| R32 | 4 |  David NalbandianClay | 78 |  Nicolas MahutClay | 7-5 7-5 | 3 | 110 | 1 | 3 | 53.9% | 68.3% | 51.4% | 3/6 |
| R32 | 522 | Jeremy ChardyClay | 87 |  Jimmy WangClay | 7-5 6-1 | 3 | 102 | 5 | 6 | 56.3% | 70.4% | 35.7% | 9/11 |
| R32 | 246 |  Fred GilClay | 596 |  David Luque-VelascoClay | 1-6 7-6(5) 6-4 | 3 | 154 | 4 | 4 | 56.8% | 68.0% | 63.2% | 3/6 |
| R32 | 33 |  Dmitry TursunovClay | - | Gastao EliasClay | 6-2 6-1 | 3 | 53 | 4 | 1 | 60.5% | 76.9% | 64.7% | 0/0 |
| R32 | 35 | Gael MonfilsClay | 99 |  Razvan SabauClay | 6-1 6-2 | 3 | 39 | 8 | 0 | 68.6% | 75.0% | 72.7% | 0/1 |
| R32 | 100 | Albert PortasClay | 118 |  Juan Antonio MarinClay | 6-3 6-4 | 3 | 85 | 1 | 3 | 70.2% | 70.0% | 41.2% | 3/5 |
| R32 | 97 |  Justin GimelstobClay | 81 |  Lukas DlouhyClay | 3-6 7-5 6-3 | 3 | 131 | 5 | 5 | 50.5% | 63.8% | 60.9% | 4/7 |
| R32 | 32 |  Nicolas MassuClay | 108 |  Raemon SluiterClay | 6-0 7-5 | 3 | 84 | 5 | 1 | 76.1% | 77.1% | 54.5% | 1/3 |
| R32 | 39 | Carlos MoyaClay | 89 |  Flavio SarettaClay | 6-3 6-4 | 3 | 105 | 4 | 0 | 47.5% | 79.3% | 65.6% | 4/4 |
| R32 | 406 | Gustavo MarcaccioClay | 107 | Tomas ZibClay | 6-4 6-2 | 3 | 82 | 2 | 0 | 67.2% | 65.9% | 55.0% | 4/5 |
| R32 | 117 | Guillermo Garcia-LopezClay | 333 |  Leonardo AzzaroClay | 6-4 4-6 6-4 | 3 | 141 | 6 | 6 | 52.1% | 63.3% | 57.8% | 3/7 |
| R32 | 82 | Carlos BerlocqClay | 578 | Didac PerezClay | 6-0 6-1 | 3 | 55 | 2 | 0 | 76.7% | 69.7% | 70.0% | 3/3 |
| R32 | 71 |  Gilles MullerClay | 38 |  Christophe RochusClay | 6-2 6-0 | 3 | 45 | 10 | 0 | 76.3% | 75.9% | 77.8% | 3/3 |
| R32 | 126 |  Nicolas LapenttiClay | 319 |  Michal PrzysieznyClay | 6-7(3) 6-4 6-4 | 3 | 188 | 4 | 4 | 61.5% | 72.0% | 55.3% | 7/8 |
| R32 | 49 | Marat SafinClay | 313 | Fabio FogniniClay | 6-1 6-4 | 3 | 71 | 2 | 1 | 53.7% | 62.1% | 64.0% | 3/4 |
| R32 | 6 | Nikolay DavydenkoClay | 74 | Vincent SpadeaClay | 7-6(3) 6-3 | 3 | 95 | 2 | 4 | 65.3% | 65.3% | 61.5% | 1/3 |
| R16 | 4 | David NalbandianClay | 522 | Jeremy ChardyClay | 6-1 7-6(0) | 3 | 75 | 2 | 6 | 53.1% | 79.4% | 56.7% | 7/9 |
| R16 | 246 | Fred GilClay | 33 | Dmitry TursunovClay | 4-6 6-4 6-1 | 3 | 139 | 2 | 1 | 70.4% | 63.8% | 51.7% | 9/12 |
| R16 | 100 | Albert PortasClay | 35 | Gael MonfilsClay | 3-6 7-6(3) 6-4 | 3 | 148 | 1 | 2 | 50.0% | 67.9% | 43.4% | 6/11 |
| R16 | 97 | Justin GimelstobClay | 32 | Nicolas MassuClay | 2-6 7-6(3) 6-4 | 3 | 157 | 9 | 4 | 53.9% | 72.7% | 48.9% | 5/8 |
| R16 | 39 | Carlos MoyaClay | 406 | Gustavo MarcaccioClay | 6-1 7-5 | 3 | 94 | 17 | 1 | 58.0% | 75.0% | 51.7% | 5/6 |
| R16 | 117 | Guillermo Garcia-LopezClay | 82 | Carlos BerlocqClay | 6-7(11) 7-5 7-6(5) | 3 | 206 | 0 | 5 | 61.9% | 60.3% | 56.3% | 1/6 |
| R16 | 71 | Gilles MullerClay | 126 | Nicolas LapenttiClay | 6-1 6-4 | 3 | 93 | 5 | 2 | 55.4% | 77.8% | 51.7% | 3/3 |
| R16 | 6 | Nikolay DavydenkoClay | 49 | Marat SafinClay | 4-6 6-1 6-2 | 3 | 108 | 1 | 2 | 64.6% | 74.5% | 46.4% | 4/6 |
| QF | 4 | David NalbandianClay | 246 | Fred GilClay | 6-1 6-2 | 3 | 76 | 2 | 2 | 52.4% | 77.3% | 70.0% | 2/2 |
| QF | 39 | Carlos MoyaClay | 117 | Guillermo Garcia-LopezClay | 7-6(4) 6-4 | 3 | 104 | 3 | 1 | 56.3% | 77.5% | 58.1% | 1/3 |
| QF | 6 | Nikolay DavydenkoClay | 71 | Gilles MullerClay | 6-4 6-4 | 3 | 91 | 1 | 2 | 70.1% | 68.1% | 70.0% | 4/4 |
| SF | 4 | David NalbandianClay | 100 | Albert PortasClay | 7-5 6-1 | 3 | 78 | 4 | 0 | 57.7% | 73.3% | 72.7% | 1/2 |
| SF | 6 | Nikolay DavydenkoClay | 39 | Carlos MoyaClay | 3-6 6-2 6-2 | 3 | 109 | 1 | 1 | 70.9% | 62.5% | 56.5% | 2/5 |
| F | 4 | David NalbandianClay | 6 | Nikolay DavydenkoClay | 6-3 6-4 | 3 | 79 | 2 | 4 | 62.3% | 68.4% | 65.2% | 1/2 |
| QF | 100 | Albert PortasClay | 97 | Justin GimelstobClay | 6-4 6-3 | 3 | 82 | 2 | 1 | 68.0% | 73.5% | 50.0% | 3/5 |
