| R64 | 112 | Albert PortasClay | 116 | Oscar HernandezClay | 6-2 6-4 | 3 | 78 | 7 | 2 | 47.5% | 85.7% | 61.3% | 5/5 |
| R64 | 38 | Feliciano LopezClay | 233 | Ivo KlecClay | 4-6 6-4 6-4 | 3 | 131 | 4 | 5 | 48.6% | 66.7% | 36.8% | 9/15 |
| R64 | 178 | Daniel Gimeno-TraverClay | 66 | Novak DjokovicClay | 6-4 3-6 6-3 | 3 | 133 | 2 | 5 | 66.7% | 70.0% | 34.3% | 7/10 |
| R64 | 164 | Ivan NavarroClay | 39 | Paradorn SrichaphanClay | 6-3 6-4 | 3 | 99 | 3 | 0 | 59.7% | 81.1% | 48.0% | 5/5 |
| R64 | 24 | Tomas BerdychClay | 91 | Albert MontanesClay | 4-6 7-5 7-5 | 3 | 146 | 13 | 5 | 57.3% | 71.4% | 46.8% | 7/11 |
| R64 | 86 | Philipp KohlschreiberClay | 95 | Raemon SluiterClay | 7-6(2) 7-6(0) | 3 | 93 | 1 | 1 | 69.4% | 80.0% | 54.5% | 0/0 |
| R64 | 347 | Galo BlancoClay | 108 | Tomas ZibClay | 6-7(3) 7-6(3) 6-2 | 3 | 164 | 12 | 4 | 59.8% | 72.4% | 43.1% | 11/14 |
| R64 | 57 | Nicolas AlmagroClay | 83 | Andrei PavelClay | 6-4 6-2 | 3 | 63 | 4 | 1 | 54.5% | 87.5% | 75.0% | 0/0 |
| R64 | 31 | Gael MonfilsClay | 183 | Stefano GalvaniClay | 6-2 7-5 | 3 | 91 | 2 | 1 | 63.2% | 69.4% | 61.9% | 2/3 |
| R64 | 28 | Juan Carlos FerreroClay | 50 | Kristof VliegenClay | 6-1 6-2 | 3 | 68 | 1 | 0 | 78.3% | 83.3% | 40.0% | 2/2 |
| R64 | 63 | Alberto MartinClay | 339 | Bartolome Salva-VidalClay | 6-4 6-2 | 3 | 89 | 3 | 1 | 59.6% | 80.6% | 61.9% | 2/2 |
| R64 | 249 | Albert CostaClay | 74 | Vincent SpadeaClay | 7-6(7) 4-6 6-1 | 3 | 157 | 3 | 6 | 75.9% | 65.9% | 40.7% | 10/14 |
| R64 | 77 | Potito StaraceClay | 80 | Lukas DlouhyClay | 6-4 6-2 | 3 | 58 | 1 | 0 | 83.3% | 80.0% | 50.0% | 0/0 |
| R64 | 61 | Agustin CalleriClay | 99 | Justin GimelstobClay | 6-2 6-1 | 3 | 159 | 6 | 0 | 76.9% | 76.7% | 66.7% | 0/0 |
| R64 | 32 | Fernando VerdascoClay | 78 | Robin VikClay | 6-3 6-4 | 3 | 70 | 2 | 3 | 74.5% | 65.9% | 57.1% | 2/4 |
| R64 | 225 | Carlos CuadradoClay | 33 | Dmitry TursunovClay | 4-6 6-0(3) 6-3 | 3 | 108 | 6 | 2 | 59.7% | 73.9% | 51.6% | 5/8 |
| R64 | 36 | Paul-Henri MathieuClay | 100 | Juan Antonio MarinClay | 7-6(3) 6-2 | 3 | 100 | 2 | 2 | 69.4% | 62.8% | 52.6% | 0/3 |
| R64 | 44 | Filippo VolandriClay | 255 | Andrea StoppiniClay | 6-3 6-1 | 3 | 59 | 0 | 0 | 54.0% | 63.0% | 52.2% | 0/2 |
