| R32 | 5 |  David FerrerClay | 160 |  Maximo GonzalezClay | 7-6(7) 6-4 | 3 | 124 | 1 | 1 | 63.2% | 72.9% | 42.9% | 2/5 |
| R32 | 48 | Carlos BerlocqClay | 49 |  Joao SousaClay | 6-4 6-2 | 3 | 86 | 1 | 0 | 71.7% | 63.2% | 80.0% | 1/2 |
| R32 | 108 | Guido PellaClay | 52 | Guillermo Garcia-LopezClay | 7-6(6) 6-4 | 3 | 105 | 2 | 1 | 69.0% | 81.6% | 50.0% | 4/5 |
| R32 | 17 | Tommy RobredoClay | 65 | Pablo Carreno BustaClay | 6-4 6-4 | 3 | 86 | 1 | 2 | 63.5% | 75.0% | 43.5% | 6/8 |
| R32 | 34 | Marcel GranollersClay | 103 | SLOAljaz BedeneClay | 7-5 3-6 6-2 | 3 | 169 | 2 | 2 | 66.2% | 59.2% | 60.0% | 0/4 |
| R32 | 43 | Pablo AndujarClay | 63 | Federico DelbonisClay | 3-6 7-5 6-1 | 3 | 135 | 2 | 3 | 69.6% | 68.8% | 60.7% | 11/13 |
| R32 | 58 | Leonardo MayerClay | 112 | Facundo ArguelloClay | 6-3 6-4 | 3 | 88 | 0 | 2 | 59.6% | 67.6% | 60.9% | 0/2 |
| R32 | 14 |  Fabio FogniniClay | 94 |  Julian ReisterClay | 7-5 6-2 | 3 | 86 | 1 | 3 | 64.0% | 62.5% | 40.7% | 13/17 |
| R32 | 57 |  Santiago GiraldoClay | 61 | Albert MontanesClay | 7-6(4) 6-2 | 3 | 110 | 4 | 0 | 47.6% | 82.1% | 48.8% | 8/8 |
| R32 | 77 | Filippo VolandriClay | 439 |  Cristian GarinClay | 5-7 6-0 6-3 | 3 | 114 | 2 | 1 | 78.4% | 61.8% | 42.9% | 6/10 |
| R32 | 92 | Albert Ramos-VinolasClay | 42 | Juan MonacoClay | 6-7(3) 6-4 6-2 | 3 | 140 | 4 | 0 | 70.7% | 63.1% | 70.4% | 2/4 |
| R32 | 18 | Nicolas AlmagroClay | 111 | Horacio ZeballosClay | 6-2 7-5 | 3 | 89 | 9 | 3 | 58.1% | 80.6% | 57.7% | 4/4 |
| R32 | 84 | Daniel Gimeno-TraverClay | 165 | Ruben Ramirez HidalgoClay | 7-5 6-2 | 3 | 99 | 8 | 2 | 52.5% | 77.4% | 53.6% | 1/2 |
| R32 | 53 |  Alexandr DolgopolovClay | 230 |  Pablo CuevasClay | 6-3 4-6 7-6(5) | 3 | 122 | 10 | 1 | 56.3% | 74.1% | 57.8% | 5/7 |
| R32 | 45 |  Jeremy ChardyClay | 78 | Alejandro GonzalezClay | 6-4 7-5 | 3 | 102 | 5 | 2 | 52.2% | 68.6% | 56.3% | 4/6 |
| R32 | 46 |  Robin HaaseClay | 131 | Martin AlundClay | 6-4 6-7(6) 6-3 | 3 | 145 | 4 | 2 | 54.2% | 80.8% | 56.8% | 2/3 |
| R16 | 5 | David FerrerClay | 57 | Santiago GiraldoClay | 6-4 7-6(1) | 3 | 112 | 1 | 1 | 73.4% | 56.9% | 52.4% | 6/10 |
| R16 | 92 | Albert Ramos-VinolasClay | 77 | Filippo VolandriClay | 6-2 6-1 | 3 | 59 | 3 | 0 | 76.2% | 75.0% | 60.0% | 2/3 |
| R16 | 18 | Nicolas AlmagroClay | 84 | Daniel Gimeno-TraverClay | 1-6 7-5 6-4 | 3 | 118 | 4 | 2 | 70.7% | 61.4% | 58.6% | 7/11 |
| R16 | 45 | Jeremy ChardyClay | 53 | Alexandr DolgopolovClay | 6-3 3-6 7-6(3) | 3 | 106 | 6 | 3 | 66.3% | 80.3% | 51.6% | 4/5 |
| R16 | 46 | Robin HaaseClay | 48 | Carlos BerlocqClay | 6-2 6-7(4) 6-2 | 3 | 128 | 4 | 2 | 65.9% | 80.4% | 62.1% | 4/4 |
| R16 | 17 | Tommy RobredoClay | 108 | Guido PellaClay | 4-6 6-1 6-4 | 3 | 94 | 12 | 3 | 57.5% | 88.1% | 61.3% | 1/2 |
| R16 | 43 | Pablo AndujarClay | 34 | Marcel GranollersClay | 6-3 6-0 | 3 | 74 | 1 | 4 | 61.0% | 80.0% | 43.8% | 2/3 |
| R16 | 14 | Fabio FogniniClay | 58 | Leonardo MayerClay | 6-7(4) 6-3 6-2 | 3 | 139 | 2 | 5 | 66.9% | 70.6% | 40.5% | 12/13 |
| QF | 5 | David FerrerClay | 92 | Albert Ramos-VinolasClay | 6-1 6-2 | 3 | 70 | 0 | 3 | 60.4% | 71.9% | 57.1% | 2/3 |
| QF | 18 | Nicolas AlmagroClay | 45 | Jeremy ChardyClay | 7-6(7) 6-3 | 3 | 104 | 4 | 1 | 64.3% | 68.5% | 56.7% | 5/8 |
| QF | 17 | Tommy RobredoClay | 46 | Robin HaaseClay | 6-1 2-0 RET | 3 | 41 | 1 | 0 | 72.2% | 92.3% | 80.0% | 0/0 |
| QF | 14 | Fabio FogniniClay | 43 | Pablo AndujarClay | 6-4 6-3 | 3 | 94 | 2 | 2 | 55.7% | 79.4% | 55.6% | 3/4 |
| SF | 5 | David FerrerClay | 18 | Nicolas AlmagroClay | 6-4 6-2 | 3 | 87 | 0 | 2 | 69.7% | 67.9% | 52.2% | 6/7 |
| SF | 14 | Fabio FogniniClay | 17 | Tommy RobredoClay | 3-6 7-5 6-3 | 3 | 119 | 2 | 3 | 64.4% | 67.9% | 45.2% | 2/6 |
| F | 5 | David FerrerClay | 14 | Fabio FogniniClay | 6-4 6-3 | 3 | 74 | 0 | 2 | 72.2% | 66.7% | 73.3% | 0/1 |
