| R64 | 45 | Potito StaraceClay | 93 | Peter LuczakClay | 7-6(4) 6-1 | 3 | 90 | 3 | 0 | 75.4% | 79.1% | 78.6% | 0/0 |
| R64 | 132 | Alberto MartinClay | 414 | Matteo MarraiClay | 6-3 6-3 | 3 | 70 | 4 | 2 | 52.9% | 63.0% | 58.3% | 1/3 |
| R64 | 35 | Feliciano LopezClay | 41 | Jose AcasusoClay | 5-2 RET | 3 | 36 | 2 | 0 | 35.7% | 100.0% | 77.8% | 0/0 |
| R64 | 37 | Juan Ignacio ChelaClay | 79 | Guillermo Garcia-LopezClay | 6-7(2) 6-4 6-2 | 3 | 173 | 0 | 7 | 68.5% | 56.6% | 34.3% | 9/16 |
| R64 | 169 | Marc LopezClay | 68 | Ivo MinarClay | 3-1 RET | 3 | 24 | 1 | 0 | 66.7% | 100.0% | 25.0% | 1/1 |
| R64 | 86 | Ernests GulbisClay | 34 | Janko TipsarevicClay | 6-4 4-2 RET | 3 | 65 | 6 | 2 | 63.8% | 76.7% | 47.1% | 3/5 |
| R64 | 85 | Denis GremelmayrClay | 147 | Ruben Ramirez HidalgoClay | 7-6(7) 2-1 RET | 3 | 93 | 4 | 2 | 66.1% | 71.8% | 50.0% | 2/3 |
| R64 | 78 | Marcos DanielClay | 118 | Ivan NavarroClay | 6-1 6-4 | 3 | 69 | 4 | 0 | 60.9% | 85.7% | 66.7% | 0/0 |
| R64 | 32 | Dmitry TursunovClay | 101 | Kevin AndersonClay | 6-4 6-3 | 3 | 81 | 9 | 0 | 62.3% | 81.8% | 70.0% | 0/0 |
| R64 | 22 | Nicolas AlmagroClay | 103 | Viktor TroickiClay | 6-2 RET | 3 | 27 | 2 | 0 | 70.0% | 92.9% | 50.0% | 0/0 |
| R64 | 42 | Filippo VolandriClay | 70 | Jurgen MelzerClay | 6-2 6-4 | 3 | 67 | 0 | 3 | 79.7% | 62.7% | 38.5% | 6/9 |
| R64 | 51 | Mario AncicClay | 71 | Mischa ZverevClay | 6-1 6-0 | 3 | 42 | 6 | 1 | 71.4% | 95.0% | 62.5% | 0/0 |
| R64 | 87 | Albert MontanesClay | 54 | Marcel GranollersClay | 3-6 6-3 6-2 | 3 | 112 | 2 | 8 | 50.5% | 66.0% | 45.7% | 8/13 |
| R64 | 106 | Pablo CuevasClay | 122 | Juan Pablo BrzezickiClay | 6-3 7-6(3) | 3 | 82 | 9 | 1 | 66.7% | 70.8% | 62.5% | 3/5 |
| R64 | 146 | Mikhail KukushkinClay | 24 | Jarkko NieminenClay | 6-4 6-4 | 3 | 86 | 2 | 1 | 69.0% | 67.5% | 61.1% | 3/5 |
| R64 | 27 | Stan WawrinkaClay | 293 | Jose Antonio Sanchez-de LunaClay | 6-3 6-3 | 3 | 81 | 1 | 1 | 51.0% | 69.2% | 60.0% | 3/5 |
| R64 | 141 | Yuri SchukinClay | 95 | Robby GinepriClay | 6-4 6-2 | 3 | 83 | 3 | 4 | 67.6% | 64.0% | 58.3% | 8/9 |
| R64 | 60 | Agustin CalleriClay | 64 | Thomas JohanssonClay | 6-1 6-3 | 3 | 62 | 6 | 0 | 52.2% | 79.2% | 68.2% | 2/2 |
