| R64 | 42 | Guillermo Garcia-LopezClay | 122 | Christophe RochusClay | 5-7 6-1 6-3 | 3 | 120 | 3 | 3 | 58.6% | 73.2% | 55.2% | 1/5 |
| R64 | 39 | Victor HanescuClay | 81 | Andreas BeckClay | 6-1 6-2 | 3 | 67 | 4 | 0 | 75.0% | 83.3% | 70.0% | 0/0 |
| R64 | 33 | Thomaz BellucciClay | 64 | Jarkko NieminenClay | 6-4 6-4 | 3 | 88 | 2 | 0 | 66.7% | 65.0% | 45.0% | 2/4 |
| R64 | 143 | Simone BolelliClay | 20 | Tommy RobredoClay | 6-7(7) 6-4 3-1 RET | 3 | 131 | 5 | 1 | 67.0% | 67.7% | 50.0% | 6/8 |
| R64 | 137 | Alberto MartinClay | 121 | Mikhail KukushkinClay | 7-5 6-4 | 3 | 103 | 0 | 3 | 65.7% | 70.5% | 47.8% | 4/6 |
| R64 | 93 | Marcel GranollersClay | 41 | Lukasz KubotClay | 6-4 6-3 | 3 | 89 | 2 | 2 | 53.8% | 89.3% | 58.3% | 1/1 |
| R64 | 161 | Albert Ramos-VinolasClay | 72 | Michael RussellClay | 6-4 6-3 | 3 | 81 | 1 | 0 | 80.4% | 66.7% | 54.5% | 4/6 |
| R64 | 44 | Ernests GulbisClay | 73 | Peter LuczakClay | 7-6(4) 6-3 | 3 | 108 | 11 | 1 | 59.7% | 94.6% | 68.0% | 1/1 |
| R64 | 46 | Jeremy ChardyClay | 29 | Albert MontanesClay | 6-3 7-6(1) | 3 | 82 | 7 | 0 | 62.5% | 70.0% | 70.8% | 0/1 |
| R64 | 27 | Jurgen MelzerClay | 118 | Nicolas LapenttiClay | 6-3 6-3 | 3 | 76 | 7 | 5 | 61.2% | 78.0% | 50.0% | 10/10 |
| R64 | 100 | Oscar HernandezClay | 79 | Illya MarchenkoClay | 6-7(2) 6-2 6-4 | 3 | 157 | 3 | 0 | 68.8% | 67.2% | 55.2% | 4/7 |
| R64 | 78 | Richard GasquetClay | 48 | Igor AndreevClay | 7-6(5) 6-4 | 3 | 102 | 6 | 2 | 65.7% | 69.6% | 37.5% | 2/5 |
| R64 | 68 | Sergiy StakhovskyClay | 91 | Mischa ZverevClay | 4-6 6-4 6-2 | 3 | 116 | 4 | 0 | 63.4% | 66.1% | 52.9% | 5/8 |
| R64 | 67 | Thiemo de BakkerClay | 58 | Alejandro FallaClay | 6-1 6-0 | 3 | 44 | 3 | 0 | 58.5% | 66.7% | 82.4% | 0/0 |
| R64 | 92 | Daniel Gimeno-TraverClay | 24 | Juan MonacoClay | 6-2 3-6 6-2 | 3 | 123 | 7 | 2 | 58.9% | 75.5% | 45.9% | 12/13 |
| R64 | 34 | Nicolas AlmagroClay | 129 | Santiago VenturaClay | 6-1 6-2 | 3 | 60 | 10 | 1 | 61.5% | 87.5% | 73.3% | 0/0 |
| R64 | 60 | Simon GreulClay | 98 | Pere RibaClay | 6-4 6-4 | 3 | 86 | 1 | 1 | 62.5% | 70.0% | 62.5% | 2/3 |
| R64 | 86 | Jan HajekClay | 61 | Potito StaraceClay | 6-1 6-4 | 3 | 87 | 1 | 0 | 63.1% | 68.3% | 58.3% | 6/7 |
| R64 | 54 | Pablo CuevasClay | 50 | Horacio ZeballosClay | 7-6(2) 6-2 | 3 | 105 | 6 | 2 | 64.3% | 66.7% | 53.3% | 7/9 |
