| R32 | 5 |  Carlos MoyaClay | 72 |  Hendrik DreekmannClay | 6-1 4-6 6-3 | 3 | 107 | 3 | 2 | 47.6% | 76.9% | 55.8% | 6/8 |
| R32 | 86 | Carlos CostaClay | 153 |  Ion MoldovanClay | 7-6(7) 6-3 | 3 | 81 | 6 | 3 | 53.2% | 73.2% | 50.0% | 4/6 |
| R32 | 64 |  Christian RuudClay | 95 | Fernando VicenteClay | 7-6(3) 7-5 | 3 | 108 | 1 | 2 | 52.1% | 59.5% | 52.9% | 2/7 |
| R32 | 43 | Marc-Kevin GoellnerClay | 87 | Juan Albert Viloca-PuigClay | 6-3 6-3 | 3 | 75 | 2 | 3 | 57.1% | 82.1% | 52.4% | 1/2 |
| R32 | 27 | Alberto BerasateguiClay | 82 | Dinu PescariuClay | 6-3 1-6 7-6(7) | 3 | 108 | 2 | 2 | 78.1% | 57.3% | 40.0% | 6/12 |
| R32 | 89 |  Nicolas LapenttiClay | 97 | Emilio Benfele AlvarezClay | 6-4 6-3 | 3 | 94 | 0 | 2 | 81.8% | 64.8% | 33.3% | 9/11 |
| R32 | 84 |  Andrea GaudenziClay | 55 | Julian AlonsoClay | 6-1 6-4 | 3 | 70 | 2 | 0 | 78.4% | 72.4% | 75.0% | 0/2 |
| R32 | 104 |  Juan Antonio MarinClay | 40 |  Marcelo FilippiniClay | 6-2 6-3 | 3 | 58 | 0 | 1 | 56.9% | 75.9% | 63.6% | 2/3 |
| R32 | 88 |  Richard FrombergClay | 36 | MARHicham AraziClay | 6-4 6-0 | 3 | 63 | 4 | 3 | 42.6% | 78.3% | 51.6% | 5/6 |
| R32 | 100 | Adrian VoineaClay | 176 | Tomas CarbonellClay | 7-6(2) 6-1 | 3 | 72 | 4 | 0 | 52.6% | 83.3% | 48.1% | 2/4 |
| R32 | 94 | Davide SanguinettiClay | 187 |  Orlin StanoytchevClay | 6-4 7-6(8) | 3 | 97 | 3 | 2 | 54.9% | 76.9% | 43.8% | 5/8 |
| R32 | 35 | Albert PortasClay | 102 | Alberto MartinClay | 4-6 7-6(5) 6-4 | 3 | 134 | 2 | 3 | 68.2% | 56.2% | 61.8% | 5/10 |
| R32 | 50 | Francisco ClavetClay | 49 | MARKarim AlamiClay | 6-3 6-3 | 3 | 71 | 4 | 2 | 64.2% | 70.6% | 57.9% | 1/3 |
| R32 | 467 | Tomas BehrendClay | 96 | Andrei PavelClay | 6-2 6-2 | 3 | 57 | 5 | 2 | 51.9% | 78.6% | 50.0% | 0/1 |
| R32 | 59 | Javier SanchezClay | 52 | Galo BlancoClay | 6-4 6-1 | 3 | 64 | 5 | 2 | 83.7% | 75.6% | 37.5% | 0/1 |
| R32 | 9 | Alex CorretjaClay | 53 |  Jeff TarangoClay | 6-4 6-1 | 3 | 78 | 3 | 3 | 56.7% | 79.4% | 46.2% | 3/4 |
| R16 | 86 | Carlos CostaClay | 5 | Carlos MoyaClay | 6-0 4-6 6-4 | 3 | 112 | 1 | 4 | 50.6% | 61.4% | 48.8% | 5/10 |
| R16 | 43 | Marc-Kevin GoellnerClay | 64 | Christian RuudClay | 6-2 5-7 6-2 | 3 | 106 | 13 | 6 | 56.5% | 79.2% | 45.9% | 2/5 |
| R16 | 89 | Nicolas LapenttiClay | 27 | Alberto BerasateguiClay | 7-6(5) 6-3 | 3 | 119 | 0 | 1 | 86.4% | 65.8% | 25.0% | 7/9 |
| R16 | 84 | Andrea GaudenziClay | 104 | Juan Antonio MarinClay | 6-4 7-5 | 3 | 87 | 3 | 2 | 66.7% | 73.8% | 42.9% | 2/5 |
| R16 | 88 | Richard FrombergClay | 100 | Adrian VoineaClay | 7-5 6-3 | 3 | 92 | 4 | 5 | 51.3% | 76.9% | 54.1% | 8/9 |
| R16 | 35 | Albert PortasClay | 94 | Davide SanguinettiClay | 6-4 6-3 | 3 | 74 | 3 | 4 | 61.6% | 60.0% | 53.6% | 10/12 |
| R16 | 50 | Francisco ClavetClay | 467 | Tomas BehrendClay | 7-6(5) 6-4 | 3 | 82 | 1 | 1 | 66.2% | 76.7% | 54.5% | 1/3 |
| R16 | 59 | Javier SanchezClay | 9 | Alex CorretjaClay | 6-3 4-6 7-5 | 3 | 133 | 0 | 1 | 75.0% | 63.6% | 50.0% | 4/8 |
| QF | 43 | Marc-Kevin GoellnerClay | 86 | Carlos CostaClay | 6-2 7-6(5) | 3 | 88 | 7 | 3 | 46.4% | 78.1% | 35.1% | 3/7 |
| QF | 84 | Andrea GaudenziClay | 89 | Nicolas LapenttiClay | 6-2 6-4 | 3 | 86 | 0 | 0 | 53.8% | 64.3% | 75.0% | 2/3 |
| QF | 88 | Richard FrombergClay | 35 | Albert PortasClay | 6-4 6-3 | 3 | 75 | 5 | 1 | 68.6% | 77.1% | 27.3% | 5/7 |
| QF | 50 | Francisco ClavetClay | 59 | Javier SanchezClay | 4-6 6-2 6-3 | 3 | 114 | 0 | 2 | 71.6% | 63.5% | 36.0% | 3/8 |
| SF | 84 | Andrea GaudenziClay | 43 | Marc-Kevin GoellnerClay | 6-2 7-6(4) | 3 | 76 | 4 | 2 | 62.7% | 81.1% | 50.0% | 1/2 |
| SF | 88 | Richard FrombergClay | 50 | Francisco ClavetClay | 4-6 6-3 6-4 | 3 | 139 | 7 | 5 | 73.0% | 71.2% | 44.4% | 7/10 |
| F | 88 | Richard FrombergClay | 84 | Andrea GaudenziClay | 6-1 7-6(2) | 3 | 88 | 6 | 1 | 59.7% | 74.4% | 58.6% | 4/5 |
