| R64 | 53 | Kristof VliegenClay | 107 | Davide SanguinettiClay | 6-2 6-4 | 3 | 76 | 4 | 1 | 62.3% | 69.8% | 50.0% | 7/8 |
| R64 | 73 | Thomas JohanssonClay | 42 | Hyung-Taik LeeClay | 6-3 6-3 | 3 | 77 | 9 | 2 | 46.8% | 75.9% | 63.6% | 9/9 |
| R64 | 27 | Robin SoderlingClay | 69 | Gaston GaudioClay | 6-1 6-0 | 3 | 43 | 2 | 0 | 54.3% | 89.5% | 68.8% | 0/0 |
| R64 | 103 | Simone BolelliClay | 26 | Marat SafinClay | 6-4 7-6(5) | 3 | 89 | 6 | 1 | 67.6% | 82.6% | 54.5% | 0/1 |
| R64 | 72 | Potito StaraceClay | 66 | Sam QuerreyClay | 6-4 6-4 | 3 | 89 | 1 | 2 | 77.1% | 70.4% | 68.8% | 4/4 |
| R64 | 78 | Vincent SpadeaClay | 71 | Teymuraz GabashviliClay | 6-3 3-6 6-1 | 3 | 98 | 1 | 3 | 66.7% | 74.1% | 48.1% | 5/7 |
| R64 | 94 | Alberto MartinClay | 98 | Alejandro FallaClay | 6-1 6-4 | 3 | 74 | 0 | 3 | 54.9% | 71.4% | 47.8% | 2/4 |
| R64 | 1009 | Felix MantillaClay | 178 | Farrukh DustovClay | 6-4 1-6 6-0 | 3 | 108 | 1 | 0 | 69.9% | 60.8% | 54.5% | 2/6 |
| R64 | 33 | Carlos MoyaClay | 153 | Marcel GranollersClay | 6-2 6-4 | 3 | 63 | 2 | 1 | 50.0% | 84.0% | 64.0% | 0/0 |
| R64 | 108 | Andrei PavelClay | 25 | Radek StepanekClay | 4-6 6-3 6-4 | 3 | 112 | 2 | 4 | 65.6% | 67.8% | 54.8% | 5/8 |
| R64 | 204 | Boris PashanskiClay | 100 | Carlos BerlocqClay | 4-0 RET | 3 | 22 | 0 | 0 | 81.8% | 77.8% | 100.0% | 0/0 |
| R64 | 114 | Paul GoldsteinClay | 133 | Fernando VicenteClay | 6-3 6-7(6) 6-3 | 3 | 132 | 1 | 4 | 69.1% | 71.6% | 66.7% | 4/5 |
| R64 | 95 | Andreas SeppiClay | 62 | Ivo KarlovicClay | 6-7(2) 7-5 6-3 | 3 | 166 | 3 | 4 | 67.7% | 80.0% | 51.6% | 0/1 |
| R64 | 43 | Benjamin BeckerClay | 90 | Igor KunitsynClay | 7-6(2) 6-4 | 3 | 96 | 4 | 1 | 63.0% | 65.2% | 74.1% | 4/5 |
| R64 | 99 | Oscar HernandezClay | 23 | Dmitry TursunovClay | 6-4 6-4 | 3 | 94 | 2 | 1 | 64.5% | 67.5% | 63.6% | 2/3 |
| R64 | 34 | Agustin CalleriClay | 207 | Marc LopezClay | 7-5 5-7 6-3 | 3 | 147 | 10 | 7 | 51.4% | 75.0% | 47.2% | 3/7 |
| R64 | 192 | Paolo LorenziClay | 101 | Stefano GalvaniClay | 6-7(6) 6-2 7-6(1) | 3 | 170 | 1 | 4 | 75.8% | 62.6% | 51.7% | 4/8 |
| R64 | 75 | Feliciano LopezClay | 60 | Guillermo Garcia-LopezClay | 7-5 6-3 | 3 | 84 | 7 | 3 | 57.7% | 68.3% | 50.0% | 5/7 |
