| R32 | 9 |  Carlos MoyaClay | 78 | Felix MantillaClay | 6-0 7-6(5) | 3 | 100 | 3 | 1 | 57.4% | 71.4% | 53.8% | 3/4 |
| R32 | 42 | Juan Carlos FerreroClay | 93 |  Marcos BaghdatisClay | 6-3 2-6 7-6(6) | 3 | 123 | 0 | 3 | 62.2% | 74.5% | 54.8% | 2/4 |
| R32 | 234 |  Tomas CaklClay | 56 |  Kenneth CarlsenClay | 6-3 6-0 | 3 | 70 | 0 | 4 | 54.4% | 67.7% | 61.5% | 4/4 |
| R32 | 73 |  Paul-Henri MathieuClay | 23 | Jiri NovakClay | 7-6(5) 6-1 | 3 | 92 | 2 | 2 | 46.4% | 59.4% | 51.4% | 4/7 |
| R32 | 15 | Tommy RobredoClay | 406 | Frantisek CermakClay | 6-2 2-6 6-4 | 3 | 123 | 0 | 3 | 56.1% | 76.1% | 36.1% | 3/7 |
| R32 | 71 | Santiago VenturaClay | 67 |  Gilles MullerClay | 3-6 6-1 6-2 | 3 | 82 | 7 | 2 | 53.8% | 85.7% | 56.7% | 3/4 |
| R32 | 81 |  Davide SanguinettiClay | 374 | Frank CondorClay | 6-0 6-2 | 3 | 47 | 3 | 0 | 55.3% | 76.2% | 70.6% | 0/0 |
| R32 | 51 | Albert CostaClay | 21 |  Nicolas MassuClay | 3-6 6-3 6-3 | 3 | 169 | 2 | 3 | 64.8% | 73.5% | 40.5% | 15/16 |
| R32 | 226 |  Juan Antonio MarinClay | 45 |  Juan Ignacio ChelaClay | 6-1 6-2 | 3 | 95 | 0 | 2 | 41.9% | 69.2% | 47.2% | 2/4 |
| R32 | 94 | Agustin CalleriClay | 318 |  Rui MachadoClay | 4-6 6-3 6-1 | 3 | 108 | 1 | 4 | 43.8% | 80.0% | 42.2% | 4/8 |
| R32 | 80 | Guillermo Garcia-LopezClay | 64 |  Ivo KarlovicClay | 6-3 6-3 | 3 | 62 | 0 | 0 | 64.1% | 96.0% | 85.7% | 0/0 |
| R32 | 12 |  Joachim JohanssonClay | 83 | Alex CalatravaClay | 7-6(1) 6-4 | 3 | 105 | 9 | 6 | 48.7% | 78.9% | 62.5% | 5/5 |
| R32 | 27 | Feliciano LopezClay | 153 | Alex CorretjaClay | 6-7(1) 7-6(4) 6-4 | 3 | 166 | 15 | 3 | 57.9% | 70.0% | 49.0% | 4/7 |
| R32 | 74 | Albert MontanesClay | 249 | Galo BlancoClay | 7-6(5) 6-4 | 3 | 110 | 4 | 1 | 63.6% | 71.4% | 50.0% | 9/11 |
| R32 | 96 | Michal TabaraClay | 47 | Tomas BerdychClay | 1-6 6-4 6-1 | 3 | 101 | 2 | 7 | 51.4% | 63.9% | 38.2% | 4/9 |
| R32 | 5 | Gaston GaudioClay | 76 | Jan HernychClay | 6-7(5) 7-5 6-0 | 3 | 144 | 2 | 3 | 47.7% | 54.7% | 62.1% | 5/9 |
| R16 | 9 | Carlos MoyaClay | 42 | Juan Carlos FerreroClay | 7-5 6-7(4) 6-4 | 3 | 168 | 3 | 7 | 61.9% | 72.9% | 41.9% | 6/9 |
| R16 | 73 | Paul-Henri MathieuClay | 234 | Tomas CaklClay | 6-1 6-1 | 3 | 61 | 4 | 1 | 52.8% | 73.7% | 70.6% | 0/1 |
| R16 | 15 | Tommy RobredoClay | 71 | Santiago VenturaClay | 7-5 6-0 | 3 | 74 | 2 | 0 | 60.6% | 65.0% | 46.2% | 4/6 |
| R16 | 81 | Davide SanguinettiClay | 51 | Albert CostaClay | 5-7 6-3 6-4 | 3 | 141 | 5 | 3 | 51.6% | 79.2% | 46.7% | 6/10 |
| R16 | 226 | Juan Antonio MarinClay | 94 | Agustin CalleriClay | 6-4 3-1 RET | 3 | 75 | 1 | 1 | 59.5% | 64.0% | 52.9% | 4/6 |
| R16 | 80 | Guillermo Garcia-LopezClay | 12 | Joachim JohanssonClay | 6-2 6-4 | 3 | 75 | 0 | 1 | 75.4% | 76.1% | 53.3% | 3/3 |
| R16 | 27 | Feliciano LopezClay | 74 | Albert MontanesClay | 7-6(5) 4-6 6-4 | 3 | 116 | 7 | 5 | 62.8% | 78.0% | 45.7% | 5/8 |
| R16 | 5 | Gaston GaudioClay | 96 | Michal TabaraClay | 6-2 6-1 | 3 | 78 | 1 | 1 | 64.3% | 58.3% | 60.0% | 8/9 |
| QF | 9 | Carlos MoyaClay | 73 | Paul-Henri MathieuClay | 6-4 6-2 | 3 | 76 | 2 | 1 | 52.7% | 82.8% | 57.7% | 1/1 |
| QF | 15 | Tommy RobredoClay | 81 | Davide SanguinettiClay | 6-2 6-2 | 3 | 53 | 1 | 1 | 57.8% | 80.8% | 63.2% | 0/0 |
| QF | 80 | Guillermo Garcia-LopezClay | 226 | Juan Antonio MarinClay | 6-1 2-6 6-3 | 3 | 130 | 0 | 2 | 80.9% | 65.3% | 47.1% | 8/10 |
| QF | 5 | Gaston GaudioClay | 27 | Feliciano LopezClay | 6-2 6-2 | 3 | 62 | 1 | 3 | 62.2% | 82.1% | 64.7% | 1/1 |
| SF | 15 | Tommy RobredoClay | 9 | Carlos MoyaClay | 6-3 3-0 RET | 3 | 51 | 0 | 4 | 70.0% | 71.4% | 33.3% | 4/6 |
| SF | 5 | Gaston GaudioClay | 80 | Guillermo Garcia-LopezClay | 6-4 2-6 6-2 | 3 | 108 | 5 | 4 | 59.5% | 65.9% | 50.0% | 6/10 |
| F | 5 | Gaston GaudioClay | 15 | Tommy RobredoClay | 6-1 2-6 6-1 | 3 | 109 | 0 | 3 | 56.5% | 71.8% | 60.0% | 2/4 |
