| R16 | 27 |  Marin CilicClay | 18 |  Tommy RobredoClay | 7-5 6-7(3) 7-6(5) | 3 | 167 | 8 | 2 | 52.1% | 75.4% | 60.7% | 5/6 |
| R16 | 17 |  Kei NishikoriClay | 60 |  Andrey GolubevClay | 6-0 6-4 | 3 | 76 | 3 | 2 | 71.2% | 61.9% | 47.1% | 4/6 |
| R16 | 23 |  Ernests GulbisClay | 59 | Albert MontanesClay | 7-5 6-1 | 3 | 75 | 6 | 1 | 70.6% | 77.8% | 60.0% | 0/1 |
| R16 | 55 |  Teymuraz GabashviliClay | 824 | Inigo CervantesClay | 6-4 6-2 | 3 | 80 | 1 | 1 | 51.0% | 88.5% | 52.0% | 1/2 |
| QF | 20 | Nicolas AlmagroClay | 1 | Rafael NadalClay | 2-6 7-6(5) 6-4 | 3 | 167 | 4 | 2 | 53.7% | 66.2% | 44.6% | 13/18 |
| QF | 65 |  Santiago GiraldoClay | 26 |  Philipp KohlschreiberClay | 6-4 4-3 RET | 3 | 67 | 4 | 0 | 63.0% | 67.6% | 55.0% | 1/3 |
| QF | 17 | Kei NishikoriClay | 27 | Marin CilicClay | 6-1 6-3 | 3 | 71 | 2 | 2 | 61.7% | 75.9% | 50.0% | 1/2 |
| QF | 23 | Ernests GulbisClay | 55 | Teymuraz GabashviliClay | 6-1 6-4 | 3 | 88 | 1 | 0 | 70.4% | 73.7% | 68.8% | 5/5 |
| SF | 65 | Santiago GiraldoClay | 20 | Nicolas AlmagroClay | 7-5 6-3 | 3 | 86 | 7 | 0 | 69.3% | 76.9% | 47.8% | 6/7 |
| SF | 17 | Kei NishikoriClay | 23 | Ernests GulbisClay | 6-2 6-4 | 3 | 86 | 1 | 3 | 62.0% | 80.6% | 63.2% | 0/0 |
| F | 17 | Kei NishikoriClay | 65 | Santiago GiraldoClay | 6-2 6-2 | 3 | 73 | 2 | 1 | 52.8% | 75.0% | 52.0% | 1/2 |
| R64 | 103 | Albert Ramos-VinolasClay | 82 |  Nikolay DavydenkoClay | 6-4 6-4 | 3 | 84 | 3 | 0 | 64.9% | 75.7% | 60.0% | 1/2 |
| R64 | 131 | Andrey KuznetsovClay | 58 | Pablo Carreno BustaClay | 2-6 6-1 6-2 | 3 | 94 | 3 | 2 | 47.8% | 69.7% | 50.0% | 2/5 |
| R64 | 60 | Andrey GolubevClay | 190 |  Matteo ViolaClay | 6-4 6-3 | 3 | 75 | 4 | 2 | 67.9% | 72.2% | 58.8% | 4/5 |
| R64 | 45 | Roberto Bautista AgutClay | 75 |  Lukasz KubotClay | 6-1 6-0 | 3 | 61 | 2 | 1 | 72.3% | 79.4% | 53.8% | 8/8 |
| R64 | 59 | Albert MontanesClay | 1014 | Marc LopezClay | 7-6(4) 6-2 | 3 | 102 | 2 | 4 | 71.6% | 70.8% | 47.4% | 6/8 |
| R64 | 104 | Daniel Gimeno-TraverClay | 187 | Roberto Carballes BaenaClay | 6-3 7-5 | 3 | 92 | 2 | 1 | 53.0% | 74.3% | 48.4% | 5/7 |
| R64 | 824 | Inigo CervantesClay | 72 | Aleksandr NedovyesovClay | 3-6 6-2 6-4 | 3 | 124 | 1 | 3 | 52.3% | 75.0% | 49.0% | 9/11 |
| R64 | 55 | Teymuraz GabashviliClay | 77 | Michal PrzysieznyClay | 6-3 6-4 | 3 | 71 | 5 | 1 | 72.4% | 81.0% | 56.3% | 4/5 |
| R64 | 37 | Ivan DodigClay | 107 |  Facundo ArguelloClay | 6-3 6-7(5) 6-2 | 3 | 120 | 6 | 2 | 58.9% | 77.4% | 70.3% | 6/7 |
| R64 | 63 |  Kenny De SchepperClay | 154 |  Marsel IlhanClay | 6-3 7-5 | 3 | 85 | 6 | 3 | 74.7% | 72.6% | 47.6% | 6/6 |
| R64 | 108 |  Martin KlizanClay | 100 |  Somdev DevvarmanClay | 6-2 6-4 | 3 | 79 | 0 | 1 | 68.0% | 70.6% | 62.5% | 3/4 |
| R64 | 65 | Santiago GiraldoClay | 56 |  Igor SijslingClay | 6-4 6-2 | 3 | 59 | 3 | 0 | 75.9% | 68.3% | 76.9% | 0/0 |
| R64 | 80 |  Dominic ThiemClay | 41 |  Radek StepanekClay | 6-4 6-4 | 3 | 71 | 5 | 3 | 50.8% | 84.8% | 43.8% | 3/4 |
