| R64 | 37 |  Juan MonacoClay | 70 |  Grigor DimitrovClay | 6-4 6-1 | 3 | 78 | 1 | 1 | 71.4% | 65.0% | 56.3% | 7/8 |
| R64 | 60 |  Daniel Gimeno-TraverClay | 43 |  Potito StaraceClay | 4-6 6-1 2-0 RET | 3 | 72 | 6 | 0 | 52.6% | 83.3% | 55.6% | 2/3 |
| R64 | 107 | Albert Ramos-VinolasClay | 97 | Ruben Ramirez HidalgoClay | 4-6 7-6(5) 7-5 | 3 | 192 | 5 | 3 | 59.8% | 70.5% | 43.9% | 7/13 |
| R64 | 54 |  Santiago GiraldoClay | 32 |  Thomaz BellucciClay | 7-5 6-3 | 3 | 106 | 3 | 1 | 63.7% | 67.2% | 36.4% | 7/10 |
| R64 | 17 |  Richard GasquetClay | 40 | Juan Ignacio ChelaClay | 2-6 7-6(2) 6-4 | 3 | 153 | 1 | 6 | 63.2% | 67.2% | 43.6% | 6/11 |
| R64 | 87 | SLOBlaz KavcicClay | 79 |  Tobias KamkeClay | 6-2 6-3 | 3 | 84 | 3 | 1 | 79.2% | 71.4% | 54.5% | 3/4 |
| R64 | 59 |  Robin HaaseClay | 161 | Flavio CipollaClay | 6-4 6-3 | 3 | 90 | 2 | 2 | 57.6% | 60.5% | 60.7% | 8/10 |
| R64 | 56 |  Ivan DodigClay | 150 | Vincent MillotClay | 6-2 6-3 | 3 | 85 | 2 | 0 | 59.4% | 60.5% | 57.7% | 5/7 |
| R64 | 125 | Simon GreulClay | 84 |  Robert KendrickClay | 6-4 6-4 | 3 | 73 | 1 | 2 | 57.1% | 80.6% | 51.9% | 2/3 |
| R64 | 28 |  Milos RaonicClay | 68 |  Radek StepanekClay | 6-4 6-2 | 3 | 73 | 7 | 1 | 57.1% | 89.3% | 52.4% | 0/0 |
| R64 | 26 | Guillermo Garcia-LopezClay | 55 |  Denis IstominClay | 7-6(6) 6-3 | 3 | 94 | 1 | 5 | 66.7% | 69.0% | 38.1% | 3/7 |
| R64 | 42 | Feliciano LopezClay | 65 |  Mikhail KukushkinClay | 6-2 6-7(7) 6-4 | 3 | 148 | 16 | 2 | 56.7% | 84.3% | 51.3% | 4/6 |
| R64 | 48 |  Kei NishikoriClay | 76 | Pere RibaClay | 6-2 RET | 3 | 37 | 0 | 1 | 56.5% | 69.2% | 70.0% | 2/3 |
| R64 | 52 | Marcel GranollersClay | 102 | Daniel BrandsClay | 7-5 6-7(5) 6-1 | 3 | 168 | 2 | 4 | 66.7% | 71.1% | 47.4% | 7/10 |
| R64 | 121 | Benoit PaireClay | 314 | Pablo Carreno BustaClay | 6-7(7) 6-3 6-2 | 3 | 129 | 5 | 4 | 46.2% | 77.6% | 49.1% | 3/6 |
| R64 | 27 | Albert MontanesClay | 80 |  Teymuraz GabashviliClay | 6-2 6-2 | 3 | 107 | 4 | 2 | 62.5% | 71.1% | 48.1% | 9/10 |
| R64 | 35 |  Kevin AndersonClay | 62 |  Pablo CuevasClay | 7-5 3-6 6-4 | 3 | 140 | 6 | 2 | 74.7% | 75.0% | 56.5% | 6/8 |
| R64 | 66 |  Victor HanescuClay | 44 | Andrey GolubevClay | 6-3 6-2 | 3 | 85 | 0 | 1 | 71.7% | 76.3% | 40.0% | 0/1 |
