| R16 | 108 |  Jeff TarangoClay | 106 |  Nuno MarquesClay | 4-6 6-1 6-3 | 3 | 140 | 4 | 3 | 71.4% | 58.7% | 56.7% | 7/10 |
| R32 | 108 | Jeff TarangoClay | 24 | Derrick RostagnoClay | 6-4 6-1 | 3 | 65 | 1 | 4 | 65.2% | 70.0% | 62.5% | 0/2 |
| R32 | 106 | Nuno MarquesClay | 284 |  Federico MordeganClay | 6-3 6-2 | 3 | 85 | 2 | 4 | 47.6% | 70.0% | 60.6% | 7/7 |
| R32 | 92 |  Jaime OncinsClay | 81 |  Tomas CarbonellClay | 7-6(4) 6-2 | 3 | 105 | 1 | 1 | 53.8% | 66.7% | 47.2% | 3/5 |
| R32 | 68 |  Marian VajdaClay | 196 |  Vladimir GabrichidzeClay | 6-0 6-0 | 3 | 33 | 1 | 0 | 55.9% | 73.7% | 73.3% | 1/1 |
| R32 | 64 |  Thomas MusterClay | 112 |  Christian SaceanuClay | 6-4 6-4 | 3 | 61 | 2 | 2 | 70.6% | 80.6% | 60.0% | 1/2 |
| R32 | 99 |  Shuzo MatsuokaClay | 184 |  Felipe RiveraClay | 6-3 6-2 | 3 | 90 | 3 | 3 | 42.9% | 75.0% | 62.5% | 3/4 |
| R32 | 224 | Paolo CaneClay | 101 |  Jason StoltenbergClay | 6-3 6-1 | 3 | 66 | 3 | 0 | 71.1% | 81.3% | 53.8% | 3/4 |
| R32 | 55 | Javier SanchezClay | 105 |  Jacco EltinghClay | 4-6 6-2 6-4 | 3 | 110 | 2 | 0 | 75.0% | 62.5% | 54.2% | 7/11 |
| R32 | 109 |  Eduardo MassoClay | 52 | Francisco ClavetClay | 6-2 7-5 | 3 | 90 | 1 | 5 | 44.8% | 69.2% | 43.8% | 2/5 |
| R32 | 79 |  Wayne FerreiraClay | 82 | Pat CashClay | 7-6(4) 6-3 | 3 | 120 | 3 | 7 | 62.8% | 70.4% | 50.0% | 8/9 |
| R32 | 293 | Francesco CancellottiClay | 124 |  Tarik BenhabilesClay | 6-3 6-3 | 3 | 75 | 1 | 0 | 69.8% | 77.3% | 42.1% | 3/3 |
| R32 | 132 |  Jan GunnarssonClay | 30 | Richard FrombergClay | 6-3 6-1 | 3 | 75 | 1 | 0 | 69.8% | 77.3% | 42.1% | 3/3 |
| R32 | 78 | Luiz MattarClay | 86 | Alexander MronzClay | 3-6 6-2 6-1 | 3 | 89 | 6 | 3 | 59.7% | 81.1% | 52.0% | 0/2 |
| R32 | 114 | Pedro RebolledoClay | 133 | Martin SinnerClay | 6-1 6-2 | 3 | 70 | 0 | 0 | 40.9% | 66.7% | 53.8% | 3/5 |
| R32 | 115 | Joao Cunha-SilvaClay | 83 | Patrick BaurClay | 6-0 1-6 6-4 | 3 | 140 | 0 | 1 | 64.4% | 60.3% | 46.9% | 6/10 |
| R32 | 31 | Omar CamporeseClay | 137 | Diego NargisoClay | 6-1 3-6 6-2 | 3 | 111 | 1 | 1 | 65.7% | 67.4% | 70.8% | 0/2 |
| R16 | 92 | Jaime OncinsClay | 68 | Marian VajdaClay | 6-2 6-2 | 3 | 71 | 1 | 1 | 60.4% | 81.3% | 42.9% | 4/5 |
| R16 | 64 | Thomas MusterClay | 99 | Shuzo MatsuokaClay | 7-6(6) 1-6 6-3 | 3 | 150 | 0 | 1 | 74.7% | 64.9% | 44.0% | 5/9 |
| R16 | 224 | Paolo CaneClay | 55 | Javier SanchezClay | 6-3 7-5 | 3 | 92 | 2 | 2 | 47.5% | 75.9% | 56.3% | 2/3 |
| R16 | 109 | Eduardo MassoClay | 79 | Wayne FerreiraClay | 7-6(5) 3-3 RET | 3 | 110 | 1 | 4 | 50.0% | 64.9% | 51.4% | 5/7 |
| R16 | 132 | Jan GunnarssonClay | 293 | Francesco CancellottiClay | 6-2 6-0 | 3 | 45 | 4 | 2 | 51.3% | 75.0% | 73.7% | 2/2 |
| R16 | 78 | Luiz MattarClay | 114 | Pedro RebolledoClay | 7-5 6-3 | 3 | 105 | 3 | 0 | 71.6% | 64.2% | 57.1% | 6/8 |
| R16 | 31 | Omar CamporeseClay | 115 | Joao Cunha-SilvaClay | 6-2 6-3 | 3 | 81 | 1 | 0 | 54.7% | 79.3% | 45.8% | 2/3 |
| QF | 108 | Jeff TarangoClay | 92 | Jaime OncinsClay | 4-6 6-3 6-2 | 3 | 130 | 1 | 4 | 73.6% | 68.8% | 34.8% | 7/10 |
| QF | 224 | Paolo CaneClay | 64 | Thomas MusterClay | 7-6(2) 7-5 | 3 | 125 | 4 | 0 | 64.8% | 67.8% | 56.3% | 4/6 |
| QF | 132 | Jan GunnarssonClay | 109 | Eduardo MassoClay | 6-0 6-2 | 3 | 60 | 2 | 1 | 42.2% | 84.2% | 61.5% | 1/1 |
| QF | 31 | Omar CamporeseClay | 78 | Luiz MattarClay | 6-2 6-1 | 3 | 85 | 2 | 0 | 56.7% | 63.2% | 62.1% | 10/10 |
| SF | 224 | Paolo CaneClay | 108 | Jeff TarangoClay | 6-4 6-4 | 3 | 89 | 7 | 0 | 40.6% | 61.5% | 57.9% | 4/6 |
| SF | 132 | Jan GunnarssonClay | 31 | Omar CamporeseClay | 7-6(3) 6-4 | 3 | 110 | 5 | 5 | 33.3% | 80.8% | 51.9% | 2/4 |
| F | 224 | Paolo CaneClay | 132 | Jan GunnarssonClay | 5-7 6-3 7-5 | 3 | 140 | 8 | 0 | 58.3% | 75.0% | 40.0% | 4/9 |
