| R32 | 55 |  Alberto MartinClay | 112 | Albert PortasClay | 6-2 7-5 | 3 | 91 | 3 | 1 | 48.2% | 88.9% | 55.2% | 3/4 |
| R32 | 57 |  Boris PashanskiClay | 168 |  Juan Pablo BrzezickiClay | 6-4 5-7 7-5 | 3 | 191 | 3 | 2 | 53.2% | 65.3% | 45.5% | 14/19 |
| R32 | 107 |  Tomas BehrendClay | 78 | Carlos BerlocqClay | 7-6(1) 6-4 | 3 | 112 | 3 | 3 | 53.3% | 70.0% | 45.7% | 2/5 |
| R32 | 33 |  Filippo VolandriClay | 100 | Fernando VicenteClay | 6-3 6-2 | 3 | 55 | 0 | 1 | 66.7% | 71.4% | 64.3% | 0/1 |
| R32 | 39 | Jose AcasusoClay | 66 | Albert MontanesClay | 6-1 6-3 | 3 | 61 | 5 | 0 | 55.6% | 92.0% | 45.0% | 0/0 |
| R32 | 204 | Martin Vassallo ArguelloClay | 149 |  Ricardo MelloClay | 6-3 6-3 | 3 | 82 | 5 | 1 | 69.2% | 80.6% | 56.3% | 0/0 |
| R32 | 103 |  Juan Antonio MarinClay | 110 |  Razvan SabauClay | 6-1 6-1 | 3 | 53 | 3 | 1 | 37.1% | 76.9% | 81.8% | 0/0 |
| R32 | 56 | Agustin CalleriClay | 37 |  Florent SerraClay | 6-0 6-4 | 3 | 61 | 6 | 0 | 44.7% | 82.4% | 76.2% | 0/1 |
| R32 | 46 | Juan Ignacio ChelaClay | 67 |  Luis HornaClay | 7-6(1) RET | 3 | 55 | 1 | 1 | 74.3% | 80.8% | 66.7% | 1/2 |
| R32 | 99 | Potito StaraceClay | 77 | Juan MonacoClay | 6-3 6-3 | 3 | 97 | 1 | 2 | 74.0% | 78.4% | 53.8% | 1/2 |
| R32 | 87 | Flavio SarettaClay | 185 | Gorka FraileClay | 6-0 4-6 6-3 | 3 | - | 3 | 0 | 65.2% | 67.4% | 56.5% | 5/8 |
| R32 | 18 | Juan Carlos FerreroClay | 155 | Juan Martin del PotroClay | 6-2 4-6 6-4 | 3 | 137 | 4 | 1 | 70.7% | 62.1% | 58.3% | 6/10 |
| R32 | 34 | Carlos MoyaClay | 312 | Fabio FogniniClay | 6-7(6) 6-4 6-4 | 3 | 143 | 2 | 2 | 68.6% | 68.1% | 54.5% | 1/3 |
| R32 | 54 |  Nicolas MassuClay | 91 | Marcos DanielClay | 6-3 5-7 6-1 | 3 | 134 | 4 | 1 | 51.9% | 67.5% | 62.2% | 3/6 |
| R32 | 93 | Ruben Ramirez HidalgoClay | 612 | Eric ProdonClay | 3-6 6-4 6-2 | 3 | 121 | 5 | 5 | 58.3% | 75.0% | 45.0% | 8/10 |
| R32 | 7 | Guillermo CoriaClay | 123 |  Jiri VanekClay | 6-1 2-6 7-6(2) | 3 | 163 | 2 | 9 | 67.6% | 59.4% | 42.4% | 6/12 |
| R16 | 57 | Boris PashanskiClay | 55 | Alberto MartinClay | 3-6 7-6(5) 6-3 | 3 | 148 | 5 | 4 | 61.9% | 68.5% | 44.4% | 8/12 |
| R16 | 33 | Filippo VolandriClay | 107 | Tomas BehrendClay | 3-6 7-6(5) 7-6(2) | 3 | 139 | 1 | 0 | 77.2% | 62.5% | 61.5% | 4/8 |
| R16 | 39 | Jose AcasusoClay | 204 | Martin Vassallo ArguelloClay | 6-3 6-1 | 3 | 64 | 4 | 2 | 56.4% | 90.9% | 58.8% | 1/2 |
| R16 | 56 | Agustin CalleriClay | 103 | Juan Antonio MarinClay | 6-4 6-2 | 3 | 87 | 9 | 2 | 63.6% | 92.9% | 68.8% | 0/0 |
| R16 | 99 | Potito StaraceClay | 46 | Juan Ignacio ChelaClay | 3-6 7-6(4) 6-2 | 3 | 157 | 3 | 1 | 77.3% | 76.0% | 36.4% | 5/6 |
| R16 | 18 | Juan Carlos FerreroClay | 87 | Flavio SarettaClay | 4-6 6-2 6-3 | 3 | 148 | 4 | 0 | 68.4% | 64.6% | 53.3% | 7/10 |
| R16 | 34 | Carlos MoyaClay | 54 | Nicolas MassuClay | 4-6 6-3 7-6(4) | 3 | 162 | 6 | 3 | 68.8% | 81.8% | 53.3% | 2/4 |
| R16 | 93 | Ruben Ramirez HidalgoClay | 7 | Guillermo CoriaClay | 7-5 6-2 | 3 | 94 | 5 | 4 | 56.9% | 73.2% | 38.7% | 6/9 |
| QF | 33 | Filippo VolandriClay | 57 | Boris PashanskiClay | 6-4 6-3 | 3 | 93 | 4 | 1 | 76.9% | 64.0% | 53.3% | 4/7 |
| QF | 56 | Agustin CalleriClay | 39 | Jose AcasusoClay | 6-3 3-6 6-4 | 3 | 133 | 3 | 1 | 59.3% | 74.5% | 42.9% | 3/7 |
| QF | 18 | Juan Carlos FerreroClay | 99 | Potito StaraceClay | 6-3 7-5 | 3 | 102 | 1 | 0 | 77.8% | 63.3% | 42.9% | 5/9 |
| QF | 34 | Carlos MoyaClay | 93 | Ruben Ramirez HidalgoClay | 6-2 6-2 | 3 | 66 | 7 | 2 | 57.1% | 87.5% | 37.5% | 4/5 |
| SF | 33 | Filippo VolandriClay | 56 | Agustin CalleriClay | 6-3 6-4 | 3 | 85 | 0 | 0 | 77.0% | 59.6% | 52.9% | 3/5 |
| SF | 34 | Carlos MoyaClay | 18 | Juan Carlos FerreroClay | 3-6 7-6(3) 6-4 | 3 | 155 | 6 | 4 | 59.0% | 77.4% | 48.8% | 4/6 |
| F | 34 | Carlos MoyaClay | 33 | Filippo VolandriClay | 7-6(6) 6-4 | 3 | 90 | 3 | 0 | 69.2% | 82.2% | 50.0% | 2/3 |
