| R32 | 240 |  Thiemo de BakkerClay | 149 |  Adrian CruciatClay | 7-5 6-4 | 3 | 84 | 10 | 1 | 51.5% | 70.6% | 68.8% | 4/5 |
| R32 | 102 |  Teymuraz GabashviliClay | 131 |  Thierry AscioneClay | 6-2 7-6(1) | 3 | 87 | 7 | 1 | 64.5% | 75.0% | 63.6% | 1/2 |
| R32 | 92 |  Martin Vassallo ArguelloClay | 273 |  Alberto BrizziClay | 6-4 6-3 | 3 | 97 | 3 | 2 | 66.2% | 70.6% | 46.2% | 12/13 |
| R32 | 122 |  Alberto MartinClay | 150 |  Yuri SchukinClay | 7-6(8) 6-4 | 3 | 103 | 7 | 6 | 57.7% | 80.5% | 40.0% | 1/4 |
| R32 | 115 |  Christophe RochusClay | 203 | David MarreroClay | 7-5 6-2 | 3 | 87 | 5 | 2 | 57.4% | 71.8% | 55.2% | 6/8 |
| R32 | 118 |  Philipp PetzschnerClay | 76 | Florent SerraClay | 2-6 6-4 6-4 | 3 | 96 | 6 | 3 | 59.8% | 75.5% | 48.5% | 5/8 |
| R32 | 146 | Jesse Huta GalungClay | 100 | Santiago VenturaClay | 6-1 1-0 RET | 3 | 36 | 2 | 1 | 53.1% | 82.4% | 53.3% | 0/0 |
| R32 | 107 | Oscar HernandezClay | 364 |  Denis MatsukevichClay | 6-1 6-3 | 3 | 73 | 2 | 0 | 78.0% | 65.6% | 77.8% | 0/1 |
| R32 | 99 | Ivan NavarroClay | 384 | Igor SijslingClay | 6-3 6-1 | 3 | 59 | 6 | 2 | 65.9% | 88.9% | 57.1% | 0/0 |
| R32 | 63 | Albert MontanesClay | 124 | Kristof VliegenClay | 6-4 6-2 | 3 | 57 | 7 | 4 | 65.5% | 75.0% | 36.8% | 6/9 |
| R32 | 134 |  Pablo CuevasClay | 218 |  Werner EschauerClay | 7-5 6-2 | 3 | 91 | 3 | 0 | 60.9% | 71.4% | 63.0% | 4/5 |
| R32 | 190 | Edouard Roger-VasselinClay | 270 | Martin VerkerkClay | 2-6 7-6(9) 4-3 RET | 3 | 124 | 7 | 5 | 62.6% | 73.7% | 47.1% | 7/10 |
| R16 | 52 | Marc GicquelClay | 240 | Thiemo de BakkerClay | 7-6(6) 6-3 | 3 | 101 | 3 | 3 | 62.9% | 79.5% | 60.9% | 3/4 |
| R16 | 102 | Teymuraz GabashviliClay | 92 | Martin Vassallo ArguelloClay | 6-4 6-0 | 3 | 79 | 4 | 4 | 60.4% | 78.1% | 57.1% | 3/3 |
| R16 | 56 | Steve DarcisClay | 122 | Alberto MartinClay | 6-1 7-6(5) | 3 | 87 | 3 | 4 | 58.7% | 68.2% | 48.4% | 5/7 |
| R16 | 115 | Christophe RochusClay | 118 | Philipp PetzschnerClay | 6-3 6-4 | 3 | 65 | 1 | 0 | 72.7% | 82.5% | 46.7% | 1/2 |
| R16 | 107 | Oscar HernandezClay | 146 | Jesse Huta GalungClay | 6-3 6-2 | 3 | 82 | 2 | 1 | 66.7% | 77.5% | 50.0% | 1/1 |
| R16 | 57 | Marcel GranollersClay | 99 | Ivan NavarroClay | 6-4 6-4 | 3 | 98 | 1 | 1 | 63.6% | 73.8% | 54.2% | 8/9 |
| R16 | 63 | Albert MontanesClay | 134 | Pablo CuevasClay | 6-4 6-4 | 3 | 94 | 2 | 3 | 61.8% | 76.6% | 51.7% | 5/5 |
| R16 | 54 | Jose AcasusoClay | 190 | Edouard Roger-VasselinClay | 6-3 6-4 | 3 | 86 | 5 | 0 | 55.2% | 81.3% | 57.7% | 1/2 |
| QF | 52 | Marc GicquelClay | 102 | Teymuraz GabashviliClay | 6-4 6-1 | 3 | 63 | 5 | 1 | 56.8% | 88.0% | 47.4% | 0/1 |
| QF | 56 | Steve DarcisClay | 115 | Christophe RochusClay | 7-5 6-3 | 3 | 68 | 8 | 2 | 55.4% | 83.9% | 60.0% | 1/2 |
| QF | 107 | Oscar HernandezClay | 57 | Marcel GranollersClay | 7-5 6-2 | 3 | 101 | 2 | 2 | 71.4% | 64.4% | 61.1% | 2/4 |
| QF | 63 | Albert MontanesClay | 54 | Jose AcasusoClay | 6-0 6-2 | 3 | 49 | 1 | 0 | 63.2% | 83.3% | 71.4% | 1/1 |
| SF | 56 | Steve DarcisClay | 52 | Marc GicquelClay | 7-6(3) 3-6 7-5 | 3 | 130 | 4 | 4 | 56.2% | 78.0% | 54.3% | 7/9 |
| SF | 63 | Albert MontanesClay | 107 | Oscar HernandezClay | 6-1 6-3 | 3 | 78 | 2 | 0 | 54.9% | 75.0% | 60.9% | 5/5 |
| F | 63 | Albert MontanesClay | 56 | Steve DarcisClay | 1-6 7-5 6-3 | 3 | 107 | 3 | 4 | 66.3% | 75.5% | 48.1% | 1/4 |
