| R32 | 123 |  Olivier PatienceClay | 4 |  Nikolay DavydenkoClay | 7-5 6-1 | 3 | 78 | 3 | 2 | 65.8% | 64.0% | 46.2% | 9/11 |
| R32 | 76 |  Vincent SpadeaClay | 73 |  Teymuraz GabashviliClay | 6-1 5-7 6-4 | 3 | 120 | 0 | 3 | 62.5% | 53.3% | 66.7% | 9/13 |
| R32 | 142 |  Fred GilClay | 55 |  Ruben Ramirez HidalgoClay | 6-1 4-6 6-3 | 3 | 126 | 1 | 1 | 63.2% | 68.8% | 50.0% | 0/3 |
| R32 | 15 | Richard GasquetClay | 47 |  Max MirnyiClay | 6-3 6-3 | 3 | 76 | 2 | 3 | 66.7% | 85.3% | 47.1% | 1/2 |
| R32 | 42 | Paul-Henri MathieuClay | 6 |  Fernando GonzalezClay | 6-2 6-4 | 3 | 83 | 0 | 4 | 57.1% | 65.6% | 58.3% | 2/4 |
| R32 | 91 | Igor KunitsynClay | 970 | Pedro SousaClay | 6-1 6-1 | 3 | 50 | 1 | 2 | 70.3% | 84.6% | 63.6% | 0/0 |
| R32 | 68 | Sam QuerreyClay | 84 |  Luis HornaClay | 7-6(5) 6-4 | 3 | 95 | 10 | 7 | 47.0% | 80.6% | 48.6% | 2/5 |
| R32 | 52 |  Juan MonacoClay | 45 | Gael MonfilsClay | 7-5 1-6 6-2 | 3 | 107 | 0 | 2 | 61.3% | 57.1% | 61.3% | 4/9 |
| R32 | 24 | Dmitry TursunovClay | 74 | Florent SerraClay | 4-6 6-3 6-1 | 3 | 84 | 8 | 2 | 51.3% | 76.9% | 59.5% | 1/2 |
| R32 | 62 | Guillermo Garcia-LopezClay | 66 | Michael RussellClay | 6-1 6-2 | 3 | 67 | 0 | 1 | 57.5% | 82.6% | 47.1% | 0/1 |
| R32 | 232 | Santiago VenturaClay | 79 | Sergio RoitmanClay | 7-5 6-2 | 3 | 73 | 2 | 1 | 55.1% | 85.2% | 63.6% | 0/1 |
| R32 | 5 |  Novak DjokovicClay | 177 | Igor AndreevClay | 6-2 4-6 7-6(5) | 3 | 163 | 2 | 3 | 65.7% | 69.2% | 64.7% | 2/4 |
| R32 | 28 | Agustin CalleriClay | 95 |  Danai UdomchokeClay | 6-4 4-6 6-1 | 3 | 105 | 5 | 1 | 36.0% | 74.2% | 60.0% | 4/6 |
| R32 | 63 | Juan Martin del PotroClay | 114 |  Alejandro FallaClay | 1-6 6-2 6-4 | 3 | 107 | 4 | 1 | 71.4% | 61.8% | 59.1% | 6/9 |
| R32 | 93 | Alberto MartinClay | 70 |  Evgeny KorolevClay | 6-1 2-0 RET | 3 | 40 | 2 | 2 | 51.3% | 65.0% | 57.9% | 3/4 |
| R32 | 7 | Tommy RobredoClay | 57 | Albert MontanesClay | 6-4 6-3 | 3 | 78 | 4 | 2 | 74.1% | 77.5% | 50.0% | 5/6 |
| R16 | 76 | Vincent SpadeaClay | 123 | Olivier PatienceClay | 2-6 6-3 6-4 | 3 | 117 | 1 | 0 | 58.6% | 64.7% | 55.6% | 7/11 |
| R16 | 15 | Richard GasquetClay | 142 | Fred GilClay | 6-1 6-2 | 3 | 65 | 2 | 0 | 65.1% | 78.6% | 73.3% | 0/0 |
| R16 | 42 | Paul-Henri MathieuClay | 91 | Igor KunitsynClay | 6-2 6-1 | 3 | 70 | 1 | 1 | 54.3% | 76.0% | 61.9% | 0/1 |
| R16 | 52 | Juan MonacoClay | 68 | Sam QuerreyClay | 3-6 6-1 6-4 | 3 | 91 | 3 | 4 | 62.2% | 78.3% | 53.6% | 5/7 |
| R16 | 62 | Guillermo Garcia-LopezClay | 24 | Dmitry TursunovClay | 6-4 6-3 | 3 | 68 | 3 | 1 | 63.2% | 66.7% | 76.2% | 4/4 |
| R16 | 5 | Novak DjokovicClay | 232 | Santiago VenturaClay | 6-2 6-2 | 3 | 56 | 3 | 2 | 72.7% | 78.1% | 41.7% | 0/1 |
| R16 | 28 | Agustin CalleriClay | 63 | Juan Martin del PotroClay | 7-5 1-0 RET | 3 | 61 | 1 | 2 | 50.0% | 65.0% | 50.0% | 3/5 |
| R16 | 7 | Tommy RobredoClay | 93 | Alberto MartinClay | 6-7(4) 7-5 6-2 | 3 | 147 | 3 | 2 | 71.3% | 68.8% | 51.6% | 6/9 |
| QF | 15 | Richard GasquetClay | 76 | Vincent SpadeaClay | 6-3 6-4 | 3 | 81 | 2 | 0 | 64.7% | 69.7% | 66.7% | 0/2 |
| QF | 42 | Paul-Henri MathieuClay | 52 | Juan MonacoClay | 6-4 4-6 6-1 | 3 | 132 | 1 | 3 | 53.1% | 62.8% | 44.7% | 2/8 |
| QF | 5 | Novak DjokovicClay | 62 | Guillermo Garcia-LopezClay | 6-4 1-6 7-5 | 3 | 163 | 5 | 4 | 56.0% | 57.4% | 50.0% | 6/12 |
| QF | 7 | Tommy RobredoClay | 28 | Agustin CalleriClay | 7-5 6-7(5) 6-3 | 3 | 150 | 1 | 1 | 82.8% | 61.4% | 52.4% | 10/14 |
| SF | 15 | Richard GasquetClay | 42 | Paul-Henri MathieuClay | 3-1 RET | 3 | 17 | 0 | 0 | 71.4% | 50.0% | 50.0% | 1/2 |
| SF | 5 | Novak DjokovicClay | 7 | Tommy RobredoClay | 7-5 6-1 | 3 | 79 | 1 | 4 | 55.2% | 75.0% | 57.7% | 1/2 |
| F | 5 | Novak DjokovicClay | 15 | Richard GasquetClay | 7-6(7) 0-6 6-1 | 3 | 131 | 3 | 4 | 62.5% | 65.0% | 38.9% | 7/12 |
