| R64 | 155 | Juan Ignacio ChelaClay | 73 | Thomaz BellucciClay | 6-2 3-6 6-4 | 3 | 126 | 2 | 2 | 67.9% | 75.5% | 52.0% | 4/6 |
| R64 | 38 | Igor KunitsynClay | 70 | Juan Carlos FerreroClay | 7-5 7-6(3) | 3 | 115 | 4 | 0 | 86.7% | 58.3% | 63.6% | 5/8 |
| R64 | 57 | Arnaud ClementClay | 113 | Guillermo CanasClay | 7-6(0) 6-3 | 3 | 113 | 5 | 1 | 73.3% | 81.8% | 37.5% | 2/4 |
| R64 | 117 | Santiago VenturaClay | 93 | Marcel GranollersClay | 7-6(3) 6-3 | 3 | 116 | 5 | 0 | 50.0% | 76.3% | 57.9% | 5/7 |
| R64 | 33 | Feliciano LopezClay | 50 | Jarkko NieminenClay | 6-2 6-1 | 3 | 52 | 8 | 3 | 57.5% | 82.6% | 64.7% | 2/2 |
| R64 | 19 | Radek StepanekClay | 71 | Guillermo Garcia-LopezClay | 6-4 2-6 6-4 | 3 | 125 | 3 | 4 | 70.2% | 72.7% | 53.6% | 11/13 |
| R64 | 55 | Janko TipsarevicClay | 32 | Albert MontanesClay | 6-4 7-6(1) | 3 | 123 | 7 | 1 | 57.1% | 72.9% | 50.0% | 7/9 |
| R64 | 72 | Mikhail YouzhnyClay | 36 | Viktor TroickiClay | 6-7(5) 7-6(6) 6-3 | 3 | 164 | 1 | 1 | 74.4% | 67.8% | 41.9% | 3/7 |
| R64 | 966 | Gaston GaudioClay | 77 | Diego JunqueiraClay | 6-4 3-6 6-4 | 3 | 134 | 5 | 2 | 62.0% | 58.1% | 52.6% | 6/11 |
| R64 | 102 | Alberto MartinClay | 53 | Marc GicquelClay | 6-3 6-4 | 3 | 83 | 4 | 3 | 61.7% | 70.3% | 52.2% | 5/8 |
| R64 | 26 | Igor AndreevClay | 40 | Andreas SeppiClay | 6-3 3-6 7-5 | 3 | 131 | 9 | 5 | 57.1% | 62.5% | 52.4% | 5/9 |
| R64 | 24 | Robin SoderlingClay | 67 | Teymuraz GabashviliClay | 6-1 6-4 | 3 | 61 | 7 | 2 | 66.0% | 75.8% | 64.7% | 1/2 |
| R64 | 101 | Potito StaraceClay | 42 | Ernests GulbisClay | 4-6 6-3 6-3 | 3 | 105 | 1 | 1 | 68.9% | 66.7% | 73.9% | 5/8 |
| R64 | 172 | Mikhail KukushkinClay | 146 | Pere RibaClay | 6-2 7-6(5) | 3 | 94 | 5 | 1 | 63.5% | 70.2% | 51.9% | 5/6 |
| R64 | 45 | Jose AcasusoClay | 59 | Dudi SelaClay | 6-4 7-5 | 3 | 98 | 4 | 2 | 55.7% | 66.7% | 61.3% | 3/5 |
| R64 | 83 | Daniel Gimeno-TraverClay | 84 | Fabio FogniniClay | 6-1 6-3 | 3 | 65 | 3 | 0 | 66.0% | 63.6% | 58.8% | 1/3 |
| R64 | 58 | Juan MonacoClay | 20 | Marat SafinClay | 6-4 6-1 | 3 | 66 | 2 | 1 | 78.8% | 80.5% | 54.5% | 2/2 |
| R64 | 28 | Tomas BerdychClay | 48 | Martin Vassallo ArguelloClay | 5-2 RET | 3 | 40 | 1 | 1 | 75.0% | 72.2% | 66.7% | 1/1 |
