| R32 | 13 |  Felix MantillaClay | 66 | Javier SanchezClay | 6-1 6-3 | 3 | 66 | 1 | 2 | 70.2% | 75.8% | 57.1% | 2/3 |
| R32 | 48 |  Andrea GaudenziClay | 56 | Galo BlancoClay | 7-6(4) 6-4 | 3 | 119 | 2 | 2 | 69.0% | 58.0% | 58.1% | 9/11 |
| R32 | 59 |  Slava DosedelClay | 78 |  Tomas NydahlClay | 6-1 3-0 RET | 3 | 48 | 0 | 2 | 62.5% | 60.0% | 50.0% | 5/6 |
| R32 | 55 | MARKarim AlamiClay | 35 | Francisco ClavetClay | 6-4 6-3 | 3 | 81 | 1 | 5 | 47.4% | 85.2% | 40.0% | 2/4 |
| R32 | 21 | Albert CostaClay | 82 | Jordi BurilloClay | 7-6(7) 6-0 | 3 | 67 | 4 | 1 | 60.7% | 75.7% | 58.3% | 1/2 |
| R32 | 95 | Jiri NovakClay | 45 | MARHicham AraziClay | 4-6 6-0 7-6(3) | 3 | 109 | 2 | 2 | 65.7% | 58.5% | 55.9% | 15/19 |
| R32 | 67 |  Fernando MeligeniClay | 187 |  Nuno MarquesClay | 6-3 6-0 | 3 | 67 | 1 | 1 | 69.4% | 76.5% | 46.7% | 1/1 |
| R32 | 30 |  Thomas MusterClay | 90 |  Dinu PescariuClay | 7-5 6-1 | 3 | 72 | 5 | 1 | 61.2% | 70.0% | 78.9% | 3/4 |
| R32 | 41 | Julian AlonsoClay | 25 |  Fabrice SantoroClay | 6-2 5-7 6-0 | 3 | 106 | 3 | 5 | 56.0% | 74.5% | 56.8% | 6/8 |
| R32 | 83 |  Juan Antonio MarinClay | 341 | Bernardo MotaClay | 6-0 7-6(5) | 3 | 82 | 1 | 1 | 65.0% | 74.4% | 47.6% | 1/3 |
| R32 | 53 |  Filip DewulfClay | 44 |  Richard FrombergClay | 7-6(4) 6-3 | 3 | 83 | 0 | 2 | 54.8% | 85.3% | 57.1% | 2/3 |
| R32 | 18 | Alberto BerasateguiClay | 203 | Joaquin Munoz-HernandezClay | 6-4 6-4 | 3 | 68 | 4 | 4 | 67.1% | 65.3% | 58.3% | 11/12 |
| R32 | 75 | Juan Albert Viloca-PuigClay | 37 | Albert PortasClay | 7-6(5) 6-3 | 3 | 103 | 3 | 0 | 56.0% | 69.0% | 54.5% | 8/10 |
| R32 | 54 | Carlos CostaClay | 121 | Alberto MartinClay | 6-3 6-3 | 3 | 65 | 2 | 3 | 73.3% | 66.7% | 58.3% | 0/2 |
| R32 | 58 |  Marc-Kevin GoellnerClay | 163 | Jose Imaz-RuizClay | 6-4 7-5 | 3 | 94 | 5 | 4 | 42.7% | 78.1% | 51.2% | 9/10 |
| R32 | 17 | Carlos MoyaClay | 51 | Bohdan UlihrachClay | 6-3 4-6 6-4 | 3 | 100 | 4 | 2 | 51.7% | 71.1% | 59.5% | 5/8 |
| R16 | 13 | Felix MantillaClay | 48 | Andrea GaudenziClay | 6-1 1-6 7-6(6) | 3 | 112 | 1 | 4 | 67.4% | 68.8% | 38.7% | 8/12 |
| R16 | 55 | MARKarim AlamiClay | 59 | Slava DosedelClay | 6-4 4-6 7-6(10) | 3 | 148 | 2 | 1 | 59.4% | 60.3% | 48.8% | 7/14 |
| R16 | 21 | Albert CostaClay | 95 | Jiri NovakClay | 6-3 6-4 | 3 | 57 | 1 | 1 | 70.9% | 74.4% | 50.0% | 4/5 |
| R16 | 30 | Thomas MusterClay | 67 | Fernando MeligeniClay | 7-5 6-3 | 3 | 94 | 2 | 4 | 63.2% | 76.7% | 52.0% | 5/7 |
| R16 | 83 | Juan Antonio MarinClay | 41 | Julian AlonsoClay | 6-2 6-4 | 3 | 70 | 1 | 0 | 67.8% | 67.5% | 57.9% | 5/6 |
| R16 | 18 | Alberto BerasateguiClay | 53 | Filip DewulfClay | 6-4 5-7 7-5 | 3 | 109 | 5 | 1 | 79.8% | 61.3% | 47.4% | 2/8 |
| R16 | 54 | Carlos CostaClay | 75 | Juan Albert Viloca-PuigClay | 6-2 3-6 6-2 | 3 | 183 | 3 | 3 | 60.0% | 66.7% | 44.4% | 10/13 |
| R16 | 17 | Carlos MoyaClay | 58 | Marc-Kevin GoellnerClay | 6-3 6-2 | 3 | 58 | 1 | 0 | 66.7% | 75.0% | 62.5% | 2/2 |
| QF | 55 | MARKarim AlamiClay | 13 | Felix MantillaClay | 3-6 7-5 6-1 | 3 | 108 | 3 | 3 | 61.8% | 70.9% | 47.1% | 4/7 |
| QF | 30 | Thomas MusterClay | 21 | Albert CostaClay | 6-4 6-4 | 3 | 84 | 1 | 4 | 50.8% | 80.6% | 36.7% | 4/7 |
| QF | 18 | Alberto BerasateguiClay | 83 | Juan Antonio MarinClay | 3-6 6-4 6-3 | 3 | 109 | 1 | 3 | 73.8% | 66.1% | 38.1% | 3/7 |
| QF | 17 | Carlos MoyaClay | 54 | Carlos CostaClay | 7-6(3) 6-7(5) 6-2 | 3 | 138 | 4 | 4 | 46.4% | 72.5% | 50.8% | 4/7 |
| SF | 30 | Thomas MusterClay | 55 | MARKarim AlamiClay | 3-6 6-2 6-4 | 3 | 111 | 3 | 1 | 77.1% | 52.7% | 54.5% | 8/13 |
| SF | 18 | Alberto BerasateguiClay | 17 | Carlos MoyaClay | 6-1 6-1 | 3 | 48 | 1 | 0 | 77.8% | 71.4% | 100.0% | 0/0 |
| F | 18 | Alberto BerasateguiClay | 30 | Thomas MusterClay | 3-6 6-1 6-3 | 3 | 87 | 3 | 4 | 73.7% | 60.7% | 55.0% | 2/6 |
