| R16 | 10 |  Janko TipsarevicClay | 76 |  Santiago GiraldoClay | 6-3 6-3 | 3 | 81 | 5 | 2 | 57.1% | 75.0% | 62.5% | 8/9 |
| R16 | 87 |  Guillermo Garcia-LopezClay | 98 |  Sergiy StakhovskyClay | 1-6 6-3 6-4 | 3 | 124 | 1 | 5 | 64.0% | 64.9% | 53.1% | 6/9 |
| R16 | 55 |  Victor HanescuClay | 30 |  Mikhail YouzhnyClay | 6-4 6-3 | 3 | 79 | 2 | 1 | 73.2% | 80.5% | 40.0% | 1/1 |
| R16 | 29 |  Florian MayerClay | 62 |  David GoffinClay | 7-6(2) 1-6 6-3 | 3 | 117 | 4 | 0 | 68.7% | 69.1% | 48.4% | 3/6 |
| R16 | 46 | Viktor TroickiClay | 78 | Tobias KamkeClay | 6-4 6-2 | 3 | 92 | 0 | 1 | 45.9% | 60.7% | 51.5% | 4/7 |
| R16 | 48 |  Lukas RosolClay | 18 |  Andreas SeppiClay | 6-1 3-6 6-3 | 3 | 104 | 5 | 2 | 51.9% | 83.3% | 48.7% | 8/10 |
| R16 | 67 | Daniel BrandsClay | 105 |  Gael MonfilsClay | 7-6(1) 2-0 RET | 3 | 59 | 5 | 2 | 66.0% | 68.6% | 61.1% | 7/8 |
| R16 | 16 | Gilles SimonClay | 39 |  Jarkko NieminenClay | 4-6 6-4 6-4 | 3 | 160 | 6 | 4 | 58.6% | 64.7% | 47.9% | 12/16 |
| QF | 87 | Guillermo Garcia-LopezClay | 10 | Janko TipsarevicClay | 6-3 3-6 6-4 | 3 | 157 | 8 | 4 | 65.7% | 66.2% | 58.8% | 6/9 |
| QF | 29 | Florian MayerClay | 55 | Victor HanescuClay | 6-3 7-6(3) | 3 | 89 | 2 | 1 | 69.2% | 73.3% | 75.0% | 2/3 |
| QF | 48 | Lukas RosolClay | 46 | Viktor TroickiClay | 6-3 6-1 | 3 | 77 | 4 | 1 | 57.8% | 78.4% | 51.9% | 10/10 |
| QF | 16 | Gilles SimonClay | 67 | Daniel BrandsClay | 6-1 7-5 | 3 | 78 | 6 | 0 | 57.1% | 78.1% | 58.3% | 0/1 |
| SF | 87 | Guillermo Garcia-LopezClay | 29 | Florian MayerClay | 6-4 4-6 6-3 | 3 | 130 | 3 | 2 | 58.5% | 71.0% | 43.2% | 9/13 |
| SF | 48 | Lukas RosolClay | 16 | Gilles SimonClay | 6-2 6-3 | 3 | 78 | 0 | 2 | 54.1% | 75.8% | 64.3% | 8/8 |
| F | 48 | Lukas RosolClay | 87 | Guillermo Garcia-LopezClay | 6-3 6-2 | 3 | 67 | 2 | 3 | 61.5% | 78.1% | 45.0% | 0/1 |
| R32 | 76 | Santiago GiraldoClay | 54 | Xavier MalisseClay | 6-1 6-2 | 3 | 51 | 1 | 1 | 61.0% | 84.0% | 56.3% | 0/0 |
| R32 | 105 | Gael MonfilsClay | 122 | Filippo VolandriClay | 6-4 6-2 | 3 | 66 | 4 | 1 | 67.3% | 69.7% | 50.0% | 2/4 |
| R32 | 67 | Daniel BrandsClay | 110 |  Tatsuma ItoClay | 6-3 6-4 | 3 | 65 | 9 | 2 | 53.7% | 82.8% | 64.0% | 0/1 |
| R32 | 39 | Jarkko NieminenClay | 77 | Evgeny DonskoyClay | 1-6 6-4 7-6(3) | 3 | 140 | 2 | 1 | 63.7% | 73.8% | 43.2% | 7/11 |
| R32 | 98 | Sergiy StakhovskyClay | 350 | Jaroslav PospisilClay | 6-2 6-2 | 3 | 76 | 3 | 0 | 68.0% | 73.5% | 68.8% | 2/2 |
| R32 | 87 | Guillermo Garcia-LopezClay | 40 |  Horacio ZeballosClay | 3-6 6-4 6-0 | 3 | 123 | 2 | 4 | 53.8% | 82.9% | 56.7% | 2/4 |
| R32 | 55 | Victor HanescuClay | 109 | Matthias BachingerClay | 6-4 6-3 | 3 | 85 | 2 | 1 | 74.1% | 72.5% | 50.0% | 0/1 |
| R32 | 62 | David GoffinClay | 134 | Adrian UngurClay | 6-3 6-1 | 3 | 56 | 3 | 1 | 64.4% | 89.7% | 50.0% | 1/1 |
| R32 | 29 | Florian MayerClay | 133 | Flavio CipollaClay | 6-0 7-6(1) | 3 | 85 | 4 | 0 | 68.8% | 61.4% | 70.0% | 4/6 |
| R32 | 46 | Viktor TroickiClay | 50 |  Marinko MatosevicClay | 7-6(5) 6-3 | 3 | 96 | 8 | 0 | 62.8% | 77.6% | 44.8% | 2/4 |
| R32 | 78 | Tobias KamkeClay | 75 | Paul-Henri MathieuClay | 6-1 6-3 | 3 | 65 | 2 | 0 | 65.9% | 79.3% | 66.7% | 1/1 |
| R32 | 48 | Lukas RosolClay | 68 |  Gilles MullerClay | 7-6(4) 6-2 | 3 | 77 | 2 | 2 | 75.0% | 88.1% | 57.1% | 0/0 |
