| R32 | 93 |  Simone BolelliClay | 26 |  Nicolas AlmagroClay | 4-6 5-1 RET | 3 | 62 | 3 | 1 | 71.7% | 75.8% | 61.5% | 3/4 |
| R32 | 164 |  Yuri SchukinClay | 73 |  Diego HartfieldClay | 7-6(5) 5-7 6-2 | 3 | 170 | 6 | 0 | 61.2% | 69.8% | 55.0% | 6/10 |
| R32 | 99 | Ivan NavarroClay | 95 |  Chris GuccioneClay | 6-4 7-6(4) | 3 | 82 | 7 | 0 | 83.3% | 70.9% | 54.5% | 2/4 |
| R32 | 77 | Carlos BerlocqClay | 44 |  Fabrice SantoroClay | 7-6(5) 6-1 | 3 | 94 | 0 | 1 | 82.8% | 64.6% | 60.0% | 1/4 |
| R32 | 75 | Andreas SeppiClay | 32 |  Jurgen MelzerClay | 4-6 7-5 6-4 | 3 | 150 | 3 | 8 | 57.9% | 59.1% | 47.9% | 10/16 |
| R32 | 230 |  Hugo ArmandoClay | 81 | Sergio RoitmanClay | 6-0 6-1 | 3 | 48 | 0 | 0 | 67.6% | 91.3% | 63.6% | 0/0 |
| R32 | 89 | Evgeny KorolevClay | 85 | Florent SerraClay | 4-6 6-5 RET | 3 | 97 | 1 | 4 | 37.7% | 65.2% | 60.5% | 2/5 |
| R32 | 42 | Gilles SimonClay | 87 | Guillermo Garcia-LopezClay | 7-6(3) 6-4 | 3 | 121 | 0 | 1 | 56.8% | 67.4% | 48.6% | 7/11 |
| R32 | 46 | Albert MontanesClay | 115 | Nicolas DevilderClay | 6-3 6-1 | 3 | 62 | 3 | 4 | 49.0% | 79.2% | 56.0% | 2/3 |
| R32 | 151 |  Victor HanescuClay | 55 |  Florian MayerClay | 7-6(1) 7-6(3) | 3 | 97 | 3 | 0 | 60.5% | 71.7% | 66.7% | 2/4 |
| R32 | 90 | Andrei PavelClay | 52 | Oscar HernandezClay | 7-5 7-5 | 3 | 106 | 3 | 2 | 59.7% | 75.0% | 59.3% | 1/3 |
| R32 | 31 | Potito StaraceClay | 80 |  Kristof VliegenClay | 3-6 7-5 6-2 | 3 | 126 | 3 | 1 | 76.1% | 61.4% | 68.2% | 5/8 |
| R32 | 38 |  Igor AndreevClay | 91 | Peter LuczakClay | 6-4 3-6 6-4 | 3 | 128 | 9 | 0 | 72.5% | 69.0% | 72.7% | 2/4 |
| R32 | 67 | Marc GicquelClay | 250 | Catalin-Ionut GardClay | 6-4 6-4 | 3 | 98 | 2 | 1 | 61.0% | 77.8% | 47.8% | 1/2 |
| R32 | 74 | Martin Vassallo ArguelloClay | 62 | Werner EschauerClay | 6-4 6-4 | 3 | 95 | 4 | 0 | 62.7% | 78.1% | 63.2% | 0/1 |
| R32 | 48 | Gael MonfilsClay | 28 | Filippo VolandriClay | 6-3 7-6(4) | 3 | 104 | 3 | 7 | 47.8% | 75.8% | 38.9% | 1/5 |
| R16 | 164 | Yuri SchukinClay | 93 | Simone BolelliClay | 6-4 6-3 | 3 | 82 | 4 | 2 | 69.0% | 75.0% | 44.4% | 5/6 |
| R16 | 77 | Carlos BerlocqClay | 99 | Ivan NavarroClay | 7-5 6-3 | 3 | 116 | 0 | 1 | 70.9% | 82.1% | 62.5% | 1/2 |
| R16 | 230 | Hugo ArmandoClay | 75 | Andreas SeppiClay | 6-0 6-3 | 3 | 67 | 1 | 1 | 64.4% | 82.8% | 62.5% | 1/1 |
| R16 | 42 | Gilles SimonClay | 89 | Evgeny KorolevClay | 6-4 6-2 | 3 | 85 | 1 | 2 | 57.8% | 70.3% | 51.9% | 4/6 |
| R16 | 151 | Victor HanescuClay | 46 | Albert MontanesClay | 6-3 6-2 | 3 | 72 | 5 | 0 | 76.7% | 76.1% | 50.0% | 3/3 |
| R16 | 31 | Potito StaraceClay | 90 | Andrei PavelClay | 6-3 6-3 | 3 | 78 | 3 | 0 | 74.5% | 68.3% | 50.0% | 2/3 |
| R16 | 67 | Marc GicquelClay | 38 | Igor AndreevClay | 6-4 6-3 | 3 | 79 | 1 | 2 | 38.2% | 85.7% | 44.1% | 4/6 |
| R16 | 48 | Gael MonfilsClay | 74 | Martin Vassallo ArguelloClay | 6-4 6-4 | 3 | 90 | 1 | 0 | 61.7% | 64.9% | 69.6% | 2/3 |
| QF | 77 | Carlos BerlocqClay | 164 | Yuri SchukinClay | 7-5 6-3 | 3 | 94 | 4 | 0 | 76.9% | 70.0% | 86.7% | 3/3 |
| QF | 42 | Gilles SimonClay | 230 | Hugo ArmandoClay | 6-4 6-2 | 3 | 80 | 3 | 0 | 65.1% | 75.6% | 50.0% | 4/5 |
| QF | 151 | Victor HanescuClay | 31 | Potito StaraceClay | 7-6(5) 7-5 | 3 | 97 | 3 | 0 | 71.0% | 88.6% | 72.2% | 0/0 |
| QF | 48 | Gael MonfilsClay | 67 | Marc GicquelClay | 6-4 6-2 | 3 | 74 | 12 | 5 | 54.7% | 80.0% | 55.2% | 8/8 |
| SF | 42 | Gilles SimonClay | 77 | Carlos BerlocqClay | 6-7(4) 6-2 6-3 | 3 | 143 | 2 | 2 | 46.8% | 70.5% | 56.0% | 7/10 |
| SF | 151 | Victor HanescuClay | 48 | Gael MonfilsClay | 6-2 6-3 | 3 | 66 | 3 | 0 | 76.9% | 80.0% | 88.9% | 0/0 |
| F | 42 | Gilles SimonClay | 151 | Victor HanescuClay | 4-6 6-3 6-2 | 3 | 111 | 4 | 2 | 61.4% | 75.9% | 52.9% | 6/7 |
