| R32 | 28 |  Guillermo CoriaClay | 340 |  Robin HaaseClay | 6-3 4-6 6-4 | 3 | 137 | 1 | 14 | 59.6% | 81.4% | 30.0% | 7/12 |
| R32 | 118 | Sergio RoitmanClay | 211 |  Marin CilicClay | 6-3 6-1 | 3 | 68 | 4 | 0 | 75.6% | 76.5% | 54.5% | 5/6 |
| R32 | 51 | Agustin CalleriClay | 133 |  Denis GremelmayrClay | 6-2 7-6(5) | 3 | 93 | 4 | 4 | 52.5% | 71.4% | 60.5% | 7/8 |
| R32 | 55 |  Daniele BraccialiClay | 503 | Igor SijslingClay | 6-7(5) 6-4 6-2 | 3 | 138 | 20 | 4 | 60.7% | 76.9% | 50.0% | 10/11 |
| R32 | 36 |  Novak DjokovicClay | 73 | Boris PashanskiClay | 6-0 6-3 | 3 | 82 | 3 | 2 | 60.0% | 63.6% | 63.6% | 0/1 |
| R32 | 127 |  Tomas ZibClay | 266 |  Steve DarcisClay | 7-5 6-3 | 3 | 91 | 3 | 1 | 62.3% | 75.8% | 75.0% | 0/0 |
| R32 | 87 |  Marc GicquelClay | 101 |  Fernando VicenteClay | 6-2 6-4 | 3 | 70 | 2 | 2 | 53.7% | 75.9% | 64.0% | 1/1 |
| R32 | 1055 | Thiemo de BakkerClay | 53 | Julien BenneteauClay | 6-3 6-3 | 3 | 84 | 3 | 4 | 41.8% | 78.6% | 53.8% | 5/6 |
| R32 | 41 | Carlos MoyaClay | 80 | Guillermo Garcia-LopezClay | 6-4 7-6(6) | 3 | 114 | 7 | 0 | 57.7% | 82.2% | 60.6% | 1/1 |
| R32 | 274 | Fabio FogniniClay | 381 | Juan-Pablo GuzmanClay | 6-3 1-6 7-5 | 3 | 126 | 3 | 5 | 54.7% | 63.8% | 50.0% | 4/7 |
| R32 | 122 |  Juan Antonio MarinClay | 67 | Davide SanguinettiClay | 6-2 7-5 | 3 | 107 | 3 | 1 | 47.7% | 71.0% | 67.6% | 0/0 |
| R32 | 37 |  Nicolas MassuClay | 262 |  Andreas VinciguerraClay | 7-6(3) 6-3 | 3 | 106 | 6 | 7 | 47.1% | 75.0% | 50.0% | 1/4 |
| R32 | 49 | Alberto MartinClay | 95 | Albert MontanesClay | 6-2 6-2 | 3 | 69 | 8 | 3 | 51.1% | 79.2% | 60.9% | 2/3 |
| R32 | 450 | Edgardo MassaClay | 110 | Ivo MinarClay | 6-4 6-3 | 3 | 71 | 1 | 2 | 58.9% | 78.8% | 60.9% | 1/2 |
| R32 | 62 | Ruben Ramirez HidalgoClay | 108 | Carlos BerlocqClay | 6-7(4) 6-3 6-3 | 3 | 183 | 4 | 4 | 58.5% | 66.1% | 52.3% | 6/10 |
| R32 | 33 | Paul-Henri MathieuClay | 93 | Alessio Di MauroClay | 6-0 6-3 | 3 | 76 | 0 | 2 | 60.4% | 71.9% | 57.1% | 1/2 |
| R16 | 28 | Guillermo CoriaClay | 118 | Sergio RoitmanClay | 7-5 4-6 6-2 | 3 | 140 | 2 | 15 | 63.5% | 69.9% | 40.5% | 10/14 |
| R16 | 51 | Agustin CalleriClay | 55 | Daniele BraccialiClay | 2-6 7-6(2) 6-0 | 3 | 102 | 12 | 2 | 59.2% | 80.0% | 54.8% | 0/2 |
| R16 | 36 | Novak DjokovicClay | 127 | Tomas ZibClay | 6-4 6-2 | 3 | 86 | 13 | 4 | 67.2% | 80.5% | 55.0% | 4/4 |
| R16 | 87 | Marc GicquelClay | 1055 | Thiemo de BakkerClay | 4-6 6-3 6-2 | 3 | 127 | 9 | 3 | 47.0% | 89.7% | 50.0% | 2/3 |
| R16 | 41 | Carlos MoyaClay | 274 | Fabio FogniniClay | 7-5 6-3 | 3 | 96 | 9 | 3 | 52.5% | 74.2% | 42.9% | 0/4 |
| R16 | 37 | Nicolas MassuClay | 122 | Juan Antonio MarinClay | 6-4 7-6(2) | 3 | 146 | 0 | 6 | 53.4% | 71.8% | 35.3% | 7/11 |
| R16 | 49 | Alberto MartinClay | 450 | Edgardo MassaClay | 6-2 6-4 | 3 | 86 | 0 | 3 | 58.6% | 70.6% | 58.3% | 3/4 |
| R16 | 62 | Ruben Ramirez HidalgoClay | 33 | Paul-Henri MathieuClay | 6-4 6-2 | 3 | 80 | 3 | 1 | 57.7% | 73.3% | 45.5% | 1/3 |
| QF | 28 | Guillermo CoriaClay | 51 | Agustin CalleriClay | 6-3 7-6(4) | 3 | 95 | 1 | 5 | 59.5% | 74.5% | 53.1% | 1/2 |
| QF | 36 | Novak DjokovicClay | 87 | Marc GicquelClay | 6-3 6-4 | 3 | 75 | 5 | 3 | 60.7% | 81.1% | 41.7% | 2/3 |
| QF | 37 | Nicolas MassuClay | 41 | Carlos MoyaClay | 7-5 6-4 | 3 | 106 | 3 | 1 | 65.1% | 61.0% | 77.3% | 2/4 |
| QF | 62 | Ruben Ramirez HidalgoClay | 49 | Alberto MartinClay | 6-2 6-2 | 3 | 63 | 3 | 0 | 65.9% | 89.7% | 46.7% | 0/0 |
| SF | 36 | Novak DjokovicClay | 28 | Guillermo CoriaClay | 6-2 1-0 RET | 3 | 38 | 2 | 0 | 65.4% | 70.6% | 77.8% | 1/2 |
| SF | 37 | Nicolas MassuClay | 62 | Ruben Ramirez HidalgoClay | 6-1 6-3 | 3 | 79 | 6 | 0 | 54.8% | 91.3% | 57.9% | 0/0 |
| F | 36 | Novak DjokovicClay | 37 | Nicolas MassuClay | 7-6(5) 6-4 | 3 | 162 | 9 | 3 | 52.9% | 75.0% | 50.0% | 2/4 |
