| QF | 33 |  Jordi ArreseClay | 159 |  Martin JaiteClay | 6-3 6-2 | 3 | 78 | 3 | 0 | 65.9% | 85.2% | 64.3% | 0/0 |
| R32 | 16 | Sergi BrugueraClay | 1121 |  Tasos BavelasClay | 6-2 6-1 | 3 | 53 | 2 | 1 | 50.0% | 84.2% | 63.2% | 0/0 |
| R32 | 136 | Horacio de la PenaClay | 264 |  Dinu PescariuClay | 6-2 6-3 | 3 | 78 | 3 | 1 | 60.9% | 71.4% | 61.1% | 1/2 |
| R32 | 73 |  Markus NaewieClay | 109 |  Martin StrelbaClay | 6-4 6-4 | 3 | 100 | 0 | 0 | 63.6% | 77.1% | 75.0% | 1/1 |
| R32 | 55 |  Magnus GustafssonClay | 116 | Lars JonssonClay | 2-6 7-6(3) 6-1 | 3 | 120 | 11 | 5 | 63.2% | 75.0% | 48.6% | 7/9 |
| R32 | 34 | Javier SanchezClay | 267 |  Thomas BuchmayerClay | 6-4 7-5 | 3 | 91 | 4 | 1 | 67.2% | 78.0% | 50.0% | 3/5 |
| R32 | 133 |  Frederic FontangClay | 147 | Jordi BurilloClay | 7-5 6-3 | 3 | 88 | 5 | 1 | 75.7% | 69.8% | 47.1% | 3/5 |
| R32 | 94 | Marcos Aurelio GorrizClay | - | Andreas FikasClay | 6-3 6-0 | 3 | 70 | 0 | 1 | 72.9% | 77.1% | 61.5% | 1/1 |
| R32 | 367 |  Milen VelevClay | 41 | Guillermo Perez-RoldanClay | 6-4 6-3 | 3 | 90 | 1 | 1 | 76.4% | 64.3% | 46.2% | 2/6 |
| R32 | 87 | Thierry ChampionClay | 45 | Gabriel MarkusClay | 6-4 6-2 | 3 | 74 | 2 | 3 | 79.3% | 67.4% | 41.7% | 3/5 |
| R32 | 159 | Martin JaiteClay | 135 | David PrinosilClay | 6-4 6-3 | 3 | 88 | 6 | 0 | 55.4% | 80.6% | 34.5% | 2/4 |
| R32 | 91 | Horst SkoffClay | 156 |  Mark KoevermansClay | 7-5 6-3 | 3 | 97 | 4 | 0 | 58.6% | 79.4% | 62.5% | 3/4 |
| R32 | 33 | Jordi ArreseClay | 128 | Jose Francisco AlturClay | 7-6(4) 6-2 | 3 | 83 | 0 | 1 | 68.3% | 68.3% | 68.4% | 1/2 |
| R32 | 113 | Marc-Kevin GoellnerClay | 58 |  Marcelo FilippiniClay | 6-3 4-6 6-4 | 3 | 122 | 4 | 3 | 58.6% | 82.4% | 44.4% | 3/5 |
| R32 | 47 |  Renzo FurlanClay | 112 | Lars KoslowskiClay | 6-2 6-1 | 3 | 81 | 7 | 1 | 68.9% | 73.8% | 42.1% | 2/3 |
| R32 | 61 | Tomas CarbonellClay | 60 | Francisco RoigClay | 6-4 7-5 | 3 | 104 | 2 | 1 | 69.6% | 70.9% | 41.7% | 9/11 |
| R32 | 22 | Francisco ClavetClay | 628 | Talito CorralesClay | 6-1 6-2 | 3 | 85 | 2 | 3 | 55.4% | 66.7% | 51.7% | 5/6 |
| R16 | 16 | Sergi BrugueraClay | 136 | Horacio de la PenaClay | 6-3 6-1 | 3 | 82 | 2 | 1 | 46.4% | 76.9% | 50.0% | 7/8 |
| R16 | 55 | Magnus GustafssonClay | 73 | Markus NaewieClay | 6-4 6-3 | 3 | 80 | 2 | 3 | 57.4% | 68.6% | 46.2% | 2/5 |
| R16 | 34 | Javier SanchezClay | 133 | Frederic FontangClay | 6-1 3-6 6-2 | 3 | 106 | 1 | 1 | 60.0% | 64.7% | 50.0% | 6/9 |
| R16 | 367 | Milen VelevClay | 94 | Marcos Aurelio GorrizClay | 6-4 6-2 | 3 | 87 | 0 | 0 | 70.8% | 76.5% | 35.7% | 2/4 |
| R16 | 159 | Martin JaiteClay | 87 | Thierry ChampionClay | 6-3 1-1 RET | 3 | 58 | 4 | 1 | 50.0% | 77.8% | 44.4% | 2/3 |
| R16 | 33 | Jordi ArreseClay | 91 | Horst SkoffClay | 6-2 6-4 | 3 | 103 | 3 | 1 | 64.9% | 60.4% | 50.0% | 6/9 |
| R16 | 113 | Marc-Kevin GoellnerClay | 47 | Renzo FurlanClay | 6-3 7-6(4) | 3 | 100 | 13 | 2 | 61.0% | 82.0% | 43.8% | 5/6 |
| R16 | 22 | Francisco ClavetClay | 61 | Tomas CarbonellClay | 6-4 7-6(5) | 3 | 113 | 2 | 3 | 67.1% | 66.0% | 57.7% | 4/6 |
| QF | 16 | Sergi BrugueraClay | 55 | Magnus GustafssonClay | 6-2 RET | 3 | 30 | 1 | 1 | 61.8% | 66.7% | 53.8% | 1/1 |
| QF | 34 | Javier SanchezClay | 367 | Milen VelevClay | 2-6 6-3 6-2 | 3 | 118 | 5 | 1 | 64.1% | 55.9% | 57.6% | 5/9 |
| QF | 22 | Francisco ClavetClay | 113 | Marc-Kevin GoellnerClay | 6-2 6-2 | 3 | 70 | 2 | 2 | 73.6% | 71.8% | 42.9% | 2/3 |
| SF | 16 | Sergi BrugueraClay | 34 | Javier SanchezClay | 7-5 6-7(1) 6-4 | 3 | 158 | 6 | 2 | 54.4% | 73.2% | 66.0% | 7/8 |
| SF | 33 | Jordi ArreseClay | 22 | Francisco ClavetClay | 7-5 6-2 | 3 | 125 | 1 | 2 | 65.4% | 67.9% | 60.7% | 4/4 |
| F | 33 | Jordi ArreseClay | 16 | Sergi BrugueraClay | 7-5 3-0 RET | 3 | 61 | 0 | 1 | 63.3% | 58.1% | 55.6% | 3/5 |