| R64 | 68 | Oscar HernandezClay | 54 | Eduardo SchwankClay | 6-2 6-4 | 3 | 78 | 5 | 0 | 69.4% | 64.7% | 73.3% | 0/2 |
| R64 | 74 | Nicolas LapenttiClay | 37 | Paul-Henri MathieuClay | 6-4 2-6 6-2 | 3 | 124 | 6 | 0 | 65.8% | 70.0% | 65.4% | 5/7 |
| R32 | 1 | Rafael NadalClay | 75 | Fred GilClay | 6-2 6-2 | 3 | 90 | 1 | 0 | 66.7% | 67.6% | 70.6% | 3/3 |
| R32 | 61 | Christophe RochusClay | 21 | Richard GasquetClay | 6-1 6-7(2) 6-3 | 3 | 137 | 6 | 1 | 64.6% | 72.6% | 45.0% | 7/9 |
| R32 | 22 | Nicolas AlmagroClay | 155 | Juan Ignacio ChelaClay | 3-6 7-6(4) 6-3 | 3 | 144 | 11 | 0 | 58.3% | 69.6% | 47.5% | 5/11 |
| R32 | 15 | David NalbandianClay | 38 | Igor KunitsynClay | 7-5 6-4 | 3 | 87 | 1 | 4 | 48.4% | 70.0% | 40.6% | 2/6 |
| R32 | 8 | Nikolay DavydenkoClay | 57 | Arnaud ClementClay | 7-6(2) 6-2 | 3 | 117 | 5 | 1 | 73.5% | 80.0% | 50.0% | 2/2 |
| R32 | 33 | Feliciano LopezClay | 117 | Santiago VenturaClay | 2-6 6-4 6-3 | 3 | 117 | 3 | 0 | 60.0% | 66.7% | 55.3% | 6/9 |
| R32 | 19 | Radek StepanekClay | 55 | Janko TipsarevicClay | 7-6(2) 6-0 | 3 | 94 | 4 | 1 | 56.6% | 80.0% | 65.2% | 2/3 |
| R32 | 12 | Stan WawrinkaClay | 72 | Mikhail YouzhnyClay | 7-5 6-1 | 3 | 88 | 6 | 1 | 63.4% | 68.9% | 61.5% | 9/10 |
| R32 | 16 | Tommy RobredoClay | 966 | Gaston GaudioClay | 7-6(6) 6-1 | 3 | 91 | 2 | 2 | 56.9% | 73.0% | 46.4% | 4/6 |
| R32 | 26 | Igor AndreevClay | 102 | Alberto MartinClay | 6-2 6-2 | 3 | 63 | 1 | 0 | 68.3% | 85.7% | 69.2% | 1/1 |
| R32 | 101 | Potito StaraceClay | 24 | Robin SoderlingClay | 7-6(5) 2-6 6-2 | 3 | 123 | 5 | 0 | 73.7% | 71.2% | 42.3% | 8/11 |
| R32 | 13 | David FerrerClay | 172 | Mikhail KukushkinClay | 6-3 3-6 6-1 | 3 | 120 | 2 | 0 | 68.3% | 66.1% | 57.7% | 6/8 |
| R32 | 14 | Fernando GonzalezClay | 45 | Jose AcasusoClay | 6-4 6-4 | 3 | 72 | 3 | 2 | 69.6% | 82.1% | 58.8% | 4/4 |
| R32 | 58 | Juan MonacoClay | 83 | Daniel Gimeno-TraverClay | 7-5 6-4 | 3 | 85 | 1 | 0 | 76.9% | 66.0% | 53.3% | 5/7 |
| R32 | 28 | Tomas BerdychClay | 68 | Oscar HernandezClay | 6-2 4-6 6-3 | 3 | 122 | 8 | 1 | 53.9% | 72.9% | 48.8% | 5/8 |
| R32 | 7 | Fernando VerdascoClay | 74 | Nicolas LapenttiClay | 7-5 6-3 | 3 | 99 | 1 | 3 | 76.8% | 66.0% | 50.0% | 4/6 |
