| R32 | 96 |  Victor HanescuClay | 39 |  Fernando VerdascoClay | 7-6(4) 7-6(3) | 3 | 119 | 1 | 0 | 73.8% | 62.7% | 57.1% | 3/7 |
| R32 | 82 |  Stefan KoubekClay | 221 | Victor IonitaClay | 6-3 7-6(3) | 3 | 123 | 3 | 1 | 67.1% | 58.2% | 44.4% | 5/10 |
| R32 | 119 |  Richard GasquetClay | 80 |  Potito StaraceClay | 6-3 6-4 | 3 | 91 | 4 | 3 | 59.4% | 75.6% | 42.9% | 7/9 |
| R32 | 53 | Filippo VolandriClay | 83 | Albert MontanesClay | 6-3 6-1 | 3 | 54 | 3 | 1 | 58.5% | 83.3% | 58.8% | 1/2 |
| R32 | 79 | Paul-Henri MathieuClay | 45 | Albert CostaClay | 6-1 6-2 | 3 | 84 | 1 | 1 | 51.7% | 70.0% | 64.3% | 1/1 |
| R32 | 91 | Alex CorretjaClay | 102 | Oscar HernandezClay | 7-5 2-6 7-5 | 3 | 183 | 5 | 2 | 62.6% | 61.3% | 48.6% | 6/12 |
| R32 | 95 |  Jose AcasusoClay | 135 | Franco SquillariClay | 3-6 6-4 6-2 | 3 | 120 | 3 | 2 | 53.8% | 81.0% | 44.4% | 2/4 |
| R32 | 77 | David SanchezClay | 93 |  Raemon SluiterClay | 6-2 7-6(3) | 3 | 83 | 4 | 0 | 69.0% | 80.0% | 61.1% | 2/3 |
| R32 | 87 | Felix MantillaClay | 44 |  Nikolay DavydenkoClay | 7-6(3) 6-0 | 3 | 90 | 1 | 3 | 52.0% | 76.9% | 66.7% | 0/1 |
| R32 | 101 | Alex CalatravaClay | 86 | Juan MonacoClay | 7-6(7) 6-2 | 3 | 104 | 5 | 0 | 66.2% | 69.8% | 72.7% | 4/5 |
| R32 | 85 |  Philipp KohlschreiberClay | 296 | Razvan SabauClay | 6-1 6-1 | 3 | 50 | 7 | 2 | 70.7% | 72.4% | 41.7% | 0/1 |
| R32 | 49 | Igor AndreevClay | 99 |  Kristof VliegenClay | 6-2 6-3 | 3 | 70 | 0 | 5 | 50.0% | 63.3% | 60.0% | 6/7 |
| R32 | 54 | David FerrerClay | 167 |  Stan WawrinkaClay | 6-4 7-6(4) | 3 | 122 | 2 | 3 | 61.9% | 59.6% | 46.9% | 4/8 |
| R32 | 272 |  Novak DjokovicClay | 67 | Arnaud ClementClay | 2-6 6-4 6-4 | 3 | 146 | 4 | 2 | 65.9% | 65.0% | 61.3% | 2/5 |
| R32 | 244 | Arnaud Di PasqualeClay | 146 | Daniel ElsnerClay | 4-0 RET | 3 | 17 | 1 | 1 | 66.7% | 100.0% | 66.7% | 0/0 |
| R32 | 36 | Florian MayerClay | - | Dennis Van ScheppingenClay | 6-1 6-1 | 3 | 46 | 3 | 0 | 68.4% | 80.8% | 66.7% | 1/1 |
| R16 | 96 | Victor HanescuClay | 82 | Stefan KoubekClay | 6-2 6-3 | 3 | 59 | 2 | 0 | 82.0% | 78.0% | 55.6% | 1/1 |
| R16 | 53 | Filippo VolandriClay | 119 | Richard GasquetClay | 6-2 1-6 6-3 | 3 | 84 | 1 | 4 | 75.9% | 61.9% | 60.0% | 7/10 |
| R16 | 79 | Paul-Henri MathieuClay | 91 | Alex CorretjaClay | 3-6 6-3 6-1 | 3 | 139 | 2 | 3 | 57.0% | 67.3% | 48.6% | 7/11 |
| R16 | 95 | Jose AcasusoClay | 77 | David SanchezClay | 6-3 6-0 | 3 | 61 | 6 | 1 | 55.6% | 95.0% | 31.3% | 0/1 |
| R16 | 87 | Felix MantillaClay | 101 | Alex CalatravaClay | 6-3 6-1 | 3 | 58 | 8 | 3 | 42.9% | 94.4% | 62.5% | 0/0 |
| R16 | 49 | Igor AndreevClay | 85 | Philipp KohlschreiberClay | 7-6(6) 6-2 | 3 | 97 | 2 | 1 | 49.3% | 72.2% | 59.5% | 1/2 |
| R16 | 54 | David FerrerClay | 272 | Novak DjokovicClay | 4-6 6-4 6-4 | 3 | 155 | 1 | 2 | 57.0% | 55.7% | 54.3% | 14/19 |
| R16 | 36 | Florian MayerClay | 244 | Arnaud Di PasqualeClay | 7-6(6) 4-6 6-3 | 3 | 140 | 8 | 1 | 70.0% | 67.1% | 60.0% | 1/3 |
| QF | 53 | Filippo VolandriClay | 96 | Victor HanescuClay | 6-3 6-1 | 3 | 60 | 3 | 0 | 76.0% | 71.1% | 50.0% | 5/6 |
| QF | 95 | Jose AcasusoClay | 79 | Paul-Henri MathieuClay | 6-2 7-6(2) | 3 | 100 | 5 | 3 | 54.8% | 79.4% | 57.1% | 3/4 |
| QF | 49 | Igor AndreevClay | 87 | Felix MantillaClay | 6-4 6-2 | 3 | 85 | 2 | 3 | 67.3% | 70.3% | 72.2% | 3/3 |
| QF | 36 | Florian MayerClay | 54 | David FerrerClay | 6-4 6-2 | 3 | 63 | 1 | 0 | 74.1% | 65.0% | 71.4% | 2/3 |
| SF | 95 | Jose AcasusoClay | 53 | Filippo VolandriClay | 7-6(5) 6-2 | 3 | 85 | 6 | 2 | 60.0% | 83.3% | 62.5% | 1/2 |
| SF | 49 | Igor AndreevClay | 36 | Florian MayerClay | 2-6 6-1 6-4 | 3 | 95 | 1 | 0 | 63.9% | 69.8% | 63.3% | 5/7 |
| F | 95 | Jose AcasusoClay | 49 | Igor AndreevClay | 6-3 6-0 | 3 | 65 | 5 | 1 | 55.3% | 85.7% | 52.9% | 0/1 |
