| R32 | 10 |  David NalbandianClay | 109 |  Nicolas LapenttiClay | 6-3 6-3 | 3 | 73 | 3 | 1 | 48.8% | 81.0% | 72.7% | 0/1 |
| R32 | 87 |  Daniel Gimeno-TraverClay | 1094 | Gaston GaudioClay | 6-2 4-6 6-2 | 3 | 118 | 3 | 1 | 74.5% | 60.3% | 48.0% | 9/13 |
| R32 | 93 | Juan Carlos FerreroClay | 70 | Agustin CalleriClay | 6-3 6-4 | 3 | 78 | 1 | 0 | 77.4% | 75.6% | 91.7% | 0/0 |
| R32 | 44 | Marcel GranollersClay | 64 |  Thomaz BellucciClay | 7-5 7-5 | 3 | 117 | 2 | 4 | 50.0% | 74.4% | 51.3% | 4/7 |
| R32 | 108 | Maximo GonzalezClay | 49 | Carlos MoyaClay | 6-4 6-4 | 3 | 78 | 1 | 3 | 61.0% | 75.0% | 47.8% | 1/3 |
| R32 | 84 | Brian DabulClay | 63 |  Nicolas DevilderClay | 5-7 7-5 6-4 | 3 | 155 | 2 | 1 | 74.1% | 68.8% | 57.1% | 12/15 |
| R32 | 67 | Juan MonacoClay | 101 | Sergio RoitmanClay | 6-0 6-0 | 3 | 59 | 1 | 2 | 33.3% | 83.3% | 70.8% | 4/4 |
| R32 | 66 | Martin Vassallo ArguelloClay | 40 | Albert MontanesClay | 6-2 6-3 | 3 | 74 | 0 | 3 | 46.3% | 72.0% | 72.4% | 0/0 |
| R32 | 144 |  Pablo CuevasClay | 53 | Eduardo SchwankClay | 6-3 6-7(4) 6-0 | 3 | 152 | 8 | 4 | 60.5% | 79.6% | 62.5% | 2/4 |
| R32 | 192 | Franco FerreiroClay | 74 | Ivan NavarroClay | 1-6 6-4 6-2 | 3 | 126 | 1 | 8 | 59.6% | 69.6% | 42.1% | 5/8 |
| R32 | 136 | Juan Ignacio ChelaClay | 85 | Alberto MartinClay | 6-3 6-2 | 3 | 69 | 0 | 2 | 66.7% | 71.1% | 63.2% | 3/4 |
| R32 | 17 | Tommy RobredoClay | 65 |  Potito StaraceClay | 5-7 6-3 6-3 | 3 | 112 | 6 | 1 | 74.1% | 78.3% | 66.7% | 2/3 |
| R32 | 35 | Jose AcasusoClay | 182 | Daniel Munoz de la NavaClay | 6-2 7-6(4) | 3 | 110 | 5 | 3 | 57.4% | 61.5% | 58.6% | 2/5 |
| R32 | 113 | Fabio FogniniClay | 91 | Pablo AndujarClay | 6-3 6-2 | 3 | 77 | 4 | 6 | 58.6% | 79.4% | 41.7% | 8/9 |
| R32 | 75 | Diego JunqueiraClay | 82 |  Nicolas MassuClay | 3-6 6-4 6-4 | 3 | 165 | 3 | 3 | 63.6% | 60.7% | 62.5% | 2/6 |
| R32 | 77 | Oscar HernandezClay | 23 | Nicolas AlmagroClay | 6-2 1-6 6-3 | 3 | 112 | 2 | 2 | 72.2% | 66.7% | 59.1% | 3/5 |
| R16 | 10 | David NalbandianClay | 87 | Daniel Gimeno-TraverClay | 7-5 6-2 | 3 | 84 | 2 | 4 | 44.6% | 82.8% | 52.8% | 1/2 |
| R16 | 93 | Juan Carlos FerreroClay | 44 | Marcel GranollersClay | 6-7(7) 6-0 6-3 | 3 | 147 | 1 | 1 | 71.4% | 63.1% | 65.4% | 1/3 |
| R16 | 108 | Maximo GonzalezClay | 84 | Brian DabulClay | 6-3 6-1 | 3 | 65 | 2 | 2 | 53.8% | 90.5% | 72.2% | 0/0 |
| R16 | 67 | Juan MonacoClay | 66 | Martin Vassallo ArguelloClay | 6-4 2-6 6-2 | 3 | 134 | 1 | 4 | 58.2% | 74.4% | 57.1% | 0/3 |
| R16 | 192 | Franco FerreiroClay | 144 | Pablo CuevasClay | 6-2 6-4 | 3 | 84 | 0 | 4 | 59.7% | 70.0% | 63.0% | 6/6 |
| R16 | 17 | Tommy RobredoClay | 136 | Juan Ignacio ChelaClay | 6-2 3-6 6-4 | 3 | 121 | 3 | 3 | 54.1% | 67.5% | 55.9% | 6/10 |
| R16 | 35 | Jose AcasusoClay | 113 | Fabio FogniniClay | 6-4 6-3 | 3 | 108 | 2 | 2 | 53.1% | 67.6% | 70.0% | 2/2 |
| R16 | 77 | Oscar HernandezClay | 75 | Diego JunqueiraClay | 3-6 7-6(5) 6-0 | 3 | 139 | 1 | 2 | 72.9% | 64.3% | 30.8% | 5/10 |
| QF | 10 | David NalbandianClay | 93 | Juan Carlos FerreroClay | 6-3 3-0 RET | 3 | 57 | 2 | 0 | 51.3% | 70.0% | 57.9% | 2/3 |
| QF | 67 | Juan MonacoClay | 108 | Maximo GonzalezClay | 6-2 6-3 | 3 | 77 | 1 | 4 | 71.9% | 65.9% | 43.8% | 2/4 |
| QF | 17 | Tommy RobredoClay | 192 | Franco FerreiroClay | 6-4 7-6(4) | 3 | 111 | 0 | 2 | 67.1% | 62.3% | 53.8% | 5/8 |
| QF | 35 | Jose AcasusoClay | 77 | Oscar HernandezClay | 6-1 6-2 | 3 | 73 | 2 | 0 | 50.0% | 94.4% | 66.7% | 0/0 |
| SF | 67 | Juan MonacoClay | 10 | David NalbandianClay | 2-6 7-5 7-6(2) | 3 | 161 | 3 | 2 | 75.7% | 63.0% | 50.0% | 3/8 |
| SF | 17 | Tommy RobredoClay | 35 | Jose AcasusoClay | 6-4 7-6(3) | 3 | 122 | 2 | 1 | 81.6% | 66.3% | 55.6% | 9/10 |
| F | 17 | Tommy RobredoClay | 67 | Juan MonacoClay | 7-5 2-6 7-6(5) | 3 | 165 | 1 | 3 | 75.2% | 56.6% | 52.0% | 3/8 |
