| R32 | 10 |  Carlos MoyaClay | 404 |  Gregory CarrazClay | 6-4 6-4 | 3 | 67 | 3 | 0 | 69.6% | 82.1% | 52.9% | 3/4 |
| R32 | 117 | Fernando VicenteClay | 79 |  Paul HaarhuisClay | 6-3 7-6(3) | 3 | 92 | 1 | 3 | 65.8% | 66.0% | 46.2% | 5/8 |
| R32 | 101 | Emilio Benfele AlvarezClay | 55 | Galo BlancoClay | 6-3 3-6 4-0 RET | 3 | 95 | 6 | 8 | 52.5% | 81.3% | 44.8% | 5/8 |
| R32 | 42 | Francisco ClavetClay | 498 |  Libor NemecekClay | 6-3 7-5 | 3 | 86 | 0 | 3 | 60.9% | 64.1% | 36.0% | 4/8 |
| R32 | 29 |  Magnus NormanClay | 45 |  Dominik HrbatyClay | 5-7 6-1 6-0 | 3 | 105 | 7 | 1 | 47.3% | 67.4% | 58.3% | 6/8 |
| R32 | 60 | Magnus GustafssonClay | 85 | Sjeng SchalkenClay | 6-3 6-3 | 3 | 77 | 6 | 5 | 59.6% | 76.5% | 56.5% | 4/5 |
| R32 | 52 |  Christian RuudClay | 87 |  Renzo FurlanClay | 6-4 6-4 | 3 | 94 | 3 | 2 | 60.3% | 68.6% | 52.2% | 0/2 |
| R32 | 76 |  Hendrik DreekmannClay | 31 | Bohdan UlihrachClay | 4-6 6-4 6-3 | 3 | 113 | 5 | 5 | 55.8% | 69.0% | 50.0% | 5/8 |
| R32 | 40 | Javier SanchezClay | 503 | Tom KempersClay | 5-7 6-4 6-4 | 3 | 120 | 2 | 0 | 69.9% | 69.4% | 67.7% | 5/6 |
| R32 | 71 |  Hernan GumyClay | 120 | Alberto MartinClay | 7-5 6-3 | 3 | 94 | 1 | 1 | 63.6% | 66.7% | 58.3% | 1/3 |
| R32 | 49 |  Marcelo FilippiniClay | 43 | Marc-Kevin GoellnerClay | 7-5 1-6 6-4 | 3 | 116 | 4 | 4 | 67.6% | 59.2% | 61.8% | 7/11 |
| R32 | 53 | MARKarim AlamiClay | 26 | Alberto BerasateguiClay | 6-4 6-4 | 3 | 75 | 7 | 2 | 62.8% | 85.7% | 24.1% | 6/7 |
| R32 | 41 | MARHicham AraziClay | 82 |  Fernando MeligeniClay | 2-6 6-1 7-6(8) | 3 | 117 | 6 | 1 | 60.2% | 66.2% | 46.5% | 4/7 |
| R32 | 59 | Slava DosedelClay | 137 | Fernon WibierClay | 6-3 6-1 | 3 | 57 | 3 | 2 | 62.2% | 85.7% | 47.1% | 3/4 |
| R32 | 233 | John van LottumClay | 44 |  Filip DewulfClay | 7-5 6-1 | 3 | 71 | 6 | 1 | 49.3% | 76.5% | 60.0% | 3/3 |
| R32 | - | Dennis Van ScheppingenClay | 17 | Albert CostaClay | 6-3 6-4 | 3 | 69 | 9 | 6 | 57.6% | 84.2% | 46.4% | 3/4 |
| R16 | 10 | Carlos MoyaClay | 117 | Fernando VicenteClay | 6-4 6-3 | 3 | 78 | 0 | 1 | 59.4% | 63.2% | 38.5% | 4/8 |
| R16 | 42 | Francisco ClavetClay | 101 | Emilio Benfele AlvarezClay | 6-1 2-6 6-4 | 3 | 112 | 0 | 0 | 70.1% | 70.2% | 60.0% | 4/6 |
| R16 | 29 | Magnus NormanClay | 60 | Magnus GustafssonClay | 6-4 6-4 | 3 | 85 | 4 | 1 | 48.4% | 80.6% | 45.5% | 5/7 |
| R16 | 52 | Christian RuudClay | 76 | Hendrik DreekmannClay | 7-5 6-4 | 3 | 102 | 3 | 2 | 55.7% | 71.4% | 46.2% | 14/16 |
| R16 | 40 | Javier SanchezClay | 71 | Hernan GumyClay | 4-6 6-4 7-6(5) | 3 | 166 | 3 | 4 | 65.8% | 64.4% | 44.7% | 10/17 |
| R16 | 49 | Marcelo FilippiniClay | 53 | MARKarim AlamiClay | 6-3 3-6 6-0 | 3 | 99 | 0 | 2 | 76.2% | 64.1% | 55.0% | 5/7 |
| R16 | 59 | Slava DosedelClay | 41 | MARHicham AraziClay | 7-5 7-6(7) | 3 | 102 | 6 | 2 | 65.7% | 78.3% | 58.3% | 2/4 |
| R16 | 233 | John van LottumClay | - | Dennis Van ScheppingenClay | 6-0 7-6(5) | 3 | 69 | 7 | 0 | 48.1% | 88.0% | 59.3% | 2/3 |
| QF | 10 | Carlos MoyaClay | 42 | Francisco ClavetClay | 6-3 6-4 | 3 | 81 | 0 | 0 | 66.0% | 60.0% | 55.6% | 2/5 |
| QF | 29 | Magnus NormanClay | 52 | Christian RuudClay | 6-3 7-6(6) | 3 | 96 | 10 | 3 | 53.9% | 82.9% | 51.4% | 1/2 |
| QF | 49 | Marcelo FilippiniClay | 40 | Javier SanchezClay | 7-5(5) 6-1 | 3 | 84 | 2 | 2 | 62.3% | 78.9% | 56.5% | 2/3 |
| QF | 59 | Slava DosedelClay | 233 | John van LottumClay | 6-4 4-6 6-2 | 3 | 129 | 4 | 3 | 52.4% | 61.8% | 60.0% | 6/8 |
| SF | 10 | Carlos MoyaClay | 29 | Magnus NormanClay | 6-4 6-3 | 3 | 73 | 2 | 0 | 60.0% | 69.2% | 57.7% | 8/9 |
| SF | 59 | Slava DosedelClay | 49 | Marcelo FilippiniClay | 7-6(5) 6-2 | 3 | 91 | 2 | 2 | 57.4% | 71.8% | 44.8% | 2/4 |
| F | 59 | Slava DosedelClay | 10 | Carlos MoyaClay | 7-6(4) 7-6(5) 6-7(4) 6-2 | 5 | 203 | 3 | 0 | 60.6% | 63.9% | 58.7% | 3/8 |
