| R32 | 12 |  Richard GasquetClay | 75 |  Oscar HernandezClay | 3-6 6-4 6-4 | 3 | 139 | 10 | 2 | 62.1% | 72.2% | 51.5% | 2/5 |
| R32 | 165 |  Victor CrivoiClay | 145 | Ruben Ramirez HidalgoClay | 3-6 6-3 6-4 | 3 | 151 | 4 | 3 | 58.6% | 63.8% | 58.5% | 12/15 |
| R32 | 183 | Adrian CruciatClay | 91 |  Filippo VolandriClay | 7-5 4-0 RET | 3 | 77 | 3 | 1 | 61.2% | 76.7% | 63.2% | 3/3 |
| R32 | 97 |  Teymuraz GabashviliClay | 48 |  Ernests GulbisClay | 6-2 2-6 6-4 | 3 | 113 | 2 | 7 | 68.1% | 76.6% | 33.3% | 8/10 |
| R32 | 18 | Nicolas AlmagroClay | 244 |  Somdev DevvarmanClay | 6-7(6) 6-2 7-5 | 3 | 146 | 11 | 4 | 54.1% | 80.0% | 51.0% | 4/6 |
| R32 | 64 | Guillermo Garcia-LopezClay | 99 |  Mischa ZverevClay | 6-4 3-6 6-0 | 3 | 110 | 1 | 7 | 67.5% | 64.8% | 50.0% | 7/10 |
| R32 | 94 | Pablo AndujarClay | 115 |  Brian DabulClay | 4-6 6-2 6-4 | 3 | 138 | 5 | 5 | 77.5% | 69.6% | 55.0% | 4/6 |
| R32 | 61 | Carlos MoyaClay | 117 | Alberto MartinClay | 6-4 6-7(4) 6-4 | 3 | 148 | 5 | 2 | 52.0% | 75.0% | 58.3% | 2/4 |
| R32 | 51 | Jose AcasusoClay | 95 | Diego JunqueiraClay | 6-2 6-4 | 3 | 106 | 4 | 1 | 60.7% | 75.7% | 58.3% | 2/3 |
| R32 | 112 | Martin Vassallo ArguelloClay | 50 | Victor HanescuClay | 4-6 7-5 6-4 | 3 | 141 | 4 | 4 | 76.0% | 64.4% | 52.2% | 2/6 |
| R32 | 87 | Denis GremelmayrClay | 73 | Jeremy ChardyClay | 6-1 5-7 6-4 | 3 | 125 | 4 | 3 | 60.2% | 73.2% | 48.6% | 6/9 |
| R32 | 71 | Ivan NavarroClay | 25 | Paul-Henri MathieuClay | 6-4 6-7(5) 6-3 | 3 | 156 | 14 | 7 | 59.6% | 77.4% | 45.2% | 3/4 |
| R32 | 74 | Potito StaraceClay | 52 | Marcel GranollersClay | 6-2 6-4 | 3 | 81 | 1 | 0 | 83.6% | 76.1% | 33.3% | 2/3 |
| R32 | 69 | Florent SerraClay | 60 | Nicolas DevilderClay | 3-6 7-6(6) 7-6(4) | 3 | 179 | 3 | 2 | 57.0% | 67.7% | 42.9% | 6/11 |
| R32 | 56 | Albert MontanesClay | 142 |  Hyung-Taik LeeClay | 6-1 7-6(4) | 3 | 75 | 3 | 1 | 51.7% | 80.6% | 65.5% | 1/2 |
| R32 | 17 | Gilles SimonClay | 82 |  Evgeny KorolevClay | 6-1 6-2 | 3 | 63 | 4 | 1 | 66.0% | 65.7% | 61.1% | 3/4 |
| R16 | 12 | Richard GasquetClay | 165 | Victor CrivoiClay | 6-3 6-2 | 3 | 65 | 3 | 1 | 56.1% | 87.0% | 55.6% | 1/2 |
| R16 | 97 | Teymuraz GabashviliClay | 183 | Adrian CruciatClay | 6-1 6-2 | 3 | 59 | 4 | 3 | 66.0% | 75.8% | 70.6% | 4/4 |
| R16 | 64 | Guillermo Garcia-LopezClay | 18 | Nicolas AlmagroClay | 6-4 7-5 | 3 | 98 | 2 | 1 | 68.3% | 78.0% | 68.4% | 3/3 |
| R16 | 61 | Carlos MoyaClay | 94 | Pablo AndujarClay | 6-3 7-6(6) | 3 | 98 | 3 | 2 | 75.4% | 71.2% | 58.8% | 0/1 |
| R16 | 51 | Jose AcasusoClay | 112 | Martin Vassallo ArguelloClay | 6-4 7-5 | 3 | 120 | 5 | 3 | 56.9% | 70.7% | 41.9% | 5/8 |
| R16 | 71 | Ivan NavarroClay | 87 | Denis GremelmayrClay | 6-3 1-0 RET | 3 | 55 | 1 | 1 | 66.7% | 75.0% | 70.0% | 3/3 |
| R16 | 69 | Florent SerraClay | 74 | Potito StaraceClay | 7-5 0-6 6-4 | 3 | 129 | 3 | 1 | 71.6% | 65.5% | 60.9% | 4/8 |
| R16 | 17 | Gilles SimonClay | 56 | Albert MontanesClay | 6-3 6-4 | 3 | 93 | 8 | 0 | 54.8% | 79.4% | 60.7% | 3/3 |
| QF | 12 | Richard GasquetClay | 97 | Teymuraz GabashviliClay | 6-7(6) 6-1 6-1 | 3 | 109 | 8 | 1 | 59.5% | 78.7% | 59.4% | 0/1 |
| QF | 61 | Carlos MoyaClay | 64 | Guillermo Garcia-LopezClay | 5-7 6-3 6-4 | 3 | 154 | 10 | 3 | 64.4% | 75.9% | 68.8% | 1/2 |
| QF | 51 | Jose AcasusoClay | 71 | Ivan NavarroClay | 6-4 6-4 | 3 | 101 | 2 | 2 | 70.7% | 73.2% | 70.6% | 2/2 |
| QF | 17 | Gilles SimonClay | 69 | Florent SerraClay | 6-2 6-3 | 3 | 73 | 0 | 1 | 46.0% | 65.2% | 44.4% | 2/5 |
| SF | 61 | Carlos MoyaClay | 12 | Richard GasquetClay | 6-2 6-4 | 3 | 78 | 3 | 2 | 66.7% | 84.4% | 68.8% | 2/2 |
| SF | 17 | Gilles SimonClay | 51 | Jose AcasusoClay | 4-6 7-6(4) 6-4 | 3 | 174 | 6 | 3 | 55.4% | 68.7% | 48.1% | 6/10 |
| F | 17 | Gilles SimonClay | 61 | Carlos MoyaClay | 6-3 6-4 | 3 | 90 | 0 | 3 | 48.5% | 93.8% | 47.1% | 6/6 |
