| R32 | 25 |  Andrei PavelClay | 96 |  Jiri VanekClay | 6-0 6-3 | 3 | 58 | 1 | 0 | 51.2% | 81.0% | 70.0% | 2/3 |
| R32 | 144 |  Tomas BehrendClay | 83 |  Jose AcasusoClay | 7-6(7) 6-4 | 3 | 110 | 1 | 3 | 59.8% | 63.6% | 59.5% | 6/9 |
| R32 | 55 |  Felix MantillaClay | 75 |  Markus HipflClay | 6-0 6-1 | 3 | 64 | 3 | 1 | 39.5% | 86.7% | 65.2% | 2/2 |
| R32 | 47 | MARYounes El AynaouiClay | 669 | Dinu PescariuClay | 6-0 6-2 | 3 | 48 | 3 | 2 | 52.8% | 89.5% | 76.5% | 3/3 |
| R32 | 111 | Adrian VoineaClay | 34 | Alberto MartinClay | 3-6 6-1 6-4 | 3 | 106 | 5 | 3 | 48.2% | 63.4% | 40.9% | 7/12 |
| R32 | 184 | Ruben Ramirez HidalgoClay | 99 |  Attila SavoltClay | 7-5 6-3 | 3 | 117 | 1 | 2 | 58.7% | 70.5% | 51.6% | 8/10 |
| R32 | 59 | Fernando VicenteClay | 116 |  Hugo ArmandoClay | 6-2 6-0 | 3 | 68 | 4 | 3 | 48.4% | 77.4% | 48.5% | 5/5 |
| R32 | 137 | Marc LopezClay | 45 | Galo BlancoClay | 6-2 6-2 | 3 | 65 | 1 | 0 | 89.8% | 72.7% | 0.0% | 2/3 |
| R32 | 48 |  Jerome GolmardClay | 81 |  Andrew IlieClay | 6-2 6-2 | 3 | 61 | 9 | 1 | 65.9% | 89.7% | 46.7% | 1/1 |
| R32 | 78 | Jacobo DiazClay | 101 |  Irakli LabadzeClay | 6-3 6-4 | 3 | 83 | 2 | 2 | 90.9% | 61.7% | 50.0% | 7/10 |
| R32 | 307 | Gabriel TrifuClay | 523 | Ion MoldovanClay | 4-6 6-1 7-6(5) | 3 | 154 | 4 | 8 | 56.8% | 68.0% | 47.4% | 1/6 |
| R32 | 76 |  Christophe RochusClay | 42 |  Andreas VinciguerraClay | 6-1 6-2 | 3 | 59 | 0 | 6 | 48.3% | 65.5% | 51.6% | 5/7 |
| R32 | 58 | Juan BalcellsClay | 148 | Marc-Kevin GoellnerClay | 7-5 7-6(4) | 3 | 94 | 3 | 1 | 73.7% | 67.9% | 65.0% | 6/8 |
| R32 | 125 | Juan Ignacio ChelaClay | 82 | David SanchezClay | 2-6 7-5 6-4 | 3 | 152 | 4 | 4 | 48.6% | 52.8% | 44.6% | 13/21 |
| R32 | 95 | Albert MontanesClay | 77 | Olivier RochusClay | 6-1 6-1 | 3 | 102 | 1 | 1 | 63.6% | 82.1% | 56.3% | 1/1 |
| R32 | 20 | Albert PortasClay | 298 |  Solon PeppasClay | 6-0 6-2 | 3 | 59 | 4 | 2 | 44.7% | 85.7% | 53.8% | 4/4 |
| R16 | 144 | Tomas BehrendClay | 25 | Andrei PavelClay | 6-0 6-2 | 3 | 57 | 1 | 0 | 73.2% | 80.0% | 54.5% | 2/2 |
| R16 | 47 | MARYounes El AynaouiClay | 55 | Felix MantillaClay | 6-3 6-2 | 3 | 74 | 10 | 2 | 64.8% | 77.1% | 57.9% | 0/0 |
| R16 | 111 | Adrian VoineaClay | 184 | Ruben Ramirez HidalgoClay | 6-3 6-2 | 3 | 61 | 5 | 1 | 63.0% | 86.2% | 70.6% | 1/1 |
| R16 | 59 | Fernando VicenteClay | 137 | Marc LopezClay | 6-3 6-3 | 3 | 71 | 2 | 1 | 53.3% | 66.7% | 71.4% | 2/4 |
| R16 | 48 | Jerome GolmardClay | 78 | Jacobo DiazClay | 6-4 2-6 7-6(4) | 3 | 165 | 8 | 2 | 60.0% | 75.4% | 42.1% | 2/5 |
| R16 | 76 | Christophe RochusClay | 307 | Gabriel TrifuClay | 7-6(4) 6-4 | 3 | 108 | 0 | 3 | 56.1% | 63.0% | 50.0% | 10/13 |
| R16 | 58 | Juan BalcellsClay | 125 | Juan Ignacio ChelaClay | 6-3 6-4 | 3 | 71 | 0 | 2 | 84.0% | 71.4% | 41.7% | 4/4 |
| R16 | 95 | Albert MontanesClay | 20 | Albert PortasClay | 6-4 4-6 7-6(7) | 3 | 159 | 4 | 3 | 49.1% | 73.1% | 40.7% | 6/13 |
| QF | 47 | MARYounes El AynaouiClay | 144 | Tomas BehrendClay | 6-4 5-7 6-4 | 3 | 139 | 4 | 8 | 46.1% | 70.2% | 43.6% | 5/11 |
| QF | 59 | Fernando VicenteClay | 111 | Adrian VoineaClay | 6-4 4-6 7-5 | 3 | 132 | 1 | 7 | 60.2% | 62.9% | 46.3% | 6/11 |
| QF | 48 | Jerome GolmardClay | 76 | Christophe RochusClay | 6-1 3-6 6-3 | 3 | 130 | 11 | 6 | 60.2% | 66.1% | 53.8% | 11/13 |
| QF | 95 | Albert MontanesClay | 58 | Juan BalcellsClay | 7-5 3-6 6-1 | 3 | 95 | 4 | 0 | 66.7% | 75.0% | 69.2% | 6/8 |
| SF | 47 | MARYounes El AynaouiClay | 59 | Fernando VicenteClay | 7-6(4) 6-4 | 3 | 125 | 8 | 2 | 59.0% | 71.4% | 55.9% | 6/7 |
| SF | 95 | Albert MontanesClay | 48 | Jerome GolmardClay | 6-7(5) 6-3 7-5 | 3 | 150 | 10 | 3 | 64.6% | 68.5% | 60.0% | 5/7 |
| F | 47 | MARYounes El AynaouiClay | 95 | Albert MontanesClay | 7-6(5) 7-6(2) | 3 | 115 | 13 | 2 | 61.2% | 76.7% | 47.4% | 7/8 |