| R64 | 43 | Andy MurrayClay | 291 | Marcel GranollersClay | 4-6 6-4 6-2 | 3 | 122 | 1 | 1 | 54.3% | 56.9% | 53.5% | 7/12 |
| R64 | 67 | Stan WawrinkaClay | 127 | Nicolas LapenttiClay | 6-2 6-7(3) 6-3 | 3 | 142 | 5 | 5 | 57.7% | 71.4% | 58.5% | 7/9 |
| R64 | 126 | Teymuraz GabashviliClay | 27 | Igor AndreevClay | 4-6 7-6(6) 7-6(0) | 3 | 148 | 4 | 1 | 82.5% | 75.0% | 72.7% | 1/2 |
| R64 | 159 | Evgeny KorolevClay | 35 | Carlos MoyaClay | 7-5 6-4 | 3 | 108 | 2 | 3 | 66.3% | 66.0% | 40.7% | 5/8 |
| R64 | 87 | Fernando VicenteClay | 184 | Alex CalatravaClay | 7-6(4) 6-4 | 3 | 106 | 5 | 3 | 69.4% | 72.9% | 38.5% | 4/6 |
| R64 | 56 | Ivo KarlovicClay | 59 | Max MirnyiClay | 6-3 6-4 | 3 | 67 | 16 | 3 | 76.0% | 86.8% | 58.3% | 0/0 |
| R32 | 2 | Rafael NadalClay | 38 | Feliciano LopezClay | 6-4 6-2 | 3 | 74 | 1 | 1 | 66.7% | 65.6% | 75.0% | 2/4 |
| R32 | 164 | Ivan NavarroClay | 178 | Daniel Gimeno-TraverClay | 7-6(5) 7-5 | 3 | 125 | 2 | 2 | 68.3% | 73.2% | 53.8% | 9/11 |
| R32 | 112 | Albert PortasClay | 24 | Tomas BerdychClay | 7-6(6) 6-3 | 3 | 97 | 10 | 3 | 62.5% | 80.0% | 44.4% | 2/3 |
| R32 | 20 | Jarkko NieminenClay | 86 | Philipp KohlschreiberClay | 6-1 6-2 | 3 | 73 | 1 | 2 | 61.7% | 67.6% | 56.5% | 9/10 |
| R32 | 9 | Guillermo CoriaClay | 347 | Galo BlancoClay | 6-7(4) 6-0 6-2 | 3 | 126 | 1 | 16 | 64.0% | 67.3% | 25.8% | 4/9 |
| R32 | 57 | Nicolas AlmagroClay | 31 | Gael MonfilsClay | 6-2 6-4 | 3 | 116 | 4 | 2 | 54.8% | 70.0% | 51.5% | 6/7 |
| R32 | 28 | Juan Carlos FerreroClay | 63 | Alberto MartinClay | 6-4 7-6(1) | 3 | 112 | 1 | 1 | 76.2% | 64.1% | 50.0% | 5/7 |
| R32 | 249 | Albert CostaClay | 21 | Dominik HrbatyClay | 6-3 7-5 | 3 | 82 | 2 | 0 | 77.3% | 64.7% | 40.0% | 3/6 |
| R32 | 15 | Tommy RobredoClay | 77 | Potito StaraceClay | 6-4 6-0 | 3 | 66 | 1 | 1 | 85.5% | 66.0% | 50.0% | 5/6 |
| R32 | 32 | Fernando VerdascoClay | 61 | Agustin CalleriClay | 7-5 6-4 | 3 | 85 | 2 | 5 | 68.7% | 80.4% | 42.9% | 4/5 |
| R32 | 36 | Paul-Henri MathieuClay | 225 | Carlos CuadradoClay | 7-6(4) 6-4 | 3 | 101 | 1 | 2 | 73.6% | 64.2% | 68.4% | 2/3 |
| R32 | 16 | Radek StepanekClay | 44 | Filippo VolandriClay | 3-6 7-6(0) 6-4 | 3 | 119 | 4 | 7 | 60.9% | 74.6% | 44.2% | 8/11 |
| R32 | 12 | David FerrerClay | 43 | Andy MurrayClay | 4-6(5) 7-6(0) 6-1 | 3 | 145 | 21 | 4 | 56.1% | 68.8% | 48.0% | 9/12 |