| R64 | 59 | Eduardo SchwankClay | 74 | Fabio FogniniClay | 6-1 6-3 | 3 | 64 | 2 | 2 | 65.9% | 81.5% | 78.6% | 2/2 |
| R64 | 32 | Lleyton HewittClay | 123 | Marsel IlhanClay | 6-4 4-6 6-2 | 3 | 118 | 10 | 3 | 57.7% | 73.3% | 48.5% | 1/5 |
| R64 | 35 | Feliciano LopezClay | 66 | Alexandr DolgopolovClay | 6-3 3-0 RET | 3 | 51 | 5 | 0 | 53.1% | 88.2% | 60.0% | 0/0 |
| R64 | 84 | Denis IstominClay | 65 | Stephane RobertClay | 7-6(5) 1-6 6-1 | 3 | 128 | 2 | 4 | 75.7% | 61.7% | 46.2% | 8/11 |
| R64 | 53 | Juan Ignacio ChelaClay | 328 | Filip KrajinovicClay | 6-1 6-4 | 3 | 78 | 0 | 0 | 75.5% | 56.8% | 58.3% | 5/8 |
| R32 | 42 | Guillermo Garcia-LopezClay | 113 | Teymuraz GabashviliClay | 1-6 7-6(5) 6-4 | 3 | 148 | 6 | 0 | 64.6% | 67.9% | 62.1% | 0/3 |
| R32 | 33 | Thomaz BellucciClay | 39 | Victor HanescuClay | 6-2 1-6 7-5 | 3 | 122 | 7 | 0 | 61.4% | 70.4% | 50.0% | 8/11 |
| R32 | 143 | Simone BolelliClay | 137 | Alberto MartinClay | 7-6(2) 7-6(1) | 3 | 107 | 3 | 1 | 68.1% | 77.6% | 47.8% | 0/2 |
| R32 | 17 | David FerrerClay | 93 | Marcel GranollersClay | 7-5 6-4 | 3 | 107 | 0 | 1 | 47.1% | 62.5% | 66.7% | 1/3 |
| R32 | 161 | Albert Ramos-VinolasClay | 12 | Fernando GonzalezClay | 6-4 6-7(8) 6-3 | 3 | 135 | 3 | 1 | 76.8% | 67.1% | 65.2% | 4/6 |
| R32 | 44 | Ernests GulbisClay | 46 | Jeremy ChardyClay | 6-3 6-2 | 3 | 78 | 5 | 2 | 62.1% | 77.8% | 50.0% | 3/4 |
| R32 | 27 | Jurgen MelzerClay | 100 | Oscar HernandezClay | 6-7(4) 7-5 7-5 | 3 | 168 | 4 | 1 | 69.0% | 66.7% | 60.0% | 8/11 |
| R32 | 9 | Fernando VerdascoClay | 78 | Richard GasquetClay | 7-5 6-3 | 3 | 80 | 1 | 2 | 77.4% | 70.8% | 57.1% | 3/4 |
| R32 | 16 | Juan Carlos FerreroClay | 68 | Sergiy StakhovskyClay | 6-3 4-2 RET | 3 | 66 | 1 | 0 | 76.7% | 63.6% | 80.0% | 3/4 |
| R32 | 67 | Thiemo de BakkerClay | 92 | Daniel Gimeno-TraverClay | 7-6(5) 6-3 | 3 | 86 | 5 | 0 | 63.2% | 83.7% | 52.0% | 0/1 |
| R32 | 34 | Nicolas AlmagroClay | 60 | Simon GreulClay | 6-1 6-3 | 3 | 65 | 9 | 1 | 57.9% | 90.9% | 75.0% | 0/0 |
| R32 | 10 | Jo-Wilfried TsongaClay | 86 | Jan HajekClay | 6-3 6-2 | 3 | 65 | 5 | 0 | 78.4% | 82.5% | 54.5% | 2/2 |
| R32 | 112 | Ivan NavarroClay | 54 | Pablo CuevasClay | 6-2 6-4 | 3 | 73 | 4 | 1 | 77.2% | 77.3% | 53.8% | 3/3 |