| R16 | 1 | Rafael NadalClay | 61 | Christophe RochusClay | 6-2 6-0 | 3 | 56 | 3 | 1 | 77.5% | 67.7% | 88.9% | 0/0 |
| R16 | 15 | David NalbandianClay | 22 | Nicolas AlmagroClay | 6-3 6-4 | 3 | 64 | 3 | 1 | 56.1% | 78.1% | 52.0% | 3/5 |
| R16 | 8 | Nikolay DavydenkoClay | 33 | Feliciano LopezClay | 7-6(8) 3-6 6-4 | 3 | 162 | 4 | 1 | 69.7% | 73.7% | 60.6% | 7/9 |
| R16 | 19 | Radek StepanekClay | 12 | Stan WawrinkaClay | 6-4 1-6 7-5 | 3 | 139 | 2 | 4 | 62.9% | 62.3% | 44.4% | 7/11 |
| R16 | 16 | Tommy RobredoClay | 26 | Igor AndreevClay | 4-6 6-2 6-3 | 3 | 122 | 2 | 4 | 57.6% | 75.5% | 53.8% | 5/6 |
| R16 | 13 | David FerrerClay | 101 | Potito StaraceClay | 4-6 7-5 6-2 | 3 | 132 | 4 | 2 | 63.3% | 64.5% | 63.9% | 6/9 |
| R16 | 14 | Fernando GonzalezClay | 58 | Juan MonacoClay | 7-6(6) 6-3 | 3 | 87 | 8 | 1 | 62.0% | 75.0% | 59.3% | 1/2 |
| R16 | 7 | Fernando VerdascoClay | 28 | Tomas BerdychClay | 7-5 5-7 6-4 | 3 | 137 | 3 | 1 | 83.5% | 67.1% | 86.7% | 6/9 |
| QF | 1 | Rafael NadalClay | 15 | David NalbandianClay | W/O | 3 | - | 3 | 1 | 83.5% | 67.1% | 86.7% | 6/9 |
| QF | 8 | Nikolay DavydenkoClay | 19 | Radek StepanekClay | 6-7(4) 6-2 6-2 | 3 | 138 | 5 | 2 | 67.7% | 74.6% | 50.0% | 4/5 |
| QF | 13 | David FerrerClay | 16 | Tommy RobredoClay | 6-3 6-4 | 3 | 82 | 3 | 2 | 65.6% | 77.5% | 57.1% | 2/2 |
| QF | 14 | Fernando GonzalezClay | 7 | Fernando VerdascoClay | 6-3 4-6 6-4 | 3 | 137 | 7 | 1 | 63.2% | 76.1% | 38.5% | 4/7 |
| SF | 1 | Rafael NadalClay | 8 | Nikolay DavydenkoClay | 6-3 6-2 | 3 | 106 | 1 | 2 | 67.2% | 73.3% | 45.5% | 6/6 |
| SF | 13 | David FerrerClay | 14 | Fernando GonzalezClay | 2-6 6-2 7-6(5) | 3 | 133 | 1 | 2 | 71.3% | 67.2% | 55.6% | 5/8 |
| F | 1 | Rafael NadalClay | 13 | David FerrerClay | 6-2 7-5 | 3 | 106 | 1 | 1 | 58.5% | 63.2% | 55.6% | 4/7 |
| R64 | 75 | Fred GilClay | 63 | Yen-Hsun LuClay | 6-2 6-1 | 3 | 62 | 0 | 2 | 59.5% | 80.0% | 70.6% | 0/0 |
| R64 | 61 | Christophe RochusClay | 64 | Nicolas DevilderClay | 6-4 6-4 | 3 | 94 | 4 | 0 | 52.8% | 73.7% | 52.9% | 5/6 |
| R64 | 21 | Richard GasquetClay | 62 | Jan HernychClay | 4-6 6-3 6-2 | 3 | 110 | 7 | 3 | 63.7% | 72.5% | 58.6% | 1/3 |
| R64 | 22 | Nicolas AlmagroClay | 35 | Victor HanescuClay | 3-6 7-6(7) 2-2 RET | 3 | 122 | 8 | 3 | 59.0% | 80.4% | 50.0% | 4/5 |