| R32 | 53 |  Jeremy ChardyClay | 59 | Adrian MannarinoClay | 6-4 6-3 | 3 | 91 | 8 | 4 | 54.0% | 76.5% | 37.9% | 5/7 |
| R32 | 135 |  Alejandro FallaClay | 48 |  Pablo AndujarClay | 4-6 6-1 4-4 RET | 3 | 122 | 2 | 0 | 60.0% | 69.2% | 84.6% | 2/4 |
| R32 | 46 |  Juan Martin del PotroClay | 488 |  Pedro SousaClay | 6-2 3-6 6-3 | 3 | 112 | 4 | 2 | 63.5% | 72.3% | 51.9% | 1/3 |
| R32 | 61 |  Pablo CuevasClay | 75 | Pere RibaClay | 6-2 6-4 | 3 | 68 | 4 | 1 | 65.9% | 93.1% | 60.0% | 0/0 |
| R32 | 129 | Edouard Roger-VasselinClay | 147 |  Marcos DanielClay | 6-3 6-1 | 3 | 82 | 3 | 2 | 64.6% | 71.0% | 52.9% | 2/4 |
| R32 | 31 | Thomaz BellucciClay | 213 |  Frederik NielsenClay | 7-5 6-1 | 3 | 77 | 4 | 0 | 54.9% | 71.4% | 69.6% | 1/2 |
| R32 | 27 |  Milos RaonicClay | 97 |  Igor AndreevClay | 6-4 6-4 | 3 | 85 | 4 | 5 | 62.0% | 75.0% | 55.6% | 8/8 |
| R32 | 254 | Joao SousaClay | 270 | Gastao EliasClay | 7-6(6) 3-6 5-2 RET | 3 | 153 | 5 | 0 | 65.2% | 65.0% | 46.9% | 3/7 |
| R32 | 72 | Carlos BerlocqClay | 60 | Daniel Gimeno-TraverClay | 6-4 6-3 | 3 | 76 | 0 | 0 | 78.4% | 72.5% | 90.9% | 1/2 |
| R32 | 34 |  Kevin AndersonClay | 81 |  Thiemo de BakkerClay | 5-7 6-3 6-2 | 3 | 146 | 2 | 0 | 71.6% | 67.2% | 69.6% | 4/7 |
| R32 | 63 |  Victor HanescuClay | 102 | Rui MachadoClay | 6-3 6-3 | 3 | 82 | 4 | 1 | 76.2% | 75.0% | 46.7% | 1/1 |
| R32 | 62 | Fred GilClay | 159 |  Flavio CipollaClay | 6-3 6-2 | 3 | 87 | 1 | 4 | 61.3% | 73.7% | 41.7% | 1/3 |
| R16 | 5 |  Robin SoderlingClay | 53 | Jeremy ChardyClay | 6-1 6-7(4) 6-1 | 3 | 118 | 5 | 2 | 58.3% | 69.4% | 57.1% | 2/5 |
| R16 | 46 | Juan Martin del PotroClay | 135 | Alejandro FallaClay | 6-2 6-1 | 3 | 71 | 3 | 0 | 60.5% | 87.0% | 80.0% | 0/0 |
| R16 | 61 | Pablo CuevasClay | 18 | Jo-Wilfried TsongaClay | 6-2 7-6(0) | 3 | 78 | 3 | 1 | 65.4% | 85.3% | 72.2% | 0/1 |
| R16 | 31 | Thomaz BellucciClay | 129 | Edouard Roger-VasselinClay | 6-3 5-7 7-5 | 3 | 178 | 6 | 3 | 62.8% | 69.0% | 50.0% | 6/9 |
| R16 | 27 | Milos RaonicClay | 254 | Joao SousaClay | 6-3 6-3 | 3 | 71 | 6 | 2 | 65.9% | 69.0% | 73.3% | 1/3 |
| R16 | 22 | Gilles SimonClay | 72 | Carlos BerlocqClay | 6-2 6-1 | 3 | 84 | 1 | 3 | 69.0% | 75.0% | 55.6% | 5/5 |
| R16 | 34 | Kevin AndersonClay | 63 | Victor HanescuClay | 6-4 6-2 | 3 | 84 | 4 | 0 | 62.3% | 78.8% | 55.0% | 0/0 |
| R16 | 15 | Fernando VerdascoClay | 62 | Fred GilClay | 6-1 7-6(5) | 3 | 103 | 2 | 7 | 65.1% | 73.2% | 45.5% | 3/5 |
| QF | 46 | Juan Martin del PotroClay | 5 | Robin SoderlingClay | 6-4 7-5 | 3 | 117 | 6 | 4 | 60.5% | 73.5% | 50.0% | 5/6 |
| QF | 61 | Pablo CuevasClay | 31 | Thomaz BellucciClay | 6-4 6-2 | 3 | 80 | 5 | 1 | 55.8% | 82.8% | 60.9% | 2/2 |
| QF | 27 | Milos RaonicClay | 22 | Gilles SimonClay | 7-6(4) 4-6 6-3 | 3 | 151 | 7 | 1 | 64.2% | 70.0% | 41.0% | 3/8 |
| QF | 15 | Fernando VerdascoClay | 34 | Kevin AndersonClay | 6-7(2) 6-2 6-3 | 3 | 156 | 3 | 1 | 83.8% | 72.3% | 43.8% | 4/5 |
| SF | 46 | Juan Martin del PotroClay | 61 | Pablo CuevasClay | 6-2 7-6(6) | 3 | 109 | 4 | 0 | 61.7% | 83.8% | 60.9% | 0/0 |
| SF | 15 | Fernando VerdascoClay | 27 | Milos RaonicClay | 6-4 RET | 3 | 42 | 0 | 0 | 84.6% | 81.8% | 50.0% | 0/0 |
| F | 46 | Juan Martin del PotroClay | 15 | Fernando VerdascoClay | 6-2 6-2 | 3 | 76 | 2 | 2 | 72.9% | 74.3% | 53.8% | 2/3 |