| R32 | 59 | Eduardo SchwankClay | 32 | Lleyton HewittClay | 7-6(3) 6-4 | 3 | 104 | 4 | 0 | 61.8% | 76.2% | 53.8% | 0/1 |
| R32 | 35 | Feliciano LopezClay | 84 | Denis IstominClay | 7-6(7) 7-5 | 3 | 104 | 10 | 4 | 60.3% | 85.1% | 58.1% | 3/3 |
| R32 | 8 | Robin SoderlingClay | 53 | Juan Ignacio ChelaClay | 7-5 7-5 | 3 | 90 | 5 | 1 | 58.5% | 73.7% | 59.3% | 1/3 |
| R16 | 33 | Thomaz BellucciClay | 42 | Guillermo Garcia-LopezClay | 6-4 6-4 | 3 | 107 | 2 | 2 | 69.7% | 71.7% | 50.0% | 4/5 |
| R16 | 17 | David FerrerClay | 143 | Simone BolelliClay | 6-0 3-0 RET | 3 | 45 | 0 | 0 | 64.0% | 62.5% | 77.8% | 0/0 |
| R16 | 44 | Ernests GulbisClay | 161 | Albert Ramos-VinolasClay | 6-1 6-3 | 3 | 62 | 9 | 1 | 68.8% | 81.8% | 53.3% | 1/1 |
| R16 | 9 | Fernando VerdascoClay | 27 | Jurgen MelzerClay | 3-6 7-6(1) 6-3 | 3 | 133 | 5 | 3 | 62.4% | 66.7% | 57.9% | 2/6 |
| R16 | 67 | Thiemo de BakkerClay | 16 | Juan Carlos FerreroClay | 7-6(2) 3-6 7-6(4) | 3 | 154 | 16 | 1 | 65.4% | 72.1% | 58.3% | 7/10 |
| R16 | 10 | Jo-Wilfried TsongaClay | 34 | Nicolas AlmagroClay | 5-7 6-1 6-4 | 3 | 123 | 8 | 1 | 64.0% | 75.4% | 53.1% | 4/6 |
| R16 | 59 | Eduardo SchwankClay | 112 | Ivan NavarroClay | 6-3 7-6(7) | 3 | 132 | 1 | 1 | 63.8% | 75.0% | 76.0% | 1/1 |
| R16 | 8 | Robin SoderlingClay | 35 | Feliciano LopezClay | 6-3 6-2 | 3 | 58 | 11 | 2 | 51.0% | 88.0% | 66.7% | 0/0 |
| QF | 17 | David FerrerClay | 33 | Thomaz BellucciClay | 6-4 6-0 | 3 | 93 | 0 | 1 | 62.5% | 67.5% | 58.3% | 4/4 |
| QF | 9 | Fernando VerdascoClay | 44 | Ernests GulbisClay | 6-2 7-6(4) | 3 | 117 | 3 | 5 | 78.3% | 69.2% | 38.9% | 8/9 |
| QF | 67 | Thiemo de BakkerClay | 10 | Jo-Wilfried TsongaClay | 6-4 3-6 6-3 | 3 | 126 | 5 | 0 | 57.3% | 67.4% | 59.4% | 2/5 |
| QF | 8 | Robin SoderlingClay | 59 | Eduardo SchwankClay | 6-2 6-3 | 3 | 68 | 7 | 2 | 61.8% | 85.3% | 52.4% | 1/1 |
| SF | 9 | Fernando VerdascoClay | 17 | David FerrerClay | 6-7(3) 7-5 6-1 | 3 | 156 | 4 | 2 | 73.9% | 72.1% | 50.0% | 1/3 |
| SF | 8 | Robin SoderlingClay | 67 | Thiemo de BakkerClay | 6-1 6-4 | 3 | 76 | 3 | 2 | 43.1% | 68.0% | 60.6% | 4/5 |
| F | 9 | Fernando VerdascoClay | 8 | Robin SoderlingClay | 6-3 4-6 6-3 | 3 | 124 | 3 | 2 | 75.3% | 65.6% | 75.0% | 3/5 |