| R32 | 81 |  Florent SerraClay | 5 |  Nikolay DavydenkoClay | 4-6 6-1 6-1 | 3 | 99 | 2 | 3 | 61.4% | 64.7% | 56.3% | 9/11 |
| R32 | 396 |  Thiemo de BakkerClay | 53 |  Nicolas MassuClay | 7-6(7) 7-6(5) | 3 | 145 | 5 | 0 | 67.4% | 65.6% | 67.7% | 4/5 |
| R32 | 130 | Robin HaaseClay | 435 |  Felix MantillaClay | 6-3 6-2 | 3 | 60 | 11 | 0 | 64.0% | 87.5% | 55.6% | 0/0 |
| R32 | 102 | Nicolas DevilderClay | 30 |  Agustin CalleriClay | 6-3 6-1 | 3 | 46 | 5 | 1 | 65.1% | 92.9% | 46.7% | 0/0 |
| R32 | 20 | Carlos MoyaClay | 174 |  Christophe RochusClay | 6-2 6-3 | 3 | 67 | 9 | 0 | 56.5% | 92.3% | 50.0% | 0/0 |
| R32 | 79 | Mariano ZabaletaClay | 72 | Kristof VliegenClay | 6-3 6-3 | 3 | 93 | 5 | 4 | 55.4% | 74.2% | 44.0% | 6/8 |
| R32 | 150 | Raemon SluiterClay | 75 |  Luis HornaClay | 3-6 7-5 6-3 | 3 | 119 | 10 | 1 | 47.1% | 82.5% | 60.0% | 4/6 |
| R32 | 66 |  Werner EschauerClay | 34 | Nicolas AlmagroClay | 7-6(1) 6-4 | 3 | 101 | 2 | 1 | 68.9% | 78.4% | 56.5% | 4/5 |
| R32 | 297 | Steve DarcisClay | 39 | Marc GicquelClay | 6-3 6-4 | 3 | 67 | 3 | 1 | 48.1% | 61.5% | 53.6% | 1/4 |
| R32 | 51 | Gilles SimonClay | 93 | Ruben Ramirez HidalgoClay | 6-2 6-4 | 3 | 67 | 5 | 0 | 67.4% | 86.2% | 64.3% | 0/1 |
| R32 | 54 | Igor AndreevClay | 47 |  Janko TipsarevicClay | 6-1 6-1 | 3 | 37 | 7 | 3 | 61.8% | 90.5% | 69.2% | 0/0 |
| R32 | 26 |  Filippo VolandriClay | 52 | Oscar HernandezClay | 6-2 6-4 | 3 | 59 | 2 | 0 | 83.0% | 71.8% | 50.0% | 0/2 |
| R32 | 89 |  Evgeny KorolevClay | 31 |  Dominik HrbatyClay | 6-3 6-7(3) 6-3 | 3 | 117 | 12 | 1 | 60.8% | 80.6% | 57.5% | 3/3 |
| R32 | 76 | Sergio RoitmanClay | 256 | Jeremy ChardyClay | 7-6(5) 6-1 | 3 | 97 | 5 | 0 | 75.4% | 71.7% | 53.3% | 4/5 |
| R32 | 272 |  Victor HanescuClay | 55 | Albert MontanesClay | 7-6(3) 4-6 7-6(4) | 3 | 133 | 15 | 1 | 73.5% | 78.3% | 50.0% | 5/7 |
| R32 | 13 | Mikhail YouzhnyClay | 85 | Martin Vassallo ArguelloClay | 6-2 7-5 | 3 | 92 | 1 | 1 | 62.1% | 83.3% | 59.1% | 1/1 |
| R16 | 81 | Florent SerraClay | 396 | Thiemo de BakkerClay | 4-6 6-3 7-6(5) | 3 | 109 | 5 | 2 | 56.4% | 88.7% | 51.2% | 3/4 |
| R16 | 130 | Robin HaaseClay | 102 | Nicolas DevilderClay | 6-4 3-6 6-3 | 3 | 120 | 2 | 0 | 53.9% | 75.6% | 65.7% | 2/4 |
| R16 | 20 | Carlos MoyaClay | 79 | Mariano ZabaletaClay | 6-2 6-3 | 3 | 62 | 2 | 1 | 68.1% | 87.5% | 60.0% | 0/0 |
| R16 | 66 | Werner EschauerClay | 150 | Raemon SluiterClay | 6-2 6-4 | 3 | 70 | 6 | 0 | 65.1% | 82.1% | 86.7% | 0/0 |
| R16 | 297 | Steve DarcisClay | 51 | Gilles SimonClay | 7-6(4) 6-1 | 3 | 92 | 6 | 1 | 48.5% | 78.8% | 57.1% | 1/2 |
| R16 | 54 | Igor AndreevClay | 26 | Filippo VolandriClay | 3-6 6-1 6-4 | 3 | 86 | 10 | 0 | 71.6% | 69.8% | 76.2% | 3/4 |
| R16 | 89 | Evgeny KorolevClay | 76 | Sergio RoitmanClay | 7-5 7-6(6) | 3 | 149 | 5 | 2 | 57.0% | 75.6% | 52.9% | 1/3 |
| R16 | 13 | Mikhail YouzhnyClay | 272 | Victor HanescuClay | 6-4 6-2 | 3 | 149 | 5 | 2 | 57.0% | 75.6% | 52.9% | 1/3 |
| QF | 130 | Robin HaaseClay | 81 | Florent SerraClay | 4-6 7-5 6-4 | 3 | 125 | 5 | 2 | 57.6% | 64.9% | 59.5% | 4/7 |
| QF | 66 | Werner EschauerClay | 20 | Carlos MoyaClay | 6-7(4) 6-4 6-4 | 3 | 154 | 9 | 2 | 58.9% | 71.2% | 60.8% | 9/9 |
| QF | 297 | Steve DarcisClay | 54 | Igor AndreevClay | 6-3 6-4 | 3 | 74 | 1 | 0 | 56.1% | 75.0% | 56.0% | 1/3 |
| QF | 13 | Mikhail YouzhnyClay | 89 | Evgeny KorolevClay | 6-4 6-3 | 3 | 91 | 4 | 1 | 66.3% | 67.9% | 48.1% | 6/6 |
| SF | 66 | Werner EschauerClay | 130 | Robin HaaseClay | 6-4 6-4 | 3 | 76 | 4 | 1 | 50.0% | 73.1% | 73.1% | 1/2 |
| SF | 297 | Steve DarcisClay | 13 | Mikhail YouzhnyClay | 4-6 6-0 7-5 | 3 | 138 | 8 | 1 | 60.8% | 78.0% | 39.5% | 9/12 |
| F | 297 | Steve DarcisClay | 66 | Werner EschauerClay | 6-1 7-6(1) | 3 | 91 | 4 | 1 | 60.5% | 80.4% | 50.0% | 7/7 |
