| R32 | 89 |  Hernan GumyClay | 16 |  Alberto BerasateguiClay | 7-5 6-7(4) 3-0 RET | 3 | 135 | 1 | 5 | 49.3% | 64.9% | 52.6% | 3/7 |
| R32 | 91 |  Juan Antonio MarinClay | 134 |  Tuomas KetolaClay | 6-4 7-6(3) | 3 | 90 | 2 | 2 | 58.0% | 75.0% | 62.1% | 0/1 |
| R32 | 103 | Mariano PuertaClay | 76 |  Johan Van HerckClay | 6-3 6-2 | 3 | 72 | 2 | 3 | 65.5% | 75.0% | 63.2% | 3/3 |
| R32 | 146 | Emilio Benfele AlvarezClay | 49 |  Fernando MeligeniClay | 7-5 6-3 | 3 | 82 | 3 | 2 | 55.9% | 65.8% | 66.7% | 5/6 |
| R32 | 39 | Julian AlonsoClay | 151 | Jose Imaz-RuizClay | 6-4 6-4 | 3 | 87 | 1 | 5 | 59.7% | 78.4% | 64.0% | 3/3 |
| R32 | 78 | Alex CalatravaClay | 307 |  Emanuel CoutoClay | 6-3 7-5 | 3 | 94 | 11 | 1 | 62.5% | 85.7% | 52.4% | 1/2 |
| R32 | 105 |  Oliver GrossClay | 90 | Fernando VicenteClay | 6-4 6-3 | 3 | 87 | 3 | 2 | 51.4% | 60.5% | 61.1% | 8/10 |
| R32 | 54 | Carlos CostaClay | 128 | Marcello CracaClay | 6-4 6-4 | 3 | 93 | 3 | 1 | 50.7% | 63.9% | 57.1% | 5/7 |
| R32 | 56 | MARKarim AlamiClay | 233 | David SanchezClay | 6-4 6-2 | 3 | 70 | 7 | 0 | 62.5% | 66.7% | 61.1% | 0/2 |
| R32 | 63 |  Davide SanguinettiClay | 74 | Albert PortasClay | 7-6(8) 6-2 | 3 | 107 | 3 | 7 | 37.0% | 76.7% | 54.9% | 7/8 |
| R32 | 83 | Juan Albert Viloca-PuigClay | 219 | Oscar SerranoClay | 6-3 6-2 | 3 | 107 | 3 | 7 | 37.0% | 76.7% | 54.9% | 7/8 |
| R32 | 129 | Marzio MartelliClay | 65 | Galo BlancoClay | 7-5 6-7(5) 6-4 | 3 | 173 | 11 | 7 | 45.1% | 80.0% | 42.5% | 6/10 |
| R32 | 53 |  Dominik HrbatyClay | 72 | Javier SanchezClay | 6-4 4-6 6-3 | 3 | 97 | 1 | 6 | 58.9% | 71.7% | 64.9% | 7/9 |
| R32 | 121 | Jacobo DiazClay | 513 |  Andrei ChesnokovClay | 6-3 6-1 | 3 | 63 | 1 | 0 | 72.7% | 78.1% | 41.7% | 0/1 |
| R32 | 176 | Davide ScalaClay | 181 | Stefano PescosolidoClay | 6-3 6-1 | 3 | 67 | 4 | 0 | 48.9% | 90.9% | 56.5% | 0/0 |
| R32 | 100 | Franco SquillariClay | 32 | Francisco ClavetClay | 6-3 4-6 6-0 | 3 | 115 | 0 | 5 | 70.5% | 66.1% | 53.8% | 6/9 |
| R16 | 91 | Juan Antonio MarinClay | 89 | Hernan GumyClay | 6-4 6-2 | 3 | 85 | 4 | 1 | 55.2% | 71.9% | 50.0% | 4/6 |
| R16 | 103 | Mariano PuertaClay | 146 | Emilio Benfele AlvarezClay | 5-7 7-6(6) 6-3 | 3 | 150 | 3 | 2 | 58.0% | 72.3% | 59.6% | 4/7 |
| R16 | 39 | Julian AlonsoClay | 78 | Alex CalatravaClay | 6-2 7-6(1) | 3 | 97 | 4 | 4 | 64.2% | 63.5% | 65.5% | 12/13 |
| R16 | 54 | Carlos CostaClay | 105 | Oliver GrossClay | 6-2 6-2 | 3 | 72 | 3 | 3 | 54.3% | 72.0% | 61.9% | 2/3 |
| R16 | 56 | MARKarim AlamiClay | 63 | Davide SanguinettiClay | 7-6(1) 6-4 | 3 | 90 | 5 | 8 | 55.8% | 72.1% | 50.0% | 5/7 |
| R16 | 129 | Marzio MartelliClay | 83 | Juan Albert Viloca-PuigClay | 6-3 6-3 | 3 | 88 | 4 | 2 | 43.5% | 70.4% | 68.6% | 4/4 |
| R16 | 53 | Dominik HrbatyClay | 121 | Jacobo DiazClay | 7-6(1) 6-1 | 3 | 80 | 10 | 2 | 55.8% | 69.0% | 73.9% | 0/2 |
| R16 | 100 | Franco SquillariClay | 176 | Davide ScalaClay | 6-3 6-3 | 3 | 74 | 0 | 3 | 64.0% | 59.4% | 55.6% | 1/4 |
| QF | 91 | Juan Antonio MarinClay | 103 | Mariano PuertaClay | 6-1 6-3 | 3 | 79 | 1 | 1 | 73.2% | 61.0% | 80.0% | 4/4 |
| QF | 39 | Julian AlonsoClay | 54 | Carlos CostaClay | 6-3 7-6(6) | 3 | 93 | 1 | 4 | 63.5% | 72.3% | 40.7% | 5/7 |
| QF | 56 | MARKarim AlamiClay | 129 | Marzio MartelliClay | 6-4 6-4 | 3 | 82 | 2 | 0 | 63.9% | 71.8% | 59.1% | 3/4 |
| QF | 53 | Dominik HrbatyClay | 100 | Franco SquillariClay | 7-5 6-4 | 3 | 101 | 3 | 4 | 52.7% | 79.5% | 45.7% | 5/7 |
| SF | 39 | Julian AlonsoClay | 91 | Juan Antonio MarinClay | 7-5 6-3 | 3 | 85 | 2 | 4 | 55.6% | 87.5% | 46.9% | 3/3 |
| SF | 56 | MARKarim AlamiClay | 53 | Dominik HrbatyClay | 1-6 7-6(1) 7-5 | 3 | 139 | 6 | 1 | 56.6% | 65.0% | 50.0% | 6/10 |
| F | 39 | Julian AlonsoClay | 56 | MARKarim AlamiClay | 6-1 6-4 | 3 | 57 | 4 | 2 | 51.9% | 74.1% | 60.0% | 4/5 |