| R32 | 67 | Stan WawrinkaClay | 126 | Teymuraz GabashviliClay | 6-4 6-7(4) 6-4 | 3 | 123 | 8 | 3 | 54.5% | 72.9% | 65.0% | 0/3 |
| R32 | 159 | Evgeny KorolevClay | 87 | Fernando VicenteClay | 6-3 6-0 | 3 | 62 | 5 | 3 | 65.8% | 70.8% | 48.0% | 7/7 |
| R32 | 56 | Ivo KarlovicClay | 6 | Nikolay DavydenkoClay | 6-7(7) 7-5 6-4 | 3 | 165 | 19 | 0 | 64.9% | 81.1% | 55.0% | 6/6 |
| R16 | 2 | Rafael NadalClay | 164 | Ivan NavarroClay | 6-4 6-2 | 3 | 89 | 0 | 1 | 68.4% | 74.4% | 61.1% | 1/1 |
| R16 | 20 | Jarkko NieminenClay | 112 | Albert PortasClay | 6-3 6-2 | 3 | 82 | 4 | 0 | 62.3% | 72.7% | 40.0% | 7/9 |
| R16 | 57 | Nicolas AlmagroClay | 9 | Guillermo CoriaClay | 6-2 6-0 | 3 | 51 | 3 | 0 | 69.8% | 76.7% | 69.2% | 2/2 |
| R16 | 28 | Juan Carlos FerreroClay | 249 | Albert CostaClay | 6-1 5-7 7-5 | 3 | 127 | 4 | 0 | 78.5% | 74.0% | 50.0% | 4/6 |
| R16 | 15 | Tommy RobredoClay | 32 | Fernando VerdascoClay | 6-3 2-6 6-2 | 3 | 129 | 2 | 2 | 71.8% | 62.0% | 41.9% | 12/15 |
| R16 | 16 | Radek StepanekClay | 36 | Paul-Henri MathieuClay | 1-6 6-3 6-2 | 3 | 107 | 8 | 2 | 71.1% | 70.4% | 45.5% | 4/6 |
| R16 | 67 | Stan WawrinkaClay | 12 | David FerrerClay | 2-6 6-2 6-1 | 3 | 101 | 4 | 1 | 55.1% | 58.1% | 45.7% | 9/13 |
| R16 | 56 | Ivo KarlovicClay | 159 | Evgeny KorolevClay | 6-7(4) 7-6(4) 7-6(5) | 3 | 166 | 24 | 4 | 63.8% | 84.3% | 51.1% | 8/8 |
| QF | 2 | Rafael NadalClay | 20 | Jarkko NieminenClay | 4-6 6-4 6-3 | 3 | 138 | 1 | 1 | 69.9% | 67.2% | 48.0% | 5/9 |
| QF | 57 | Nicolas AlmagroClay | 28 | Juan Carlos FerreroClay | 6-3 6-3 | 3 | 86 | 5 | 3 | 57.3% | 72.1% | 46.9% | 10/11 |
| QF | 15 | Tommy RobredoClay | 16 | Radek StepanekClay | 6-3 6-2 | 3 | 72 | 1 | 0 | 84.8% | 67.9% | 70.0% | 7/7 |
| QF | 67 | Stan WawrinkaClay | 56 | Ivo KarlovicClay | 4-6 6-3 6-4 | 3 | 120 | 7 | 1 | 60.6% | 75.4% | 54.1% | 4/5 |
| SF | 2 | Rafael NadalClay | 57 | Nicolas AlmagroClay | 7-6(2) 6-3 | 3 | 100 | 5 | 1 | 70.6% | 79.2% | 50.0% | 1/2 |
| SF | 15 | Tommy RobredoClay | 67 | Stan WawrinkaClay | 6-4 6-4 | 3 | 94 | 2 | 0 | 77.0% | 66.0% | 50.0% | 3/6 |
| F | 2 | Rafael NadalClay | 15 | Tommy RobredoClay | 6-4 6-4 6-0 | 5 | 139 | 2 | 4 | 71.8% | 72.1% | 62.5% | 3/3 |