| R64 | 69 | Jose AcasusoClay | 168 | Fernando VicenteClay | 7-5 6-4 | 3 | 95 | 5 | 1 | 63.5% | 70.2% | 59.3% | 4/5 |
| R32 | 58 | Juan Carlos FerreroClay | 27 | Feliciano LopezClay | 6-4 6-4 | 3 | 81 | 2 | 2 | 76.9% | 72.0% | 66.7% | 5/5 |
| R32 | 20 | David FerrerClay | 79 | Jan HernychClay | 6-2 6-3 | 3 | 81 | 2 | 2 | 76.9% | 72.0% | 66.7% | 5/5 |
| R32 | 8 | Gaston GaudioClay | 75 | Felix MantillaClay | 6-4 6-2 | 3 | 99 | 1 | 1 | 48.3% | 75.0% | 70.0% | 8/9 |
| R16 | 113 | Stan WawrinkaClay | 69 | Jose AcasusoClay | 6-3 6-4 | 3 | 69 | 6 | 0 | 58.2% | 78.1% | 73.9% | 0/0 |
| R16 | 22 | Radek StepanekClay | 13 | Guillermo CanasClay | 6-7(6) 7-6(2) 7-6(5) | 3 | 190 | 11 | 4 | 63.9% | 71.8% | 47.9% | 6/9 |
| R16 | 99 | Agustin CalleriClay | 5 | Guillermo CoriaClay | 6-4 6-7(5) 7-6(2) | 3 | 166 | 4 | 3 | 54.2% | 73.8% | 36.4% | 10/16 |
| R16 | 11 | Rafael NadalClay | 25 | Dominik HrbatyClay | 6-1 6-2 | 3 | 79 | 2 | 0 | 75.5% | 70.0% | 53.8% | 5/6 |
| R16 | 16 | Nikolay DavydenkoClay | 17 | Thomas JohanssonClay | 6-3 6-7(3) 7-6(2) | 3 | 162 | 1 | 1 | 75.0% | 66.7% | 61.5% | 4/6 |
| R16 | 44 | Max MirnyiClay | 7 | Carlos MoyaClay | 6-4 6-4 | 3 | 85 | 7 | 2 | 64.6% | 76.2% | 34.8% | 2/4 |
| R16 | 58 | Juan Carlos FerreroClay | 55 | Alberto MartinClay | 6-1 6-2 | 3 | 71 | 1 | 0 | 70.2% | 67.5% | 47.1% | 6/7 |
| R16 | 8 | Gaston GaudioClay | 20 | David FerrerClay | 6-3 6-4 | 3 | 98 | 1 | 3 | 55.7% | 61.5% | 45.2% | 6/9 |
| QF | 22 | Radek StepanekClay | 113 | Stan WawrinkaClay | 3-6 6-3 6-2 | 3 | 123 | 5 | 4 | 67.1% | 75.5% | 46.2% | 4/6 |
| QF | 11 | Rafael NadalClay | 99 | Agustin CalleriClay | 6-2 3-0 RET | 3 | 53 | 1 | 0 | 71.0% | 77.3% | 66.7% | 0/0 |
| QF | 16 | Nikolay DavydenkoClay | 44 | Max MirnyiClay | 6-4 6-4 | 3 | 81 | 0 | 1 | 78.3% | 72.3% | 76.9% | 2/2 |
| QF | 58 | Juan Carlos FerreroClay | 8 | Gaston GaudioClay | 6-4 4-6 6-3 | 3 | 178 | 3 | 2 | 66.7% | 61.3% | 57.5% | 15/18 |
| SF | 11 | Rafael NadalClay | 22 | Radek StepanekClay | 7-5 6-2 | 3 | 80 | 1 | 0 | 72.3% | 91.2% | 69.2% | 0/0 |
| SF | 58 | Juan Carlos FerreroClay | 16 | Nikolay DavydenkoClay | 7-6(1) 6-1 | 3 | 95 | 1 | 6 | 58.0% | 77.5% | 55.2% | 3/4 |
