| R32 | 101 |  Diego JunqueiraClay | 75 |  Igor AndreevClay | 7-6(3) 3-6 6-4 | 3 | 141 | 0 | 1 | 77.8% | 68.6% | 50.0% | 6/10 |
| R32 | 275 |  Jonathan Dasnieres de VeigyClay | 727 |  Andreas VinciguerraClay | 6-1 1-6 6-3 | 3 | 101 | 3 | 7 | 66.7% | 73.9% | 39.1% | 2/5 |
| R32 | 51 |  Potito StaraceClay | 156 |  Julian ReisterClay | 7-6(6) 6-3 | 3 | 88 | 0 | 0 | 76.1% | 66.7% | 75.0% | 2/4 |
| R32 | 138 |  Teymuraz GabashviliClay | 234 |  Michael YaniClay | 6-3 3-6 6-3 | 3 | 129 | 3 | 5 | 55.9% | 69.2% | 58.5% | 0/1 |
| R32 | 79 | SLOBlaz KavcicClay | 106 | Julien BenneteauClay | 6-4 4-6 7-5 | 3 | 174 | 4 | 2 | 72.7% | 58.8% | 43.3% | 8/14 |
| R32 | 43 | Juan MonacoClay | 77 | Carlos BerlocqClay | 6-7(5) 7-6(7) 6-2 | 3 | 212 | 0 | 3 | 66.9% | 64.9% | 56.3% | 16/18 |
| R32 | 142 |  Ruben Ramirez HidalgoClay | 46 |  Andrey GolubevClay | 6-7(4) 6-1 6-2 | 3 | 131 | 1 | 3 | 52.6% | 60.0% | 55.6% | 7/10 |
| R32 | 311 | Michael RyderstedtClay | 90 | Maximo GonzalezClay | 6-4 2-6 6-2 | 3 | 125 | 6 | 0 | 68.8% | 67.9% | 62.5% | 1/3 |
| R32 | 182 | Guillermo OlasoClay | 196 |  Antonio VeicClay | 6-4 6-1 | 3 | 76 | 2 | 4 | 57.4% | 74.3% | 46.2% | 5/6 |
| R32 | 87 | Filippo VolandriClay | 33 | Tommy RobredoClay | 7-5 5-5 RET | 3 | 110 | 0 | 2 | 75.0% | 60.4% | 56.3% | 1/5 |
| R32 | 74 |  Andreas Haider-MaurerClay | 67 | Mikhail KukushkinClay | 7-5 6-2 | 3 | 86 | 11 | 3 | 56.8% | 71.4% | 37.5% | 5/8 |
| R32 | 71 | Pere RibaClay | 288 | Christian LindellClay | 6-4 6-2 | 3 | 89 | 3 | 1 | 55.6% | 76.7% | 54.2% | 2/4 |
| R16 | 5 | Robin SoderlingClay | 101 | Diego JunqueiraClay | 6-0 6-1 | 3 | 47 | 3 | 1 | 71.4% | 76.0% | 70.0% | 0/1 |
| R16 | 51 | Potito StaraceClay | 275 | Jonathan Dasnieres de VeigyClay | 6-0 6-7(5) 6-2 | 3 | 134 | 0 | 1 | 78.2% | 67.6% | 52.6% | 5/7 |
| R16 | 8 |  Tomas BerdychClay | 138 | Teymuraz GabashviliClay | 6-2 6-2 | 3 | 86 | 9 | 2 | 63.0% | 70.6% | 65.0% | 1/1 |
| R16 | 79 | SLOBlaz KavcicClay | 43 | Juan MonacoClay | W/O | 3 | - | 9 | 2 | 63.0% | 70.6% | 65.0% | 1/1 |
| R16 | 311 | Michael RyderstedtClay | 142 | Ruben Ramirez HidalgoClay | 6-4 6-2 | 3 | 91 | 6 | 4 | 68.8% | 75.0% | 40.0% | 6/7 |
| R16 | 14 | Nicolas AlmagroClay | 182 | Guillermo OlasoClay | 6-2 6-3 | 3 | 56 | 3 | 5 | 54.5% | 83.3% | 48.0% | 2/2 |
| R16 | 74 | Andreas Haider-MaurerClay | 87 | Filippo VolandriClay | 6-3 7-6(7) | 3 | 95 | 5 | 5 | 56.4% | 86.4% | 35.3% | 3/5 |
| R16 | 6 | David FerrerClay | 71 | Pere RibaClay | 6-2 7-6(4) | 3 | 125 | 1 | 3 | 47.2% | 79.4% | 63.2% | 4/4 |
| QF | 5 | Robin SoderlingClay | 51 | Potito StaraceClay | 6-3 6-4 | 3 | 72 | 6 | 3 | 50.0% | 88.0% | 72.0% | 0/0 |
| QF | 8 | Tomas BerdychClay | 79 | SLOBlaz KavcicClay | 6-1 6-4 | 3 | 79 | 2 | 3 | 57.4% | 74.2% | 60.9% | 0/0 |
| QF | 14 | Nicolas AlmagroClay | 311 | Michael RyderstedtClay | 6-4 7-6(4) | 3 | 83 | 11 | 5 | 56.7% | 73.7% | 55.2% | 1/4 |
| QF | 6 | David FerrerClay | 74 | Andreas Haider-MaurerClay | 6-1 6-1 | 3 | 56 | 2 | 0 | 51.4% | 68.4% | 88.9% | 2/2 |
| SF | 5 | Robin SoderlingClay | 8 | Tomas BerdychClay | 6-1 6-0 | 3 | 71 | 3 | 0 | 61.7% | 69.0% | 61.1% | 4/4 |
| SF | 6 | David FerrerClay | 14 | Nicolas AlmagroClay | 6-1 6-3 | 3 | 64 | 5 | 2 | 66.7% | 70.6% | 52.9% | 2/3 |
| F | 5 | Robin SoderlingClay | 6 | David FerrerClay | 6-2 6-2 | 3 | 67 | 4 | 3 | 51.2% | 85.7% | 55.0% | 0/1 |