| R64 | 185 | Pablo AndujarClay | 392 | Bartolome Salva-VidalClay | 6-4 6-0 | 3 | 80 | 0 | 3 | 68.5% | 67.6% | 41.2% | 4/6 |
| R64 | 124 | Jiri VanekClay | 259 | Juan Antonio MarinClay | 6-0 3-2 RET | 3 | 72 | 0 | 1 | 66.7% | 66.7% | 50.0% | 3/4 |
| R64 | 28 | Guillermo CanasClay | 48 | Max MirnyiClay | 6-2 7-6(4) | 3 | 84 | 3 | 2 | 61.9% | 79.5% | 58.3% | 4/6 |
| R64 | 32 | Nicolas AlmagroClay | 205 | Fabio FogniniClay | 6-3 6-2 | 3 | 58 | 6 | 0 | 53.2% | 80.0% | 72.7% | 1/2 |
| R64 | 55 | Filippo VolandriClay | 65 | Evgeny KorolevClay | 6-0 6-4 | 3 | 60 | 2 | 1 | 76.7% | 75.8% | 80.0% | 0/0 |
| R64 | 218 | Yuri SchukinClay | 97 | Werner EschauerClay | 6-4 6-4 | 3 | 89 | 1 | 1 | 72.5% | 67.6% | 57.1% | 1/3 |
| R32 | 2 | Rafael NadalClay | 53 | Kristof VliegenClay | 6-1 6-2 | 3 | 71 | 0 | 0 | 59.4% | 89.5% | 84.6% | 0/0 |
| R32 | 73 | Thomas JohanssonClay | 27 | Robin SoderlingClay | 7-6(4) 7-6(2) | 3 | 100 | 9 | 2 | 59.8% | 77.6% | 60.6% | 5/6 |
| R32 | 72 | Potito StaraceClay | 103 | Simone BolelliClay | 6-4 6-3 | 3 | 68 | 2 | 0 | 80.9% | 84.2% | 44.4% | 0/1 |
| R32 | 22 | Juan Ignacio ChelaClay | 78 | Vincent SpadeaClay | 6-3 6-3 | 3 | 86 | 3 | 2 | 70.3% | 73.3% | 15.8% | 4/7 |
| R32 | 14 | David NalbandianClay | 94 | Alberto MartinClay | 6-2 6-0 | 3 | 65 | 3 | 0 | 66.7% | 75.0% | 71.4% | 1/1 |
| R32 | 33 | Carlos MoyaClay | 1009 | Felix MantillaClay | 3-6 6-3 6-4 | 3 | 125 | 9 | 2 | 53.7% | 68.2% | 50.0% | 6/10 |
| R32 | 204 | Boris PashanskiClay | 108 | Andrei PavelClay | 6-3 4-6 6-2 | 3 | 105 | 2 | 1 | 66.7% | 71.4% | 53.6% | 4/6 |
| R32 | 16 | David FerrerClay | 114 | Paul GoldsteinClay | 6-0 6-0 | 3 | 44 | 4 | 1 | 70.7% | 75.9% | 41.7% | 1/1 |
| R32 | 20 | Jarkko NieminenClay | 95 | Andreas SeppiClay | 6-4 7-5 | 3 | 96 | 1 | 2 | 50.0% | 67.7% | 54.8% | 2/5 |
| R32 | 99 | Oscar HernandezClay | 43 | Benjamin BeckerClay | 6-1 7-6(4) | 3 | 79 | 6 | 3 | 71.9% | 73.2% | 56.3% | 2/4 |
| R32 | 34 | Agustin CalleriClay | 192 | Paolo LorenziClay | 6-2 6-2 | 3 | 58 | 3 | 0 | 69.4% | 88.0% | 90.9% | 0/0 |
| R32 | 5 | Tommy RobredoClay | 75 | Feliciano LopezClay | 6-2 6-2 | 3 | 69 | 2 | 2 | 86.7% | 63.5% | 62.5% | 3/4 |
| R32 | 185 | Pablo AndujarClay | 18 | Juan Carlos FerreroClay | 2-1 RET | 3 | 14 | 1 | 0 | 58.3% | 71.4% | 60.0% | 0/0 |
