| R32 | 3 |  Rafael NadalClay | 66 |  Juan MonacoClay | 6-1 6-1 | 3 | 55 | 3 | 2 | 73.7% | 82.1% | 50.0% | 0/0 |
| R32 | 50 | Alberto MartinClay | 96 | Agustin CalleriClay | 6-1 6-1 | 3 | 48 | 0 | 0 | 60.5% | 87.0% | 60.0% | 1/1 |
| R32 | 73 | Guillermo Garcia-LopezClay | 98 |  Nicolas LapenttiClay | 7-5 6-1 | 3 | 85 | 0 | 2 | 67.7% | 73.8% | 30.0% | 5/8 |
| R32 | 31 | Juan Carlos FerreroClay | 136 |  Lukas DlouhyClay | 6-4 6-1 | 3 | 61 | 0 | 0 | 70.6% | 61.1% | 60.0% | 2/4 |
| R32 | 20 | Tommy RobredoClay | 112 | Michal TabaraClay | 7-5 6-0 | 3 | 69 | 2 | 1 | 66.7% | 73.5% | 64.7% | 1/2 |
| R32 | 67 |  Gael MonfilsClay | 104 |  Jonas BjorkmanClay | 6-2 6-2 | 3 | 64 | 4 | 2 | 45.3% | 75.0% | 62.1% | 6/7 |
| R32 | 1466 | Andreas VinciguerraClay | 132 | Michael RyderstedtClay | 6-3 6-1 | 3 | 69 | 6 | 1 | 61.4% | 85.2% | 64.7% | 1/1 |
| R32 | 27 |  Mikhail YouzhnyClay | 109 | Jerome HaehnelClay | 6-1 6-1 | 3 | 50 | 0 | 1 | 57.1% | 75.0% | 86.7% | 0/0 |
| R32 | 88 | Nicolas AlmagroClay | 44 | Jose AcasusoClay | 6-4 6-1 | 3 | 66 | 3 | 0 | 70.9% | 66.7% | 62.5% | 5/7 |
| R32 | 42 | Tomas BerdychClay | 71 |  Kevin KimClay | 6-2 6-3 | 3 | 67 | 6 | 1 | 57.9% | 84.8% | 58.3% | 2/2 |
| R32 | 63 | Mariano ZabaletaClay | 119 |  Raemon SluiterClay | 2-6 6-1 6-4 | 3 | 120 | 8 | 4 | 65.7% | 78.3% | 50.0% | 2/4 |
| R32 | 28 | Carlos MoyaClay | 130 | Alex CalatravaClay | 7-5 6-2 | 3 | 80 | 2 | 0 | 69.6% | 66.7% | 52.4% | 7/9 |
| R32 | 38 | Robin SoderlingClay | 85 |  Florian MayerClay | 6-2 6-4 | 3 | 69 | 3 | 1 | 63.8% | 81.1% | 57.1% | 2/2 |
| R32 | 80 | Oscar HernandezClay | 259 | Gorka FraileClay | 3-6 6-2 6-2 | 3 | 108 | 2 | 1 | 70.4% | 59.6% | 50.0% | 5/8 |
| R32 | 97 | Florent SerraClay | 68 |  Jarkko NieminenClay | 7-5 6-1 | 3 | 88 | 1 | 1 | 62.2% | 63.0% | 57.1% | 11/12 |
| R32 | 105 | Jiri VanekClay | 14 | Joachim JohanssonClay | 6-7(2) 7-6(2) 6-2 | 3 | 130 | 10 | 4 | 56.6% | 80.0% | 54.3% | 6/8 |
| R16 | 3 | Rafael NadalClay | 50 | Alberto MartinClay | 6-2 6-4 | 3 | 101 | 0 | 0 | 75.0% | 73.8% | 50.0% | 6/7 |
| R16 | 31 | Juan Carlos FerreroClay | 73 | Guillermo Garcia-LopezClay | 6-3 6-4 | 3 | 99 | 0 | 0 | 71.8% | 58.8% | 70.0% | 4/6 |
| R16 | 20 | Tommy RobredoClay | 67 | Gael MonfilsClay | 6-4 4-2 RET | 3 | 88 | 1 | 2 | 66.7% | 75.0% | 62.5% | 0/0 |
| R16 | 27 | Mikhail YouzhnyClay | 1466 | Andreas VinciguerraClay | 4-6 7-6(4) 7-5 | 3 | 157 | 8 | 9 | 50.9% | 70.2% | 43.6% | 2/8 |
| R16 | 42 | Tomas BerdychClay | 88 | Nicolas AlmagroClay | 4-6 6-3 6-4 | 3 | 123 | 7 | 3 | 57.5% | 70.5% | 48.9% | 6/8 |
| R16 | 63 | Mariano ZabaletaClay | 28 | Carlos MoyaClay | 7-6(3) 6-2 | 3 | 99 | 2 | 4 | 57.1% | 70.0% | 60.0% | 3/5 |
| R16 | 80 | Oscar HernandezClay | 38 | Robin SoderlingClay | 1-6 6-3 6-2 | 3 | 100 | 1 | 2 | 56.8% | 52.4% | 56.3% | 5/10 |
| R16 | 105 | Jiri VanekClay | 97 | Florent SerraClay | 6-4 1-6 6-3 | 3 | 149 | 6 | 2 | 41.0% | 70.7% | 40.7% | 16/21 |
| QF | 3 | Rafael NadalClay | 31 | Juan Carlos FerreroClay | 6-3 6-3 | 3 | 65 | 3 | 1 | 73.4% | 68.1% | 64.7% | 6/6 |
| QF | 20 | Tommy RobredoClay | 27 | Mikhail YouzhnyClay | 3-6 6-4 6-3 | 3 | 126 | 1 | 3 | 60.9% | 64.2% | 52.9% | 7/12 |
| QF | 42 | Tomas BerdychClay | 63 | Mariano ZabaletaClay | 6-3 6-2 | 3 | 66 | 6 | 2 | 66.0% | 74.2% | 87.5% | 1/1 |
| QF | 105 | Jiri VanekClay | 80 | Oscar HernandezClay | 6-4 6-2 | 3 | 100 | 5 | 2 | 55.9% | 78.8% | 57.7% | 4/4 |
| SF | 3 | Rafael NadalClay | 20 | Tommy RobredoClay | 6-3 6-3 | 3 | 90 | 0 | 1 | 70.7% | 65.9% | 41.2% | 7/9 |
| SF | 42 | Tomas BerdychClay | 105 | Jiri VanekClay | 7-5 6-1 | 3 | 76 | 3 | 3 | 64.2% | 72.1% | 58.3% | 5/6 |
| F | 3 | Rafael NadalClay | 42 | Tomas BerdychClay | 2-6 6-2 6-4 | 3 | 120 | 1 | 1 | 71.8% | 62.7% | 60.0% | 5/9 |