| R64 | 56 | Robin HaaseClay | 260 | Max MirnyiClay | 6-2 6-2 | 3 | 54 | 3 | 0 | 63.6% | 75.0% | 75.0% | 2/2 |
| R64 | 138 | Teymuraz GabashviliClay | 811 | Guillermo CoriaClay | 5-7 6-4 6-4 | 3 | 135 | 5 | 3 | 59.6% | 66.1% | 50.0% | 5/10 |
| R64 | 31 | Guillermo CanasClay | 72 | Oscar HernandezClay | 6-1 6-4 | 3 | 93 | 4 | 1 | 42.9% | 75.0% | 59.4% | 2/3 |
| R64 | 83 | Nicolas LapenttiClay | 29 | Fernando VerdascoClay | 6-3 6-4 | 3 | 111 | 5 | 2 | 65.4% | 68.6% | 48.1% | 7/8 |
| R64 | 131 | Daniel Gimeno-TraverClay | 81 | Santiago VenturaClay | 6-2 6-1 | 3 | 61 | 5 | 0 | 81.1% | 80.0% | 71.4% | 1/1 |
| R64 | 237 | Gabriel Trujillo-SolerClay | 124 | Werner EschauerClay | 6-4 4-6 6-2 | 3 | 100 | 7 | 1 | 72.2% | 71.9% | 72.7% | 5/6 |
| R32 | 2 | Rafael NadalClay | 45 | Potito StaraceClay | 6-4 6-2 | 3 | 78 | 2 | 1 | 72.9% | 74.3% | 84.6% | 2/3 |
| R32 | 35 | Feliciano LopezClay | 132 | Alberto MartinClay | 3-6 6-2 6-4 | 3 | 120 | 12 | 3 | 58.5% | 74.5% | 43.6% | 9/12 |
| R32 | 37 | Juan Ignacio ChelaClay | 169 | Marc LopezClay | 5-1 RET | 3 | 37 | 0 | 1 | 52.4% | 72.7% | 60.0% | 1/1 |
| R32 | 86 | Ernests GulbisClay | 14 | Carlos MoyaClay | 4-6 6-1 6-4 | 3 | 106 | 6 | 2 | 55.2% | 81.3% | 51.3% | 5/6 |
| R32 | 85 | Denis GremelmayrClay | 8 | James BlakeClay | 6-1 6-4 | 3 | 68 | 5 | 1 | 51.9% | 74.1% | 72.0% | 1/1 |
| R32 | 32 | Dmitry TursunovClay | 78 | Marcos DanielClay | 6-4 6-3 | 3 | 75 | 4 | 0 | 67.2% | 84.6% | 52.6% | 3/3 |
| R32 | 22 | Nicolas AlmagroClay | 42 | Filippo VolandriClay | 6-4 7-6(5) | 3 | 91 | 16 | 1 | 60.0% | 82.1% | 38.5% | 0/2 |
| R32 | 51 | Mario AncicClay | 19 | Andy MurrayClay | 6-4 6-4 | 3 | 101 | 3 | 1 | 62.3% | 70.8% | 51.7% | 5/6 |
| R32 | 87 | Albert MontanesClay | 21 | Ivo KarlovicClay | 6-7(7) 6-3 7-5 | 3 | 134 | 6 | 2 | 72.9% | 79.1% | 53.1% | 8/8 |
| R32 | 146 | Mikhail KukushkinClay | 106 | Pablo CuevasClay | 6-0 6-4 | 3 | 63 | 2 | 1 | 64.7% | 69.7% | 72.2% | 2/2 |
| R32 | 27 | Stan WawrinkaClay | 141 | Yuri SchukinClay | 6-3 6-4 | 3 | 85 | 5 | 2 | 63.8% | 83.8% | 47.6% | 2/2 |
| R32 | 7 | David NalbandianClay | 60 | Agustin CalleriClay | 1-6 7-6(2) 6-3 | 3 | 119 | 2 | 4 | 64.9% | 62.0% | 48.1% | 1/5 |
| R32 | 17 | Tommy RobredoClay | 56 | Robin HaaseClay | 6-2 6-4 | 3 | 73 | 1 | 0 | 84.4% | 76.3% | 71.4% | 2/3 |
