| R32 | 36 |  Carlos CostaClay | 95 | Jordi ArreseClay | 6-4 6-3 | 3 | 76 | 2 | 3 | 50.0% | 76.9% | 53.8% | 1/3 |
| R32 | 237 | Jacobo DiazClay | 1181 |  Guillermo Perez-RoldanClay | 6-1 6-3 | 3 | 68 | 1 | 4 | 69.6% | 64.1% | 58.8% | 4/5 |
| R32 | 211 |  Jimy SzymanskiClay | 185 | Juan Albert Viloca-PuigClay | 6-4 6-2 | 3 | 85 | 3 | 5 | 70.9% | 74.4% | 50.0% | 4/5 |
| R32 | 28 | Felix MantillaClay | 152 |  Patrick BaurClay | 7-6(4) 6-2 | 3 | 81 | 2 | 0 | 92.5% | 79.6% | 100.0% | 0/1 |
| R32 | 35 |  Bohdan UlihrachClay | 129 |  Lionel RouxClay | 7-6(4) 6-4 | 3 | 103 | 4 | 3 | 57.1% | 70.5% | 57.6% | 2/4 |
| R32 | 112 |  Richard FrombergClay | 280 |  Herbert WiltschnigClay | 3-6 6-1 6-4 | 3 | 93 | 8 | 3 | 51.5% | 85.7% | 51.5% | 6/9 |
| R32 | 60 | Javier SanchezClay | 122 |  Omar CamporeseClay | 6-4 6-4 | 3 | 78 | 1 | 0 | 64.2% | 85.3% | 73.7% | 1/1 |
| R32 | 80 | MARHicham AraziClay | 42 |  Andrei MedvedevClay | 6-4 3-6 6-3 | 3 | 90 | 5 | 5 | 55.6% | 67.5% | 56.3% | 2/6 |
| R32 | 50 | Alberto BerasateguiClay | 113 |  Sandor NoszalyClay | 3-6 7-6(3) 6-0 | 3 | 113 | 1 | 0 | 76.0% | 68.4% | 66.7% | 2/4 |
| R32 | 115 | Galo BlancoClay | 68 | MARYounes El AynaouiClay | 6-3 6-2 | 3 | 59 | 5 | 2 | 67.4% | 80.6% | 73.3% | 0/0 |
| R32 | 88 |  Andrei ChesnokovClay | 119 | Cristiano CarattiClay | 7-5 6-1 | 3 | 74 | 2 | 1 | 64.9% | 70.3% | 55.0% | 1/3 |
| R32 | 32 | Gilbert SchallerClay | 178 | Rodolphe GilbertClay | 7-5 6-4 | 3 | 98 | 0 | 1 | 82.5% | 57.7% | 81.8% | 3/6 |
| R32 | 102 |  Kris GoossensClay | 52 | Filip DewulfClay | 6-4 3-6 6-4 | 3 | 131 | 2 | 2 | 94.8% | 81.8% | 33.3% | 0/3 |
| R32 | 57 | MARKarim AlamiClay | 65 | Roberto CarreteroClay | 4-6 7-6(8) 7-6(3) | 3 | 155 | 5 | 10 | 67.2% | 76.9% | 44.7% | 4/7 |
| R32 | 58 |  Christian RuudClay | 124 | Emilio SanchezClay | 6-4 7-5 | 3 | 122 | 0 | 3 | 50.0% | 63.9% | 66.7% | 3/4 |
| R32 | 34 | Francisco ClavetClay | 70 | Stefano PescosolidoClay | 6-2 6-3 | 3 | 66 | 1 | 0 | 67.6% | 68.0% | 100.0% | 0/1 |
| R16 | 36 | Carlos CostaClay | 237 | Jacobo DiazClay | 6-2 2-6 6-1 | 3 | 129 | 5 | 2 | 37.6% | 78.1% | 47.2% | 7/11 |
| R16 | 211 | Jimy SzymanskiClay | 28 | Felix MantillaClay | 6-2 5-7 6-4 | 3 | 140 | 5 | 5 | 42.0% | 72.7% | 47.4% | 14/17 |
| R16 | 35 | Bohdan UlihrachClay | 112 | Richard FrombergClay | 6-4 6-2 | 3 | 69 | 0 | 0 | 62.3% | 69.7% | 70.0% | 2/3 |
| R16 | 60 | Javier SanchezClay | 80 | MARHicham AraziClay | 6-0 6-4 | 3 | 59 | 0 | 2 | 69.1% | 68.4% | 47.1% | 2/3 |
| R16 | 50 | Alberto BerasateguiClay | 115 | Galo BlancoClay | 3-6 7-5 6-4 | 3 | 132 | 1 | 5 | 79.0% | 58.2% | 33.3% | 5/12 |
| R16 | 88 | Andrei ChesnokovClay | 32 | Gilbert SchallerClay | 6-4 6-4 | 3 | 107 | 3 | 2 | 56.4% | 71.0% | 29.2% | 2/7 |
| R16 | 57 | MARKarim AlamiClay | 102 | Kris GoossensClay | 6-4 4-6 6-2 | 3 | 117 | 2 | 2 | 53.4% | 71.8% | 61.8% | 1/4 |
| R16 | 34 | Francisco ClavetClay | 58 | Christian RuudClay | 6-4 6-2 | 3 | 78 | 1 | 1 | 60.0% | 60.6% | 54.5% | 2/5 |
| QF | 36 | Carlos CostaClay | 211 | Jimy SzymanskiClay | 7-5 2-6 6-3 | 3 | 122 | 5 | 4 | 50.0% | 69.0% | 47.6% | 6/11 |
| QF | 35 | Bohdan UlihrachClay | 60 | Javier SanchezClay | 6-4 6-4 | 3 | 74 | 2 | 1 | 63.2% | 72.2% | 61.9% | 5/7 |
| QF | 50 | Alberto BerasateguiClay | 88 | Andrei ChesnokovClay | 6-1 6-2 | 3 | 64 | 1 | 1 | 75.0% | 79.5% | 53.8% | 3/3 |
| QF | 34 | Francisco ClavetClay | 57 | MARKarim AlamiClay | 6-4 6-4 | 3 | 77 | 1 | 0 | 57.4% | 85.2% | 75.0% | 0/1 |
| SF | 36 | Carlos CostaClay | 35 | Bohdan UlihrachClay | 7-6(6) 6-1 | 3 | 89 | 3 | 1 | 52.5% | 68.8% | 51.7% | 0/2 |
| SF | 50 | Alberto BerasateguiClay | 34 | Francisco ClavetClay | 6-2 6-3 | 3 | 69 | 1 | 1 | 90.4% | 55.3% | 80.0% | 4/6 |
| F | 50 | Alberto BerasateguiClay | 36 | Carlos CostaClay | 6-3 6-4 | 3 | 72 | 0 | 1 | 81.0% | 61.7% | 72.7% | 5/7 |
