| R16 | 85 |  Galo BlancoClay | 118 | Jacobo DiazClay | 6-4 6-2 | 3 | 81 | 1 | 2 | 49.1% | 64.3% | 58.6% | 3/5 |
| R32 | 28 | Francisco ClavetClay | 126 |  Christian VinckClay | 6-2 7-6(2) | 3 | 101 | 3 | 2 | 75.4% | 71.4% | 50.0% | 2/4 |
| R32 | 84 |  Dinu PescariuClay | 99 |  Christian RuudClay | 6-3 6-4 | 3 | 69 | 2 | 2 | 69.1% | 81.6% | 58.8% | 2/2 |
| R32 | 100 | Alex CalatravaClay | 92 | Oliver GrossClay | 3-6 6-3 1-1 RET | 3 | 94 | 3 | 4 | 50.0% | 75.0% | 45.0% | 6/8 |
| R32 | 63 | Julian AlonsoClay | 140 |  Tomas ZibClay | 1-0 RET | 3 | 1 | 0 | 0 | - | - | NaN% | 0/0 |
| R32 | 49 | Carlos CostaClay | 75 |  Sebastien GrosjeanClay | 6-2 7-5 | 3 | 78 | 0 | 2 | 52.1% | 65.8% | 45.7% | 9/12 |
| R32 | 79 | Andrei PavelClay | 325 |  Fabio MaggiClay | 6-0 6-3 | 3 | 57 | 2 | 0 | 62.7% | 75.0% | 63.2% | 3/3 |
| R32 | 103 | Albert PortasClay | 101 | Javier SanchezClay | 6-3 6-3 | 3 | 63 | 0 | 1 | 74.5% | 70.7% | 57.1% | 0/1 |
| R32 | 170 |  Attila SavoltClay | 51 |  Andrew IlieClay | 6-0 6-2 | 3 | 59 | 2 | 0 | 57.1% | 85.0% | 53.3% | 0/1 |
| R32 | 56 |  Nicolas LapenttiClay | 163 |  Jan ApellClay | 6-3 6-4 | 3 | 82 | 3 | 3 | 60.9% | 76.9% | 64.0% | 1/1 |
| R32 | 150 | Arnaud Di PasqualeClay | 270 | Gabriel TrifuClay | 7-6(1) 7-6(5) | 3 | 45 | 2 | 1 | 65.8% | 65.4% | 44.4% | 2/7 |
| R32 | 118 | Jacobo DiazClay | 155 | Bernd KarbacherClay | 6-1 6-3 | 3 | 80 | 1 | 2 | 63.2% | 63.9% | 66.7% | 6/7 |
| R32 | 85 | Galo BlancoClay | 40 |  Dominik HrbatyClay | 7-6(6) 7-5 | 3 | 102 | 2 | 2 | 52.5% | 76.2% | 50.0% | 3/4 |
| R32 | 369 | Ion MoldovanClay | 58 |  Mariano PuertaClay | 6-4 6-4 | 3 | 77 | 2 | 0 | 85.0% | 72.5% | 55.6% | 4/5 |
| R32 | 83 | Adrian VoineaClay | 80 |  Juan Antonio MarinClay | 6-4 6-3 | 3 | 68 | 3 | 1 | 62.7% | 71.9% | 63.2% | 3/4 |
| R32 | 159 | Emilio Benfele AlvarezClay | 716 |  Nikos RovasClay | 6-3 6-2 | 3 | 74 | 5 | 0 | 69.0% | 62.5% | 38.9% | 2/5 |
| R32 | 30 | Richard FrombergClay | 205 | Razvan SabauClay | 6-7(4) 6-1 6-3 | 3 | 106 | 18 | 1 | 62.8% | 79.6% | 56.3% | 3/4 |
| R16 | 28 | Francisco ClavetClay | 84 | Dinu PescariuClay | 3-6 7-5 6-2 | 3 | 135 | 7 | 3 | 49.5% | 66.7% | 52.2% | 4/7 |
| R16 | 63 | Julian AlonsoClay | 100 | Alex CalatravaClay | 6-2 6-7(4) 6-4 | 3 | 128 | 7 | 5 | 49.4% | 76.7% | 50.0% | 2/6 |
| R16 | 79 | Andrei PavelClay | 49 | Carlos CostaClay | 6-7(6) 6-3 6-1 | 3 | 121 | 4 | 1 | 61.9% | 65.0% | 54.1% | 9/12 |
| R16 | 103 | Albert PortasClay | 170 | Attila SavoltClay | 2-6 7-6(3) 6-2 | 3 | 165 | 8 | 7 | 53.4% | 69.8% | 50.9% | 10/13 |
| R16 | 150 | Arnaud Di PasqualeClay | 56 | Nicolas LapenttiClay | 6-2 6-7(7) 6-1 | 3 | 122 | 1 | 0 | 70.3% | 62.0% | 53.3% | 5/8 |
| R16 | 83 | Adrian VoineaClay | 369 | Ion MoldovanClay | 6-3 6-4 | 3 | 65 | 9 | 3 | 54.4% | 80.6% | 73.1% | 3/3 |
| R16 | 159 | Emilio Benfele AlvarezClay | 30 | Richard FrombergClay | 7-6(4) 3-6 7-5 | 3 | 168 | 3 | 4 | 62.3% | 71.8% | 51.2% | 4/8 |
| QF | 28 | Francisco ClavetClay | 63 | Julian AlonsoClay | 7-5 6-0 | 3 | 79 | 2 | 2 | 65.2% | 65.1% | 52.2% | 7/8 |
| QF | 103 | Albert PortasClay | 79 | Andrei PavelClay | 2-6 6-3 7-5 | 3 | 118 | 4 | 2 | 54.1% | 69.8% | 48.9% | 9/13 |
| QF | 150 | Arnaud Di PasqualeClay | 85 | Galo BlancoClay | 7-6(2) 2-6 6-2 | 3 | 106 | 4 | 3 | 67.1% | 67.3% | 48.1% | 3/8 |
| QF | 83 | Adrian VoineaClay | 159 | Emilio Benfele AlvarezClay | 6-4 6-1 | 3 | 62 | 3 | 2 | 64.4% | 69.0% | 75.0% | 1/2 |
| SF | 28 | Francisco ClavetClay | 103 | Albert PortasClay | 3-6 6-0 6-2 | 3 | 103 | 5 | 0 | 73.2% | 63.5% | 52.6% | 4/7 |
| SF | 150 | Arnaud Di PasqualeClay | 83 | Adrian VoineaClay | 6-3 2-6 7-5 | 3 | 122 | 3 | 3 | 60.2% | 59.7% | 61.0% | 10/14 |
| F | 28 | Francisco ClavetClay | 150 | Arnaud Di PasqualeClay | 6-4 2-6 7-5 | 3 | 115 | 5 | 0 | 68.8% | 63.6% | 56.0% | 1/5 |