| R32 | 31 | Guillermo CanasClay | 138 | Teymuraz GabashviliClay | 6-1 6-2 | 3 | 79 | 5 | 1 | 51.2% | 77.3% | 61.9% | 0/0 |
| R32 | 83 | Nicolas LapenttiClay | 131 | Daniel Gimeno-TraverClay | 6-3 6-7(5) 7-5 | 3 | 173 | 0 | 2 | 60.2% | 57.6% | 53.8% | 4/9 |
| R32 | 5 | David FerrerClay | 237 | Gabriel Trujillo-SolerClay | 6-1 6-1 | 3 | 50 | 1 | 1 | 61.5% | 79.2% | 66.7% | 1/1 |
| R16 | 2 | Rafael NadalClay | 35 | Feliciano LopezClay | 6-4 6-3 | 3 | 106 | 3 | 1 | 66.0% | 78.8% | 70.6% | 0/0 |
| R16 | 37 | Juan Ignacio ChelaClay | 86 | Ernests GulbisClay | 2-6 6-4 6-3 | 3 | 106 | 2 | 4 | 57.3% | 67.4% | 62.5% | 3/5 |
| R16 | 85 | Denis GremelmayrClay | 32 | Dmitry TursunovClay | 6-4 6-0 | 3 | 63 | 6 | 0 | 66.0% | 72.7% | 52.9% | 4/5 |
| R16 | 22 | Nicolas AlmagroClay | 51 | Mario AncicClay | 7-6(5) 6-2 | 3 | 97 | 5 | 0 | 57.8% | 86.5% | 63.0% | 2/2 |
| R16 | 87 | Albert MontanesClay | 146 | Mikhail KukushkinClay | 6-3 3-6 6-3 | 3 | 114 | 1 | 1 | 62.3% | 79.2% | 41.4% | 1/4 |
| R16 | 27 | Stan WawrinkaClay | 7 | David NalbandianClay | 6-3 6-1 | 3 | 85 | 1 | 1 | 54.2% | 62.5% | 70.4% | 9/10 |
| R16 | 17 | Tommy RobredoClay | 31 | Guillermo CanasClay | 6-1 7-5 | 3 | 79 | 3 | 0 | 86.5% | 75.6% | 42.9% | 1/2 |
| R16 | 5 | David FerrerClay | 83 | Nicolas LapenttiClay | 4-6 6-4 6-3 | 3 | 151 | 2 | 2 | 57.1% | 69.6% | 57.1% | 7/9 |
| QF | 2 | Rafael NadalClay | 37 | Juan Ignacio ChelaClay | 6-4 6-2 | 3 | 102 | 0 | 0 | 66.7% | 79.4% | 35.3% | 0/1 |
| QF | 85 | Denis GremelmayrClay | 22 | Nicolas AlmagroClay | 6-2 3-6 7-6(7) | 3 | 129 | 3 | 5 | 57.1% | 63.3% | 53.3% | 5/8 |
| QF | 27 | Stan WawrinkaClay | 87 | Albert MontanesClay | 6-3 6-7(6) 6-4 | 3 | 166 | 2 | 4 | 54.2% | 65.6% | 55.6% | 4/6 |
| QF | 5 | David FerrerClay | 17 | Tommy RobredoClay | 7-6(4) 6-4 | 3 | 126 | 1 | 0 | 61.5% | 66.7% | 50.0% | 5/8 |
| SF | 2 | Rafael NadalClay | 85 | Denis GremelmayrClay | 6-1 6-0 | 3 | 51 | 3 | 0 | 69.7% | 87.0% | 80.0% | 0/0 |
| SF | 5 | David FerrerClay | 27 | Stan WawrinkaClay | 7-6(8) 6-3 | 3 | 114 | 2 | 1 | 65.3% | 68.1% | 72.0% | 1/2 |
| F | 2 | Rafael NadalClay | 5 | David FerrerClay | 6-1 4-6 6-1 | 3 | 134 | 3 | 3 | 68.9% | 62.7% | 69.6% | 5/7 |