| R32 | 22 |  Dmitry TursunovClay | 114 |  Alexander WaskeClay | 1-6 7-6(4) 6-4 | 3 | 130 | 9 | 2 | 54.5% | 70.9% | 37.0% | 4/10 |
| R32 | 82 |  Guillermo Garcia-LopezClay | 84 | Albert MontanesClay | 3-6 7-5 6-1 | 3 | 113 | 4 | 2 | 70.6% | 58.3% | 48.0% | 8/13 |
| R32 | 196 |  Victor CrivoiClay | 323 |  Edgardo MassaClay | 7-5 4-6 6-4 | 3 | 126 | 1 | 3 | 67.4% | 77.6% | 35.7% | 2/6 |
| R32 | 54 |  Paul-Henri MathieuClay | 83 | Simon GreulClay | 6-1 6-1 | 3 | 54 | 1 | 0 | 60.5% | 69.2% | 64.7% | 2/3 |
| R32 | 46 | Gilles SimonClay | 70 | Juan MonacoClay | 7-5 3-6 6-3 | 3 | 152 | 6 | 4 | 50.5% | 63.3% | 56.3% | 7/11 |
| R32 | 67 |  Jurgen MelzerClay | 306 |  Michal MertinakClay | 5-7 6-2 7-5 | 3 | 138 | 8 | 2 | 63.9% | 71.0% | 48.6% | 4/8 |
| R32 | 64 |  Christophe RochusClay | 375 |  Alexandr DolgopolovClay | 6-2 7-6(5) | 3 | 70 | 2 | 3 | 70.5% | 76.7% | 55.6% | 2/3 |
| R32 | 59 | Ruben Ramirez HidalgoClay | 271 | Victor IonitaClay | 6-4 6-4 | 3 | 88 | 2 | 0 | 69.5% | 73.2% | 38.9% | 2/4 |
| R32 | 51 |  Filippo VolandriClay | 194 | Simone VagnozziClay | 3-6 6-2 6-2 | 3 | 85 | 4 | 2 | 67.9% | 60.0% | 38.5% | 6/11 |
| R32 | 118 | Stefan KoubekClay | 366 | Mariano ZabaletaClay | 4-6 6-4 6-3 | 3 | 154 | 4 | 5 | 57.5% | 59.0% | 57.8% | 7/11 |
| R32 | 79 | Andrei PavelClay | 92 |  Boris PashanskiClay | 6-3 6-1 | 3 | 77 | 4 | 1 | 55.1% | 77.8% | 68.2% | 1/1 |
| R32 | 41 | Carlos MoyaClay | 56 |  Luis HornaClay | 6-7(4) 7-6(3) 7-5 | 3 | 179 | 11 | 3 | 62.8% | 80.3% | 54.8% | 1/1 |
| R32 | 53 | Florian MayerClay | 101 | Potito StaraceClay | 6-2 6-3 | 3 | 69 | 1 | 1 | 66.1% | 67.6% | 52.6% | 3/5 |
| R32 | 110 | Sergio RoitmanClay | 88 | Alessio Di MauroClay | 6-3 6-2 | 3 | 71 | 1 | 0 | 68.3% | 78.6% | 84.6% | 0/0 |
| R32 | 108 | Martin Vassallo ArguelloClay | 163 | Razvan SabauClay | 6-3 1-6 6-3 | 3 | 120 | 8 | 2 | 69.1% | 63.1% | 55.2% | 10/13 |
| R32 | 44 | Florent SerraClay | 327 | Juan-Martin ArangurenClay | 6-1 6-0 | 3 | 135 | 2 | 1 | 75.0% | 83.3% | 62.5% | 0/0 |
| R16 | 82 | Guillermo Garcia-LopezClay | 22 | Dmitry TursunovClay | 6-2 3-6 7-6(3) | 3 | 148 | 2 | 3 | 72.4% | 67.6% | 44.4% | 7/11 |
| R16 | 54 | Paul-Henri MathieuClay | 196 | Victor CrivoiClay | 6-1 6-1 | 3 | 69 | 4 | 0 | 68.4% | 76.9% | 75.0% | 0/0 |
| R16 | 67 | Jurgen MelzerClay | 46 | Gilles SimonClay | 3-6 6-3 6-4 | 3 | 133 | 5 | 2 | 62.1% | 59.4% | 41.0% | 6/12 |
| R16 | 59 | Ruben Ramirez HidalgoClay | 64 | Christophe RochusClay | 3-6 6-3 6-1 | 3 | 99 | 6 | 2 | 73.2% | 69.2% | 47.4% | 5/9 |
| R16 | 51 | Filippo VolandriClay | 118 | Stefan KoubekClay | 3-6 6-2 6-2 | 3 | 108 | 1 | 0 | 76.0% | 59.6% | 44.4% | 1/5 |
| R16 | 41 | Carlos MoyaClay | 79 | Andrei PavelClay | 6-4 7-6(5) | 3 | 98 | 6 | 1 | 59.5% | 79.5% | 46.7% | 4/6 |
| R16 | 53 | Florian MayerClay | 110 | Sergio RoitmanClay | 6-4 6-1 | 3 | 68 | 5 | 1 | 62.7% | 75.0% | 63.2% | 1/1 |
| R16 | 44 | Florent SerraClay | 108 | Martin Vassallo ArguelloClay | 6-4 6-1 | 3 | 79 | 1 | 1 | 59.5% | 84.0% | 70.6% | 3/3 |
| QF | 54 | Paul-Henri MathieuClay | 82 | Guillermo Garcia-LopezClay | 6-1 6-4 | 3 | 91 | 1 | 1 | 63.1% | 63.4% | 62.5% | 6/7 |
| QF | 67 | Jurgen MelzerClay | 59 | Ruben Ramirez HidalgoClay | 6-4 6-2 | 3 | 72 | 3 | 1 | 72.2% | 59.0% | 53.3% | 1/4 |
| QF | 51 | Filippo VolandriClay | 41 | Carlos MoyaClay | 6-3 6-3 | 3 | 78 | 0 | 1 | 77.6% | 75.6% | 46.2% | 4/4 |
| QF | 44 | Florent SerraClay | 53 | Florian MayerClay | 6-3 7-6(5) | 3 | 82 | 3 | 1 | 58.2% | 61.5% | 53.6% | 5/9 |
| SF | 67 | Jurgen MelzerClay | 54 | Paul-Henri MathieuClay | 6-4 RET | 3 | 49 | 2 | 0 | 69.0% | 75.0% | 77.8% | 2/2 |
| SF | 51 | Filippo VolandriClay | 44 | Florent SerraClay | 7-6(6) 6-4 | 3 | 101 | 1 | 1 | 72.2% | 65.4% | 80.0% | 5/6 |
| F | 67 | Jurgen MelzerClay | 51 | Filippo VolandriClay | 6-1 7-5 | 3 | 85 | 7 | 0 | 67.8% | 77.5% | 68.4% | 1/1 |