| R64 | 72 | Carlos BerlocqClay | 57 |  Jarkko NieminenClay | 6-4 4-6 6-2 | 3 | 144 | 3 | 4 | 66.0% | 65.2% | 50.0% | 11/15 |
| R64 | 51 | Pablo AndujarClay | 326 | Gerard GranollersClay | 6-0 6-1 | 3 | 58 | 5 | 2 | 63.6% | 89.3% | 43.8% | 0/0 |
| R64 | 144 | Edouard Roger-VasselinClay | 209 |  Andrey KuznetsovClay | 6-2 6-4 | 3 | 77 | 1 | 0 | 66.0% | 71.0% | 68.8% | 1/2 |
| R64 | 39 | Nikolay DavydenkoClay | 20 |  Alexandr DolgopolovClay | 6-4 7-6(6) | 3 | 100 | 2 | 5 | 76.5% | 66.2% | 45.0% | 7/9 |
| R64 | 186 | Simone VagnozziClay | 49 | Fabio FogniniClay | 2-6 4-2 RET | 3 | 62 | 0 | 2 | 63.4% | 73.1% | 20.0% | 3/7 |
| R64 | 77 | Juan Carlos FerreroClay | 47 |  Xavier MalisseClay | 6-4 6-2 | 3 | 81 | 2 | 0 | 77.3% | 64.7% | 60.0% | 3/4 |
| R32 | 1 | Rafael NadalClay | 60 | Daniel Gimeno-TraverClay | 6-1 6-1 | 3 | 66 | 2 | 0 | 61.5% | 83.3% | 60.0% | 0/0 |
| R32 | 54 | Santiago GiraldoClay | 107 | Albert Ramos-VinolasClay | 6-3 4-6 6-3 | 3 | 142 | 9 | 3 | 64.0% | 66.2% | 45.0% | 7/10 |
| R32 | 17 | Richard GasquetClay | 87 | SLOBlaz KavcicClay | 6-3 4-6 6-2 | 3 | 118 | 1 | 0 | 68.5% | 76.0% | 65.2% | 4/7 |
| R32 | 9 | Gael MonfilsClay | 59 | Robin HaaseClay | 3-6 7-6(3) 6-2 | 3 | 124 | 4 | 4 | 58.2% | 56.6% | 55.3% | 4/9 |
| R32 | 56 | Ivan DodigClay | 5 |  Robin SoderlingClay | 6-2 6-4 | 3 | 83 | 9 | 1 | 61.9% | 69.2% | 50.0% | 7/9 |
| R32 | 28 | Milos RaonicClay | 125 | Simon GreulClay | 6-3 4-6 7-6(5) | 3 | 140 | 10 | 2 | 64.8% | 83.1% | 37.5% | 7/9 |
| R32 | 42 | Feliciano LopezClay | 26 | Guillermo Garcia-LopezClay | 6-7(2) 6-3 6-4 | 3 | 125 | 13 | 3 | 58.5% | 70.9% | 64.1% | 2/3 |
| R32 | 48 | Kei NishikoriClay | 95 |  Rui MachadoClay | 6-1 6-4 | 3 | 180 | 1 | 2 | 67.3% | 84.8% | 56.3% | 2/2 |
| R32 | 8 |  Jurgen MelzerClay | 52 | Marcel GranollersClay | 6-1 6-3 | 3 | 83 | 2 | 3 | 62.7% | 67.6% | 50.0% | 2/3 |
| R32 | 27 | Albert MontanesClay | 121 | Benoit PaireClay | 6-7(3) 6-1 6-4 | 3 | 122 | 1 | 3 | 76.2% | 67.5% | 52.0% | 7/9 |
| R32 | 66 | Victor HanescuClay | 35 | Kevin AndersonClay | 6-4 6-4 | 3 | 90 | 4 | 0 | 74.5% | 88.6% | 75.0% | 0/0 |
| R32 | 6 | David FerrerClay | 72 | Carlos BerlocqClay | 6-2 6-2 | 3 | 91 | 1 | 1 | 65.5% | 68.4% | 70.0% | 4/4 |
