| R32 | 89 |  Pavel KotovClay | 95 |  Marco CecchinatoClay | 6-1 6-2 | 3 | 59 | 1 | 3 | 81.0% | 73.5% | 37.5% | 1/2 |
| R32 | 122 |  Thiago MonteiroClay | 56 |  Daniel Elahi GalanClay | 5-7 6-4 6-4 | 3 | 182 | 9 | 2 | 65.3% | 74.2% | 51.4% | 4/6 |
| R32 | 19 |  Alexander ZverevClay | 81 |  Alex MolcanClay | 6-4 3-6 7-5 | 3 | 145 | 5 | 5 | 73.3% | 75.8% | 33.3% | 3/6 |
| R32 | 77 |  Luca Van AsscheClay | 191 |  Dragos Nicolae MadarasClay | 7-6(2) 6-4 | 3 | 107 | 3 | 3 | 58.1% | 88.9% | 30.8% | 2/5 |
| R32 | 437 | Leo BorgClay | 166 | Elias YmerClay | 7-6(5) 6-3 | 3 | 104 | 3 | 2 | 64.6% | 81.0% | 56.5% | 2/3 |
| R32 | 113 |  Federico CoriaClay | 63 | Sebastian BaezClay | 6-4 4-6 7-6(5) | 3 | 169 | 1 | 5 | 71.7% | 61.7% | 46.9% | 8/13 |
| R32 | 159 | Jozef KovalikClay | 35 |  Alejandro Davidovich FokinaClay | 6-3 6-4 | 3 | 96 | 1 | 3 | 75.4% | 67.4% | 40.0% | 1/3 |
| R32 | 139 |  Filip MisolicClay | 61 |  Dusan LajovicClay | 7-6(4) 7-6(4) | 3 | 115 | 6 | 1 | 68.3% | 76.8% | 42.3% | 5/8 |
| R32 | 75 | Matteo ArnaldiClay | 48 |  Emil RuusuvuoriClay | 6-4 2-6 7-6(0) | 3 | 134 | 9 | 3 | 56.2% | 80.0% | 56.4% | 2/5 |
| R32 | 58 | Sebastian OfnerClay | 34 | Tomas Martin EtcheverryClay | 4-6 6-1 7-5 | 3 | 122 | 6 | 3 | 56.3% | 75.5% | 55.3% | 6/8 |
| R32 | 53 | Bernabe Zapata MirallesClay | 167 |  Hugo DellienClay | 6-3 7-6(3) | 3 | 93 | 3 | 1 | 78.7% | 75.0% | 53.8% | 2/4 |
| R32 | 96 |  Alexander ShevchenkoClay | 100 | Juan Manuel CerundoloClay | 6-3 6-3 | 3 | 82 | 2 | 2 | 66.7% | 61.8% | 58.8% | 4/6 |
| R16 | 7 | Andrey RublevClay | 89 | Pavel KotovClay | 6-3 7-6(4) | 3 | 92 | 3 | 1 | 57.1% | 75.0% | 50.0% | 2/4 |
| R16 | 19 | Alexander ZverevClay | 122 | Thiago MonteiroClay | 6-1 6-0 | 3 | 60 | 3 | 1 | 80.5% | 78.8% | 50.0% | 2/2 |
| R16 | 20 | Francisco CerundoloClay | 77 | Luca Van AsscheClay | 6-2 6-3 | 3 | 81 | 5 | 3 | 57.1% | 78.1% | 41.7% | 4/5 |
| R16 | 113 | Federico CoriaClay | 437 | Leo BorgClay | 6-4 6-2 | 3 | 86 | 2 | 1 | 76.3% | 66.7% | 64.3% | 4/5 |
| R16 | 139 | Filip MisolicClay | 159 | Jozef KovalikClay | 4-6 7-6(6) 6-4 | 3 | 150 | 2 | 3 | 62.9% | 78.8% | 48.7% | 5/7 |
| R16 | 16 | Lorenzo MusettiClay | 75 | Matteo ArnaldiClay | 6-3 4-6 7-6(6) | 3 | 155 | 6 | 2 | 56.3% | 77.6% | 47.4% | 1/4 |
| R16 | 58 | Sebastian OfnerClay | 53 | Bernabe Zapata MirallesClay | 4-6 6-4 6-4 | 3 | 152 | 6 | 2 | 56.7% | 61.8% | 42.3% | 14/20 |
| R16 | 4 |  Casper RuudClay | 96 | Alexander ShevchenkoClay | 6-2 6-4 | 3 | 79 | 2 | 4 | 53.4% | 80.6% | 55.6% | 2/3 |
| QF | 7 | Andrey RublevClay | 19 | Alexander ZverevClay | 6-2 6-3 | 3 | 67 | 6 | 2 | 55.6% | 80.0% | 58.3% | 2/2 |
| QF | 20 | Francisco CerundoloClay | 113 | Federico CoriaClay | 6-3 6-3 | 3 | 90 | 3 | 6 | 58.3% | 65.7% | 40.0% | 5/8 |
| QF | 16 | Lorenzo MusettiClay | 139 | Filip MisolicClay | 4-6 6-1 6-2 | 3 | 125 | 5 | 1 | 61.7% | 74.0% | 61.3% | 3/4 |
| QF | 4 | Casper RuudClay | 58 | Sebastian OfnerClay | 6-3 6-4 | 3 | 88 | 2 | 2 | 51.6% | 81.8% | 61.3% | 4/4 |
| SF | 7 | Andrey RublevClay | 20 | Francisco CerundoloClay | 7-6(6) 6-7(7) 6-3 | 3 | 167 | 9 | 2 | 61.9% | 76.9% | 54.2% | 10/11 |
| SF | 4 | Casper RuudClay | 16 | Lorenzo MusettiClay | 6-3 7-5 | 3 | 106 | 5 | 1 | 65.3% | 74.5% | 60.0% | 1/1 |
| F | 7 | Andrey RublevClay | 4 | Casper RuudClay | 7-6(3) 6-0 | 3 | 91 | 6 | 1 | 73.3% | 81.8% | 50.0% | 2/3 |