| R32 | 28 | Guillermo CanasClay | 124 | Jiri VanekClay | 6-1 6-1 | 3 | 53 | 4 | 1 | 53.8% | 81.0% | 72.2% | 1/1 |
| R32 | 55 | Filippo VolandriClay | 32 | Nicolas AlmagroClay | 6-7(5) 6-4 6-1 | 3 | 126 | 2 | 0 | 84.4% | 69.1% | 53.3% | 4/7 |
| R32 | 4 | Nikolay DavydenkoClay | 218 | Yuri SchukinClay | 6-4 3-6 6-2 | 3 | 104 | 7 | 2 | 62.9% | 82.1% | 65.2% | 0/2 |
| R16 | 2 | Rafael NadalClay | 73 | Thomas JohanssonClay | 6-1 6-4 | 3 | 70 | 1 | 1 | 73.0% | 96.3% | 60.0% | 0/0 |
| R16 | 72 | Potito StaraceClay | 22 | Juan Ignacio ChelaClay | 6-4 7-6(10) | 3 | 120 | 0 | 0 | 85.4% | 59.8% | 57.1% | 7/9 |
| R16 | 14 | David NalbandianClay | 33 | Carlos MoyaClay | 6-4 6-3 | 3 | 90 | 2 | 3 | 57.4% | 60.0% | 57.7% | 3/5 |
| R16 | 16 | David FerrerClay | 204 | Boris PashanskiClay | 6-2 7-5 | 3 | 100 | 5 | 0 | 69.2% | 66.7% | 56.3% | 0/3 |
| R16 | 99 | Oscar HernandezClay | 20 | Jarkko NieminenClay | 6-1 6-7(6) 6-3 | 3 | 161 | 3 | 3 | 66.1% | 67.5% | 48.8% | 17/19 |
| R16 | 34 | Agustin CalleriClay | 5 | Tommy RobredoClay | 6-4 2-6 6-3 | 3 | 111 | 2 | 3 | 55.8% | 72.1% | 44.1% | 0/5 |
| R16 | 28 | Guillermo CanasClay | 185 | Pablo AndujarClay | 7-5 6-3 | 3 | 108 | 1 | 3 | 51.6% | 65.6% | 63.3% | 3/5 |
| R16 | 4 | Nikolay DavydenkoClay | 55 | Filippo VolandriClay | 7-6(5) 7-6(6) | 3 | 128 | 5 | 3 | 63.7% | 64.7% | 48.3% | 5/10 |
| QF | 2 | Rafael NadalClay | 72 | Potito StaraceClay | 6-2 7-5 | 3 | 102 | 2 | 0 | 73.4% | 63.8% | 70.6% | 3/4 |
| QF | 16 | David FerrerClay | 14 | David NalbandianClay | 7-6(5) 6-2 | 3 | 86 | 4 | 2 | 63.3% | 81.6% | 59.1% | 0/0 |
| QF | 34 | Agustin CalleriClay | 99 | Oscar HernandezClay | 6-0 6-3 | 3 | 59 | 5 | 1 | 52.8% | 94.7% | 70.6% | 0/0 |
| QF | 28 | Guillermo CanasClay | 4 | Nikolay DavydenkoClay | W/O | 3 | - | 5 | 1 | 52.8% | 94.7% | 70.6% | 0/0 |
| SF | 2 | Rafael NadalClay | 16 | David FerrerClay | 7-5 6-1 | 3 | 95 | 0 | 1 | 77.4% | 63.4% | 58.3% | 1/3 |
| SF | 28 | Guillermo CanasClay | 34 | Agustin CalleriClay | 7-6(1) 6-7(5) 6-2 | 3 | 177 | 7 | 3 | 55.7% | 70.3% | 47.1% | 7/11 |
| F | 2 | Rafael NadalClay | 28 | Guillermo CanasClay | 6-3 6-4 | 3 | 101 | 2 | 0 | 75.5% | 82.5% | 61.5% | 2/2 |