| R64 | 46 | Edouard Roger-VasselinClay | 141 | Andreas BeckClay | 6-2 6-2 | 3 | 68 | 11 | 1 | 67.9% | 77.8% | 58.8% | 6/6 |
| R64 | 73 | Jurgen MelzerClay | 57 | Mikhail KukushkinClay | 7-6(5) 3-6 6-3 | 3 | 149 | 5 | 4 | 52.7% | 81.6% | 45.5% | 2/6 |
| R64 | 70 |  Marinko MatosevicClay | 40 |  Joao SousaClay | 6-3 6-2 | 3 | 74 | 4 | 0 | 64.2% | 76.5% | 52.6% | 1/2 |
| R32 | 1 | Rafael NadalClay | 103 | Albert Ramos-VinolasClay | 7-6(2) 6-4 | 3 | 117 | 1 | 0 | 72.9% | 68.6% | 63.2% | 2/4 |
| R32 | 37 | Ivan DodigClay | 30 | Feliciano LopezClay | 6-1 6-4 | 3 | 61 | 10 | 0 | 62.2% | 82.1% | 76.5% | 0/0 |
| R32 | 25 | Fernando VerdascoClay | 63 | Kenny De SchepperClay | 6-4 6-3 | 3 | 79 | 1 | 1 | 74.1% | 70.0% | 64.3% | 7/8 |
| R32 | 20 | Nicolas AlmagroClay | 108 | Martin KlizanClay | 7-5 7-6(4) | 3 | 109 | 12 | 2 | 56.3% | 80.0% | 61.3% | 2/3 |
| R32 | 65 | Santiago GiraldoClay | 13 | Fabio FogniniClay | 6-0 4-0 RET | 3 | 38 | 2 | 0 | 73.3% | 81.8% | 50.0% | 0/0 |
| R32 | 80 | Dominic ThiemClay | 31 | Marcel GranollersClay | 3-6 6-3 6-2 | 3 | 135 | 0 | 1 | 61.2% | 57.1% | 55.0% | 9/13 |
| R32 | 26 | Philipp KohlschreiberClay | 46 | Edouard Roger-VasselinClay | 7-6(4) 6-2 | 3 | 81 | 10 | 2 | 58.7% | 81.1% | 57.7% | 1/2 |
| R32 | 73 | Jurgen MelzerClay | 21 | Jerzy JanowiczClay | 6-4 7-6(1) | 3 | 92 | 5 | 3 | 66.2% | 64.4% | 47.8% | 3/7 |
| R32 | 18 | Tommy RobredoClay | 70 | Marinko MatosevicClay | 6-3 6-4 | 3 | 82 | 1 | 0 | 69.4% | 69.8% | 47.4% | 3/5 |
| R32 | 27 | Marin CilicClay | 131 | Andrey KuznetsovClay | 6-1 7-6(2) | 3 | 77 | 10 | 1 | 58.2% | 87.2% | 46.4% | 4/5 |
| R32 | 60 | Andrey GolubevClay | 36 | Benoit PaireClay | 6-4 5-1 RET | 3 | 61 | 1 | 2 | 70.6% | 77.8% | 33.3% | 2/3 |
| R32 | 17 | Kei NishikoriClay | 45 | Roberto Bautista AgutClay | 6-1 4-6 6-3 | 3 | 118 | 5 | 2 | 58.4% | 68.9% | 46.9% | 3/7 |
| R32 | 59 | Albert MontanesClay | 22 |  Alexandr DolgopolovClay | 7-6(5) 6-3 | 3 | 93 | 3 | 1 | 71.6% | 83.0% | 33.3% | 4/4 |
| R32 | 23 | Ernests GulbisClay | 104 | Daniel Gimeno-TraverClay | 7-5 7-6(1) | 3 | 97 | 4 | 1 | 63.2% | 83.7% | 56.0% | 1/3 |
| R32 | 824 | Inigo CervantesClay | 34 | Dmitry TursunovClay | 5-7 6-0 6-3 | 3 | 103 | 2 | 2 | 51.4% | 78.4% | 40.0% | 3/7 |
| R32 | 55 | Teymuraz GabashviliClay | 5 | David FerrerClay | 6-4 6-2 | 3 | 81 | 1 | 2 | 50.8% | 66.7% | 59.4% | 7/8 |
| R16 | 1 | Rafael NadalClay | 37 | Ivan DodigClay | 6-3 6-3 | 3 | 84 | 1 | 0 | 75.0% | 69.4% | 75.0% | 0/1 |
| R16 | 20 | Nicolas AlmagroClay | 25 | Fernando VerdascoClay | 6-3 6-3 | 3 | 73 | 4 | 0 | 47.9% | 87.0% | 60.0% | 3/4 |
| R16 | 65 | Santiago GiraldoClay | 80 | Dominic ThiemClay | 4-6 6-4 7-5 | 3 | 147 | 4 | 1 | 68.9% | 67.1% | 51.4% | 18/21 |
| R16 | 26 | Philipp KohlschreiberClay | 73 | Jurgen MelzerClay | 7-5 6-3 | 3 | 86 | 3 | 1 | 59.7% | 73.0% | 68.0% | 2/2 |
