| R32 | 98 |  Nicolas AlmagroClay | 85 | Santiago VenturaClay | 6-3 6-3 | 3 | 74 | 5 | 3 | 57.4% | 74.2% | 52.2% | 3/4 |
| R32 | 6 | Carlos MoyaClay | 154 |  Peter LuczakClay | 6-3 7-6(5) | 3 | 90 | 7 | 2 | 60.3% | 89.5% | 64.0% | 4/4 |
| R32 | 83 |  Juan MonacoClay | 54 | Albert CostaClay | 7-5 6-4 | 3 | 102 | 1 | 1 | 58.9% | 78.8% | 69.6% | 1/2 |
| R32 | 117 | Mariano PuertaClay | 156 | Juan-Pablo GuzmanClay | 6-2 7-6(2) | 3 | 86 | 3 | 2 | 69.4% | 76.7% | 47.4% | 1/2 |
| R32 | 95 |  Lars BurgsmullerClay | 40 |  Filippo VolandriClay | 6-4 6-2 | 3 | 84 | 7 | 0 | 53.4% | 67.7% | 44.4% | 6/9 |
| R32 | 91 | Guillermo Garcia-LopezClay | 78 | David SanchezClay | 6-4 6-3 | 3 | 85 | 0 | 4 | 70.2% | 67.5% | 35.3% | 3/6 |
| R32 | 57 | Jose AcasusoClay | 104 |  Paul-Henri MathieuClay | 6-3 6-2 | 3 | 59 | 8 | 1 | 54.2% | 76.9% | 54.5% | 1/2 |
| R32 | 50 | Mariano ZabaletaClay | 86 | Alex CalatravaClay | 6-3 6-2 | 3 | 68 | 6 | 2 | 70.2% | 72.5% | 52.9% | 5/6 |
| R32 | 141 | Marc LopezClay | 23 | Juan Ignacio ChelaClay | 7-5 6-1 | 3 | 95 | 0 | 0 | 70.6% | 63.9% | 53.3% | 1/3 |
| R32 | 119 | Felix MantillaClay | 84 | Oscar HernandezClay | 6-4 7-6(0) | 3 | 118 | 1 | 1 | 63.9% | 73.6% | 56.7% | 7/7 |
| R32 | 69 | Alberto MartinClay | 47 | David FerrerClay | 5-0 RET | 3 | 22 | 0 | 2 | 25.0% | 75.0% | 75.0% | 0/0 |
| R32 | 12 | Guillermo CanasClay | 127 | Alex CorretjaClay | 6-3 6-1 | 3 | 72 | 3 | 6 | 54.0% | 77.8% | 52.2% | 4/5 |
| R32 | 48 | Rafael NadalClay | 61 | Agustin CalleriClay | 7-6(2) 6-3 | 3 | 99 | 0 | 0 | 74.2% | 73.9% | 81.3% | 0/0 |
| R32 | 66 | Potito StaraceClay | 125 | Edgardo MassaClay | 7-6(5) 6-0 | 3 | 92 | 3 | 0 | 76.9% | 60.0% | 72.2% | 4/5 |
| R32 | 114 |  Flavio SarettaClay | 97 | Albert MontanesClay | 6-3 0-6 6-2 | 3 | 117 | 3 | 2 | 55.3% | 64.3% | 52.9% | 3/6 |
| R32 | 8 | Gaston GaudioClay | 202 | Federico LuzziClay | 2-6 6-1 6-3 | 3 | 114 | 4 | 1 | 71.4% | 63.6% | 45.5% | 3/6 |
| R16 | 6 | Carlos MoyaClay | 83 | Juan MonacoClay | 6-1 6-2 | 3 | 68 | 5 | 2 | 42.4% | 84.0% | 55.9% | 7/7 |
| R16 | 117 | Mariano PuertaClay | 95 | Lars BurgsmullerClay | 6-2 6-0 | 3 | 56 | 1 | 1 | 65.1% | 75.0% | 66.7% | 4/4 |
| R16 | 57 | Jose AcasusoClay | 91 | Guillermo Garcia-LopezClay | 6-4 6-3 | 3 | 78 | 2 | 0 | 55.3% | 88.5% | 66.7% | 1/1 |
| R16 | 98 | Nicolas AlmagroClay | 50 | Mariano ZabaletaClay | 6-7(4) 6-4 6-4 | 3 | 140 | 11 | 0 | 66.4% | 73.3% | 47.4% | 5/7 |
| R16 | 119 | Felix MantillaClay | 141 | Marc LopezClay | 4-6 7-6(5) 7-6(4) | 3 | 206 | 2 | 2 | 66.7% | 75.0% | 52.9% | 5/9 |
| R16 | 69 | Alberto MartinClay | 12 | Guillermo CanasClay | 6-4 6-3 | 3 | 98 | 1 | 2 | 67.1% | 67.3% | 58.3% | 8/9 |
| R16 | 48 | Rafael NadalClay | 66 | Potito StaraceClay | 6-1 6-3 | 3 | 76 | 1 | 1 | 69.8% | 86.7% | 38.5% | 2/3 |
| R16 | 8 | Gaston GaudioClay | 114 | Flavio SarettaClay | 6-3 6-2 | 3 | 82 | 2 | 1 | 61.7% | 70.3% | 56.5% | 2/3 |
| QF | 117 | Mariano PuertaClay | 6 | Carlos MoyaClay | 7-6(0) 6-3 | 3 | 87 | 4 | 0 | 80.0% | 79.2% | 75.0% | 2/2 |
| QF | 57 | Jose AcasusoClay | 98 | Nicolas AlmagroClay | 6-3 6-4 | 3 | 77 | 3 | 1 | 52.0% | 84.6% | 75.0% | 0/0 |
| QF | 69 | Alberto MartinClay | 119 | Felix MantillaClay | 5-7 6-4 7-6(3) | 3 | 152 | 8 | 1 | 47.1% | 77.6% | 60.0% | 5/8 |
| QF | 8 | Gaston GaudioClay | 48 | Rafael NadalClay | 0-6 6-0 6-1 | 3 | 103 | 6 | 1 | 56.9% | 59.5% | 60.7% | 6/9 |
| SF | 117 | Mariano PuertaClay | 57 | Jose AcasusoClay | 6-4 7-6(5) | 3 | 100 | 6 | 1 | 71.4% | 76.0% | 60.0% | 1/2 |
| SF | 8 | Gaston GaudioClay | 69 | Alberto MartinClay | 6-3 6-4 | 3 | 94 | 1 | 5 | 54.8% | 82.4% | 46.4% | 0/1 |
| F | 8 | Gaston GaudioClay | 117 | Mariano PuertaClay | 6-4 6-4 | 3 | 92 | 4 | 1 | 64.5% | 75.0% | 63.6% | 0/0 |