| R32 | 11 | Nicolas AlmagroClay | 51 | Pablo AndujarClay | 7-5 7-6(1) | 3 | 117 | 8 | 2 | 46.2% | 72.2% | 59.5% | 5/8 |
| R32 | 39 | Nikolay DavydenkoClay | 144 | Edouard Roger-VasselinClay | 6-2 7-6(11) | 3 | 108 | 0 | 1 | 77.9% | 61.7% | 52.9% | 6/9 |
| R32 | 186 | Simone VagnozziClay | 37 | Juan MonacoClay | 6-3 6-2 | 3 | 83 | 0 | 1 | 63.8% | 60.0% | 82.4% | 4/5 |
| R32 | 77 | Juan Carlos FerreroClay | 105 | Mischa ZverevClay | 6-4 7-5 | 3 | 100 | 3 | 1 | 73.6% | 66.0% | 57.9% | 2/4 |
| R16 | 1 | Rafael NadalClay | 54 | Santiago GiraldoClay | 6-3 6-1 | 3 | 83 | 1 | 2 | 64.2% | 70.6% | 52.6% | 2/3 |
| R16 | 9 | Gael MonfilsClay | 17 | Richard GasquetClay | 6-4 7-6(7) | 3 | 97 | 0 | 3 | 87.2% | 64.7% | 50.0% | 3/5 |
| R16 | 56 | Ivan DodigClay | 28 | Milos RaonicClay | 7-6(0) 4-6 6-3 | 3 | 150 | 9 | 3 | 71.9% | 69.5% | 46.9% | 8/11 |
| R16 | 42 | Feliciano LopezClay | 48 | Kei NishikoriClay | 6-4 7-6(5) | 3 | 106 | 4 | 2 | 55.0% | 72.7% | 58.3% | 3/4 |
| R16 | 8 | Jurgen MelzerClay | 27 | Albert MontanesClay | 6-7(2) 6-3 6-2 | 3 | 124 | 7 | 2 | 69.4% | 67.5% | 50.0% | 13/15 |
| R16 | 6 | David FerrerClay | 66 | Victor HanescuClay | 6-3 6-2 | 3 | 65 | 1 | 0 | 57.8% | 100.0% | 52.6% | 0/0 |
| R16 | 11 | Nicolas AlmagroClay | 39 | Nikolay DavydenkoClay | 7-6(2) 6-3 | 3 | 98 | 6 | 1 | 62.3% | 60.4% | 72.4% | 4/6 |
| R16 | 77 | Juan Carlos FerreroClay | 186 | Simone VagnozziClay | 7-6(3) 4-6 6-4 | 3 | 163 | 1 | 0 | 72.8% | 55.4% | 51.6% | 13/20 |
| QF | 1 | Rafael NadalClay | 9 | Gael MonfilsClay | 6-2 6-2 | 3 | 75 | 1 | 1 | 57.5% | 78.3% | 82.4% | 0/0 |
| QF | 56 | Ivan DodigClay | 42 | Feliciano LopezClay | 6-4 2-6 6-4 | 3 | 116 | 6 | 0 | 66.2% | 73.5% | 64.0% | 1/3 |
| QF | 6 | David FerrerClay | 8 | Jurgen MelzerClay | 6-3 6-3 | 3 | 87 | 0 | 3 | 65.6% | 80.0% | 38.1% | 4/5 |
| QF | 11 | Nicolas AlmagroClay | 77 | Juan Carlos FerreroClay | 6-3 6-3 | 3 | 65 | 6 | 1 | 46.8% | 77.3% | 56.0% | 3/5 |
| SF | 1 | Rafael NadalClay | 56 | Ivan DodigClay | 6-3 6-2 | 3 | 88 | 1 | 0 | 71.4% | 68.6% | 50.0% | 2/4 |
| SF | 6 | David FerrerClay | 11 | Nicolas AlmagroClay | 6-3 6-4 | 3 | 97 | 3 | 1 | 66.2% | 72.1% | 50.0% | 3/4 |
| F | 1 | Rafael NadalClay | 6 | David FerrerClay | 6-2 6-4 | 3 | 109 | 0 | 1 | 67.2% | 56.1% | 50.0% | 5/8 |
