 80.0% | 0/0 |
| R32 | 113 |  Gastao EliasClay | 41 |  Horacio ZeballosClay | 6-3 6-4 | 3 | 82 | 4 | 2 | 50.8% | 81.3% | 51.6% | 4/5 |
| R32 | 50 |  Denis IstominClay | 77 |  Evgeny DonskoyClay | 2-6 7-6(6) 6-4 | 3 | 127 | 4 | 3 | 69.2% | 68.1% | 50.0% | 7/10 |
| R32 | 57 |  Albert Ramos-VinolasClay | 64 | Carlos BerlocqClay | 7-6(4) 2-6 6-3 | 3 | 155 | 3 | 2 | 68.3% | 57.7% | 48.5% | 9/16 |
| R32 | 54 |  Victor HanescuClay | 330 | Rui MachadoClay | 6-4 6-4 | 3 | 100 | 1 | 1 | 80.3% | 63.9% | 53.3% | 9/10 |
| R32 | 32 | Benoit PaireClay | 70 |  Igor SijslingClay | 7-6(5) 6-3 | 3 | 74 | 7 | 5 | 48.7% | 78.4% | 38.5% | 6/9 |
| R32 | 65 |  Alejandro FallaClay | 82 | Andrey KuznetsovClay | 7-5 6-4 | 3 | 95 | 3 | 0 | 59.2% | 73.3% | 51.6% | 9/10 |
| R32 | 74 | Robin HaaseClay | 92 | Pablo AndujarClay | 4-6 6-2 6-3 | 3 | 134 | 3 | 1 | 71.6% | 70.5% | 48.4% | 11/12 |
| R32 | 38 | Tommy RobredoClay | 52 | Daniel Gimeno-TraverClay | 2-6 7-5 6-3 | 3 | 108 | 3 | 2 | 74.4% | 65.6% | 40.9% | 2/6 |
| R32 | 228 | Pablo Carreno BustaClay | 33 | Julien BenneteauClay | 6-3 6-4 | 3 | 94 | 5 | 0 | 45.6% | 61.3% | 64.9% | 5/7 |
| R32 | 61 |  David GoffinClay | 224 | Pedro SousaClay | 7-6(1) 4-6 6-4 | 3 | 124 | 2 | 4 | 77.6% | 53.0% | 37.5% | 5/14 |
| R32 | 63 |  Paolo LorenziClay | 208 | Niels DeseinClay | 6-3 4-6 6-2 | 3 | 124 | 4 | 3 | 64.3% | 70.4% | 56.7% | 7/9 |
| R16 | 4 | David FerrerClay | 73 | Edouard Roger-VasselinClay | 6-4 4-6 6-3 | 3 | 110 | 2 | 4 | 64.0% | 73.7% | 53.1% | 5/8 |
| R16 | 54 | Victor HanescuClay | 32 | Benoit PaireClay | 7-6(2) 6-4 | 3 | 90 | 1 | 1 | 72.2% | 71.2% | 65.0% | 1/2 |
| R16 | 18 | Andreas SeppiClay | 65 | Alejandro FallaClay | 6-4 6-0 | 3 | 62 | 2 | 3 | 57.1% | 79.2% | 61.1% | 0/1 |
| R16 | 38 | Tommy RobredoClay | 74 | Robin HaaseClay | 6-4 6-4 | 3 | 85 | 2 | 1 | 72.1% | 69.4% | 52.6% | 4/6 |
| R16 | 228 | Pablo Carreno BustaClay | 61 | David GoffinClay | 1-6 6-2 6-2 | 3 | 115 | 3 | 2 | 54.1% | 54.3% | 48.7% | 3/8 |
| R16 | 25 | Fabio FogniniClay | 63 | Paolo LorenziClay | 7-6(5) 5-7 6-4 | 3 | 163 | 3 | 4 | 68.1% | 74.0% | 47.2% | 5/8 |
| R16 | 113 | Gastao EliasClay | 50 | Denis IstominClay | 3-6 6-1 6-4 | 3 | 115 | 1 | 5 | 55.3% | 61.7% | 60.5% | 5/8 |
| R16 | 16 |  Stan WawrinkaClay | 57 | Albert Ramos-VinolasClay | 1-6 6-3 6-4 | 3 | 105 | 4 | 3 | 56.6% | 79.1% | 51.5% | 4/6 |
| QF | 4 | David FerrerClay | 54 | Victor HanescuClay | 6-4 7-6(2) | 3 | 99 | 1 | 2 | 67.5% | 69.2% | 56.0% | 2/4 |
| QF | 18 | Andreas SeppiClay | 38 | Tommy RobredoClay | 6-4 6-3 | 3 | 81 | 0 | 2 | 63.2% | 77.8% | 47.6% | 2/3 |
| QF | 228 | Pablo Carreno BustaClay | 25 | Fabio FogniniClay | 3-6 6-4 6-4 | 3 | 132 | 2 | 1 | 51.4% | 70.2% | 44.4% | 8/11 |
| QF | 16 | Stan WawrinkaClay | 113 | Gastao EliasClay | 6-4 6-4 | 3 | 71 | 2 | 1 | 67.3% | 71.4% | 82.4% | 0/1 |
| SF | 4 | David FerrerClay | 18 | Andreas SeppiClay | 6-1 6-4 | 3 | 70 | 4 | 0 | 63.5% | 72.7% | 57.9% | 0/1 |
| SF | 16 | Stan WawrinkaClay | 228 | Pablo Carreno BustaClay | 6-3 3-6 6-1 | 3 | 95 | 10 | 1 | 71.3% | 71.9% | 60.9% | 2/3 |
| F | 16 | Stan WawrinkaClay | 4 | David FerrerClay | 6-1 6-4 | 3 | 64 | 2 | 1 | 64.3% | 88.9% | 80.0% | 0/0 |
