| R32 | 10 |  Mariano PuertaClay | 122 |  Janko TipsarevicClay | 7-5 6-2 | 3 | 81 | 6 | 0 | 64.6% | 87.1% | 58.8% | 0/1 |
| R32 | 89 |  Guillermo Garcia-LopezClay | 63 |  Luis HornaClay | 6-3 3-6 6-2 | 3 | 126 | 3 | 3 | 69.1% | 67.9% | 60.0% | 3/5 |
| R32 | 52 |  Igor AndreevClay | 110 |  Alexander WaskeClay | 6-4 7-6(4) | 3 | 91 | 10 | 0 | 64.9% | 89.2% | 80.0% | 1/1 |
| R32 | 74 | Albert MontanesClay | 46 |  Gael MonfilsClay | 3-6 6-1 6-4 | 3 | 137 | 2 | 3 | 62.2% | 62.7% | 48.4% | 6/10 |
| R32 | 45 |  Victor HanescuClay | 107 |  Potito StaraceClay | 6-3 6-2 | 3 | 54 | 2 | 4 | 64.3% | 72.2% | 55.0% | 2/2 |
| R32 | 47 | Davide SanguinettiClay | 79 | Razvan SabauClay | 6-4 6-3 | 3 | 60 | 5 | 0 | 68.0% | 82.4% | 56.3% | 0/0 |
| R32 | 133 | Ruben Ramirez HidalgoClay | 102 | Nicolas AlmagroClay | 7-6(8) 6-1 | 3 | 101 | 1 | 0 | 53.4% | 80.6% | 59.3% | 0/1 |
| R32 | 43 | Jose AcasusoClay | 53 | Juan Ignacio ChelaClay | 6-2 6-4 | 3 | 96 | 5 | 0 | 55.1% | 85.2% | 63.6% | 0/0 |
| R32 | 39 | Fernando VerdascoClay | 67 | Mariano ZabaletaClay | 6-2 6-4 | 3 | 80 | 2 | 2 | 77.2% | 68.2% | 30.8% | 2/4 |
| R32 | 66 | Florian MayerClay | 75 | Oscar HernandezClay | 6-2 6-0 | 3 | 53 | 2 | 0 | 75.6% | 71.0% | 80.0% | 2/2 |
| R32 | 128 |  Oliver MarachClay | 836 |  Mariusz FyrstenbergClay | 6-4 6-4 | 3 | 100 | 3 | 2 | 50.0% | 69.2% | 65.4% | 1/3 |
| R32 | 56 | Andrei PavelClay | 62 | Alberto MartinClay | 6-4 6-4 | 3 | 88 | 4 | 0 | 80.6% | 67.2% | 50.0% | 6/7 |
| R32 | 54 | Paul-Henri MathieuClay | 116 | David SanchezClay | 2-6 6-2 6-1 | 3 | 89 | 3 | 2 | 53.8% | 71.4% | 63.3% | 0/2 |
| R32 | 127 | Albert PortasClay | 57 |  Christophe RochusClay | 6-4 6-1 | 3 | 75 | 6 | 1 | 57.1% | 67.9% | 47.6% | 3/5 |
| R32 | 68 | Florent SerraClay | 318 | Victor CrivoiClay | 3-6 7-6(5) 6-1 | 3 | 121 | 4 | 5 | 54.2% | 64.4% | 42.1% | 3/9 |
| R32 | 41 | Filippo VolandriClay | 86 | Tomas BehrendClay | 6-2 6-4 | 3 | 73 | 1 | 1 | 65.5% | 73.7% | 60.0% | 3/4 |
| R16 | 10 | Mariano PuertaClay | 89 | Guillermo Garcia-LopezClay | 6-2 6-4 | 3 | 86 | 4 | 1 | 68.3% | 62.8% | 60.0% | 5/6 |
| R16 | 52 | Igor AndreevClay | 74 | Albert MontanesClay | 6-2 6-2 | 3 | 58 | 0 | 1 | 62.5% | 76.7% | 50.0% | 1/2 |
| R16 | 45 | Victor HanescuClay | 47 | Davide SanguinettiClay | 6-2 6-3 | 3 | 70 | 3 | 0 | 77.8% | 73.8% | 58.3% | 7/8 |
| R16 | 133 | Ruben Ramirez HidalgoClay | 43 | Jose AcasusoClay | 6-4 7-5 | 3 | 97 | 2 | 0 | 80.6% | 74.1% | 53.8% | 3/4 |
| R16 | 66 | Florian MayerClay | 39 | Fernando VerdascoClay | 7-5 7-6(7) | 3 | 104 | 3 | 2 | 70.5% | 71.0% | 50.0% | 7/10 |
| R16 | 56 | Andrei PavelClay | 128 | Oliver MarachClay | 3-6 7-6(2) 6-4 | 3 | 154 | 7 | 0 | 71.6% | 67.1% | 55.2% | 3/6 |
| R16 | 54 | Paul-Henri MathieuClay | 127 | Albert PortasClay | 6-2 6-0 | 3 | 78 | 1 | 0 | 48.8% | 90.0% | 57.1% | 2/2 |
| R16 | 68 | Florent SerraClay | 41 | Filippo VolandriClay | 1-6 6-4 6-3 | 3 | 94 | 2 | 1 | 63.4% | 53.8% | 56.7% | 5/10 |
| QF | 52 | Igor AndreevClay | 10 | Mariano PuertaClay | 4-6 6-1 6-1 | 3 | 114 | 2 | 1 | 54.7% | 63.8% | 69.2% | 7/8 |
| QF | 45 | Victor HanescuClay | 133 | Ruben Ramirez HidalgoClay | 6-4 6-4 | 3 | 77 | 7 | 0 | 87.5% | 77.6% | 71.4% | 4/4 |
| QF | 56 | Andrei PavelClay | 66 | Florian MayerClay | 7-5 7-6(4) | 3 | 96 | 7 | 2 | 72.6% | 75.5% | 65.0% | 0/1 |
| QF | 68 | Florent SerraClay | 54 | Paul-Henri MathieuClay | 6-3 6-1 | 3 | 70 | 3 | 0 | 50.0% | 76.0% | 52.0% | 0/1 |
| SF | 52 | Igor AndreevClay | 45 | Victor HanescuClay | 4-6 7-6(2) 6-3 | 3 | 169 | 5 | 3 | 65.2% | 64.4% | 61.5% | 4/7 |
| SF | 68 | Florent SerraClay | 56 | Andrei PavelClay | 6-7(5) 6-2 6-3 | 3 | 157 | 3 | 1 | 54.1% | 75.0% | 56.9% | 5/5 |
| F | 68 | Florent SerraClay | 52 | Igor AndreevClay | 6-3 6-4 | 3 | 96 | 0 | 0 | 55.4% | 67.7% | 60.0% | 2/4 |
