| R32 | 76 |  Oscar HernandezClay | 28 |  Victor HanescuClay | 7-6(5) 6-4 | 3 | 113 | 4 | 1 | 69.1% | 73.2% | 40.0% | 4/6 |
| R32 | 67 |  Maximo GonzalezClay | 83 |  Olivier RochusClay | 6-7(4) 6-1 6-4 | 3 | 164 | 7 | 2 | 63.1% | 67.1% | 51.2% | 10/12 |
| R32 | 68 |  Simon GreulClay | 95 | Steve DarcisClay | 7-5 6-3 | 3 | 104 | 1 | 4 | 55.4% | 71.7% | 48.6% | 4/5 |
| R32 | 57 |  Daniel KoellererClay | 227 |  Filippo VolandriClay | 2-6 7-5 6-3 | 3 | 169 | 2 | 1 | 65.0% | 53.7% | 50.0% | 11/17 |
| R32 | 37 | Juan MonacoClay | 160 |  Julio SilvaClay | 6-2 6-4 | 3 | 77 | 4 | 0 | 62.5% | 65.7% | 71.4% | 2/3 |
| R32 | 157 | Pere RibaClay | 102 |  Fred GilClay | 7-5 5-7 6-2 | 3 | 158 | 3 | 2 | 52.7% | 67.8% | 54.7% | 7/10 |
| R32 | 70 |  Peter LuczakClay | 90 |  Karol BeckClay | 7-5 7-6(6) | 3 | 148 | 7 | 3 | 58.7% | 68.9% | 46.5% | 6/8 |
| R32 | 59 |  Pablo CuevasClay | 646 | Andrei PavelClay | 6-3 7-6(2) | 3 | 80 | 8 | 1 | 71.4% | 80.0% | 61.1% | 2/3 |
| R32 | 125 | Ruben Ramirez HidalgoClay | 56 | Andreas SeppiClay | 6-4 6-4 | 3 | 124 | 1 | 3 | 62.3% | 69.8% | 46.2% | 7/9 |
| R32 | 546 | Marius CopilClay | 98 | Victor CrivoiClay | 6-3 6-2 | 3 | 75 | 3 | 2 | 49.1% | 75.0% | 62.1% | 2/2 |
| R32 | 78 | Alberto MartinClay | 86 |  Florent SerraClay | 4-6 6-0 6-4 | 3 | 137 | 5 | 1 | 53.0% | 71.7% | 48.9% | 6/8 |
| R32 | 112 | Santiago VenturaClay | 43 |  Igor AndreevClay | 6-4 6-1 | 3 | 64 | 4 | 0 | 63.0% | 75.9% | 70.6% | 2/3 |
| R32 | 53 | Albert MontanesClay | 91 | Potito StaraceClay | 6-4 6-2 | 3 | 76 | 4 | 0 | 69.0% | 72.5% | 61.1% | 6/7 |
| R32 | 79 | Marcel GranollersClay | 328 | Petru-Alexandru LuncanuClay | 6-2 6-7(3) 6-1 | 3 | 130 | 2 | 1 | 65.1% | 80.4% | 46.7% | 5/6 |
| R32 | 87 | Fabio FogniniClay | 108 | Daniel Gimeno-TraverClay | 1-6 6-4 6-3 | 3 | 121 | 2 | 4 | 61.0% | 68.1% | 40.0% | 3/7 |
| R32 | 30 | Nicolas AlmagroClay | 63 | Simone BolelliClay | 6-4 6-3 | 3 | 81 | 5 | 1 | 57.6% | 73.7% | 60.7% | 5/6 |
| R16 | 67 | Maximo GonzalezClay | 76 | Oscar HernandezClay | 7-5 3-6 6-1 | 3 | 139 | 1 | 2 | 69.8% | 71.7% | 57.7% | 4/6 |
| R16 | 68 | Simon GreulClay | 57 | Daniel KoellererClay | 6-1 6-4 | 3 | 80 | 11 | 4 | 45.8% | 77.8% | 53.1% | 11/12 |
| R16 | 37 | Juan MonacoClay | 157 | Pere RibaClay | 6-4 6-2 | 3 | 78 | 0 | 1 | 47.7% | 76.2% | 87.0% | 0/0 |
| R16 | 59 | Pablo CuevasClay | 70 | Peter LuczakClay | 7-5 6-4 | 3 | 119 | 7 | 2 | 54.7% | 70.7% | 55.9% | 7/9 |
| R16 | 125 | Ruben Ramirez HidalgoClay | 546 | Marius CopilClay | 6-3 6-7(3) 6-4 | 3 | 198 | 0 | 6 | 66.7% | 65.4% | 48.7% | 7/9 |
| R16 | 112 | Santiago VenturaClay | 78 | Alberto MartinClay | 4-5 RET | 3 | 49 | 2 | 1 | 58.1% | 72.0% | 38.9% | 2/3 |
| R16 | 53 | Albert MontanesClay | 79 | Marcel GranollersClay | 6-1 6-3 | 3 | 68 | 1 | 3 | 56.8% | 84.0% | 63.2% | 0/0 |
| R16 | 87 | Fabio FogniniClay | 30 | Nicolas AlmagroClay | 6-4 7-6(3) | 3 | 103 | 2 | 2 | 68.8% | 67.3% | 60.0% | 6/8 |
| QF | 68 | Simon GreulClay | 67 | Maximo GonzalezClay | 6-2 6-2 | 3 | 64 | 0 | 0 | 58.3% | 60.7% | 75.0% | 1/2 |
| QF | 37 | Juan MonacoClay | 59 | Pablo CuevasClay | 6-3 2-6 6-1 | 3 | 115 | 1 | 0 | 65.8% | 68.0% | 65.4% | 6/8 |
| QF | 112 | Santiago VenturaClay | 125 | Ruben Ramirez HidalgoClay | 6-2 6-3 | 3 | 91 | 5 | 1 | 64.8% | 71.4% | 42.1% | 3/5 |
| QF | 53 | Albert MontanesClay | 87 | Fabio FogniniClay | 6-1 6-1 | 3 | 57 | 2 | 0 | 70.0% | 78.6% | 83.3% | 2/2 |
| SF | 37 | Juan MonacoClay | 68 | Simon GreulClay | 6-4 6-3 | 3 | 91 | 3 | 2 | 72.1% | 69.4% | 47.4% | 4/5 |
| SF | 53 | Albert MontanesClay | 112 | Santiago VenturaClay | 4-6 6-4 6-1 | 3 | 111 | 1 | 3 | 65.5% | 76.4% | 48.3% | 3/6 |
| F | 53 | Albert MontanesClay | 37 | Juan MonacoClay | 7-6(2) 7-6(6) | 3 | 131 | 2 | 2 | 70.0% | 68.3% | 59.3% | 5/6 |