| F | 11 | Rafael NadalClay | 58 | Juan Carlos FerreroClay | 6-1 7-6(4) 6-3 | 5 | 176 | 6 | 1 | 76.1% | 69.8% | 55.6% | 8/9 |
| R64 | 113 | Stan WawrinkaClay | 81 | Guillermo Garcia-LopezClay | 6-3 6-1 | 3 | 59 | 5 | 2 | 52.4% | 90.9% | 65.0% | 0/0 |
| R64 | 39 | Paradorn SrichaphanClay | 57 | Kenneth CarlsenClay | 6-2 6-1 | 3 | 68 | 0 | 1 | 60.0% | 74.1% | 61.1% | 1/2 |
| R64 | 22 | Radek StepanekClay | 167 | Irakli LabadzeClay | 4-6 6-2 7-5 | 3 | 137 | 9 | 5 | 59.1% | 72.7% | 47.4% | 2/5 |
| R64 | 72 | Santiago VenturaClay | 257 | Galo BlancoClay | 6-3 6-3 | 3 | 72 | 3 | 1 | 59.7% | 80.0% | 40.7% | 7/8 |
| R64 | 74 | Wayne ArthursClay | 134 | Ruben Ramirez HidalgoClay | 6-4 6-3 | 3 | 71 | 11 | 4 | 54.9% | 82.1% | 60.9% | 0/0 |
| R64 | 80 | Peter WesselsClay | 50 | Cyril SaulnierClay | 6-3 6-3 | 3 | 58 | 6 | 1 | 74.4% | 87.5% | 72.7% | 0/0 |
| R64 | 99 | Agustin CalleriClay | 107 | Gael MonfilsClay | 7-6(2) 7-6(2) | 3 | 127 | 0 | 5 | 57.3% | 70.2% | 54.3% | 2/5 |
| R64 | 37 | Juan Ignacio ChelaClay | 180 | Albert PortasClay | 6-4 7-6(2) | 3 | 102 | 3 | 3 | 68.7% | 73.9% | 61.9% | 3/4 |
| R64 | 25 | Dominik HrbatyClay | 89 | Jerome HaehnelClay | 6-1 6-1 | 3 | 52 | 10 | 2 | 62.5% | 71.4% | 52.4% | 7/7 |
| R64 | 63 | Potito StaraceClay | 237 | Teymuraz GabashviliClay | 6-1 6-1 | 3 | 57 | 3 | 0 | 75.6% | 71.0% | 80.0% | 1/1 |
| R64 | 64 | Gilles MullerClay | 183 | Marc LopezClay | 6-4 7-6(2) | 3 | 100 | 7 | 6 | 58.1% | 82.0% | 47.2% | 7/8 |
| R64 | 333 | Francisco FoguesClay | 67 | Christophe RochusClay | 7-6(10) 1-6 6-3 | 3 | 122 | 4 | 2 | 71.7% | 68.2% | 42.3% | 3/8 |
| R64 | 36 | Xavier MalisseClay | 68 | Philipp KohlschreiberClay | 6-1 6-2 | 3 | 63 | 7 | 0 | 50.0% | 75.9% | 62.1% | 1/1 |
| R64 | 17 | Thomas JohanssonClay | 78 | Stefan KoubekClay | 6-2 6-1 | 3 | 63 | 1 | 2 | 59.0% | 82.6% | 62.5% | 1/1 |
| R64 | 71 | Juan MonacoClay | 35 | Igor AndreevClay | 6-3 2-6 6-3 | 3 | 106 | 1 | 4 | 77.8% | 74.6% | 44.4% | 4/6 |
| R64 | 44 | Max MirnyiClay | 53 | Albert CostaClay | 7-6(4) 3-6 7-6(2) | 3 | 144 | 12 | 6 | 58.4% | 81.4% | 40.5% | 4/8 |
| R64 | 121 | Jarkko NieminenClay | 60 | Hyung-Taik LeeClay | 6-4 7-6(4) | 3 | 104 | 1 | 2 | 64.9% | 66.0% | 55.6% | 2/3 |
| R64 | 55 | Alberto MartinClay | 582 | MARYounes El AynaouiClay | 6-4 6-3 | 3 | 82 | 3 | 1 | 73.4% | 63.8% | 76.5% | 7/7 |
| R64 | 58 | Juan Carlos FerreroClay | 77 | Albert MontanesClay | 6-3 3-6 7-5 | 3 | 162 | 2 | 8 | 62.7% | 78.3% | 36.6% | 8/11 |
| R64 | 27 | Feliciano LopezClay | 102 | Nicolas AlmagroClay | 6-4 6-2 | 3 | 70 | 6 | 4 | 65.5% | 83.3% | 47.4% | 2/2 |
| R64 | 20 | David FerrerClay | 59 | Fernando VerdascoClay | 6-3 6-4 | 3 | 76 | 4 | 3 | 68.6% | 60.4% | 50.0% | 1/4 |
| R64 | 79 | Jan HernychClay | 397 | Andy MurrayClay | 3-6 6-4 6-4 | 3 | 123 | 1 | 2 | 66.3% | 64.2% | 47.1% | 10/14 |
| R64 | 75 | Felix MantillaClay | 52 | Michael LlodraClay | 6-2 6-1 | 3 | 47 | 1 | 4 | 65.9% | 88.9% | 42.9% | 2/3 |
| R32 | 69 | Jose AcasusoClay | 3 | Marat SafinClay | 6-4 6-4 | 3 | 94 | 2 | 1 | 60.3% | 82.9% | 48.1% | 4/4 |
| R32 | 113 | Stan WawrinkaClay | 39 | Paradorn SrichaphanClay | 1-6 6-3 7-6(3) | 3 | 112 | 2 | 1 | 57.3% | 62.8% | 68.8% | 0/4 |
| R32 | 22 | Radek StepanekClay | 72 | Santiago VenturaClay | 6-3 6-2 | 3 | 66 | 6 | 1 | 73.6% | 82.1% | 57.1% | 1/1 |
| R32 | 13 | Guillermo CanasClay | 74 | Wayne ArthursClay | 7-5 7-6(3) | 3 | 114 | 5 | 2 | 49.4% | 69.0% | 62.8% | 3/4 |
| R32 | 5 | Guillermo CoriaClay | 80 | Peter WesselsClay | 6-2 6-7(4) 6-4 | 3 | 127 | 6 | 5 | 63.9% | 69.4% | 62.9% | 7/9 |
| R32 | 99 | Agustin CalleriClay | 37 | Juan Ignacio ChelaClay | 6-3 6-7(9) 7-6(1) | 3 | 149 | 5 | 3 | 60.0% | 83.3% | 50.0% | 3/5 |
| R32 | 25 | Dominik HrbatyClay | 63 | Potito StaraceClay | 6-3 6-2 | 3 | 59 | 7 | 3 | 61.2% | 93.3% | 52.6% | 1/1 |
| R32 | 11 | Rafael NadalClay | 64 | Gilles MullerClay | 6-0 6-2 | 3 | 54 | 2 | 2 | 64.4% | 82.8% | 56.3% | 4/4 |
| R32 | 16 | Nikolay DavydenkoClay | 333 | Francisco FoguesClay | 6-3 6-2 | 3 | 95 | 1 | 2 | 72.5% | 64.9% | 42.9% | 2/4 |
| R32 | 17 | Thomas JohanssonClay | 36 | Xavier MalisseClay | 7-5 7-5 | 3 | 108 | 5 | 1 | 52.1% | 83.8% | 58.8% | 1/2 |
| R32 | 44 | Max MirnyiClay | 71 | Juan MonacoClay | 7-6(3) 6-2 | 3 | 82 | 4 | 4 | 65.0% | 79.5% | 57.1% | 0/0 |
| R32 | 7 | Carlos MoyaClay | 121 | Jarkko NieminenClay | 7-5 5-7 6-2 | 3 | 142 | 7 | 2 | 60.4% | 74.1% | 50.0% | 3/6 |
| R32 | 55 | Alberto MartinClay | 15 | Tommy RobredoClay | 6-1 6-4 | 3 | 75 | 2 | 2 | 50.0% | 67.7% | 54.8% | 4/5 |