| R32 | 12 |  Marcelo RiosClay | 111 |  Sandor NoszalyClay | 7-5 6-2 | 3 | 79 | 8 | 2 | 46.0% | 91.3% | 70.4% | 0/0 |
| R32 | 75 |  Adrian VoineaClay | 117 |  Frederik FetterleinClay | 6-2 6-4 | 3 | 70 | 5 | 1 | 60.7% | 55.9% | 77.3% | 3/4 |
| R32 | 52 |  Slava DosedelClay | 438 |  Peter WesselsClay | 6-4 6-4 | 3 | 66 | 1 | 0 | 66.7% | 64.3% | 52.4% | 2/4 |
| R32 | 40 |  Carlos CostaClay | 94 | David RiklClay | 6-2 6-3 | 3 | 76 | 6 | 1 | 61.7% | 59.5% | 52.2% | 2/5 |
| R32 | 23 | Felix MantillaClay | 248 | John van LottumClay | 6-3 6-1 | 3 | 65 | 2 | 1 | 68.1% | 78.1% | 46.7% | 0/1 |
| R32 | 46 |  Gilbert SchallerClay | 56 | Javier SanchezClay | 6-4 6-4 | 3 | 100 | 1 | 2 | 73.0% | 73.9% | 41.2% | 4/5 |
| R32 | 58 | Jordi BurilloClay | 576 | Stephen NoteboomClay | 7-6(4) 4-6 6-3 | 3 | 118 | 4 | 2 | 82.9% | 66.7% | 38.1% | 10/13 |
| R32 | 30 | Francisco ClavetClay | 73 |  Christian RuudClay | 7-6(3) 6-3 | 3 | 90 | 2 | 2 | 60.3% | 68.3% | 51.9% | 6/9 |
| R32 | 29 | Carlos MoyaClay | 301 |  Grant DoyleClay | 6-2 6-2 | 3 | 76 | 1 | 2 | 66.7% | 88.5% | 30.8% | 1/3 |
| R32 | 76 |  Alexander VolkovClay | 100 | Galo BlancoClay | 2-6 6-2 6-4 | 3 | 88 | 14 | 6 | 51.9% | 73.2% | 55.3% | 3/5 |
| R32 | - | Dennis Van ScheppingenClay | 218 |  Ronald AgenorClay | 7-6(5) 6-1 | 3 | 72 | 4 | 2 | 50.0% | 88.9% | 59.3% | 0/1 |
| R32 | 19 | Alberto BerasateguiClay | 103 |  Marcelo FilippiniClay | 6-4 4-6 6-1 | 3 | 112 | 1 | 4 | 73.6% | 64.1% | 56.5% | 10/13 |
| R32 | 33 | Bohdan UlihrachClay | 51 | Sjeng SchalkenClay | 7-5 4-6 6-0 | 3 | 119 | 3 | 6 | 59.0% | 66.1% | 53.5% | 11/14 |
| R32 | 43 |  Hernan GumyClay | 70 | Roberto CarreteroClay | 6-2 6-3 | 3 | 55 | 0 | 2 | 61.4% | 88.9% | 52.9% | 1/2 |
| R32 | 68 | MARYounes El AynaouiClay | 45 |  Filip DewulfClay | 4-6 6-4 6-1 | 3 | 92 | 3 | 4 | 64.4% | 69.6% | 41.9% | 6/9 |
| R32 | 15 | Albert CostaClay | 321 | German PuentesClay | 6-4 6-2 | 3 | 65 | 3 | 0 | 78.0% | 82.1% | 54.5% | 0/0 |
| R16 | 75 | Adrian VoineaClay | 12 | Marcelo RiosClay | 6-0 7-5 | 3 | 60 | 7 | 0 | 63.6% | 82.1% | 43.8% | 0/2 |
| R16 | 52 | Slava DosedelClay | 40 | Carlos CostaClay | 6-2 7-5 | 3 | 65 | 2 | 1 | 73.4% | 68.1% | 52.9% | 3/5 |
| R16 | 23 | Felix MantillaClay | 46 | Gilbert SchallerClay | 6-4 6-2 | 3 | 77 | 2 | 3 | 41.2% | 57.1% | 56.7% | 2/5 |
| R16 | 30 | Francisco ClavetClay | 58 | Jordi BurilloClay | 6-4 2-1 RET | 3 | 49 | 6 | 2 | 61.1% | 72.7% | 57.1% | 0/1 |
| R16 | 29 | Carlos MoyaClay | 76 | Alexander VolkovClay | 6-0 6-2 | 3 | 53 | 2 | 1 | 70.8% | 70.6% | 57.1% | 4/4 |
| R16 | - | Dennis Van ScheppingenClay | 19 | Alberto BerasateguiClay | 6-7(1) 6-3 7-6(2) | 3 | 119 | 9 | 4 | 54.0% | 78.7% | 55.8% | 4/5 |
| R16 | 43 | Hernan GumyClay | 33 | Bohdan UlihrachClay | 6-1 6-2 | 3 | 65 | 4 | 1 | 62.5% | 74.3% | 42.9% | 2/3 |
| R16 | 68 | MARYounes El AynaouiClay | 15 | Albert CostaClay | 6-7(7) 7-6(5) 7-5 | 3 | 143 | 7 | 3 | 61.3% | 73.5% | 55.8% | 1/3 |
| QF | 75 | Adrian VoineaClay | 52 | Slava DosedelClay | 7-6(7) 7-5 | 3 | 136 | 1 | 4 | 68.5% | 56.6% | 51.4% | 10/14 |
| QF | 30 | Francisco ClavetClay | 23 | Felix MantillaClay | 6-4 6-3 | 3 | 81 | 2 | 2 | 55.6% | 73.3% | 54.2% | 3/5 |
| QF | - | Dennis Van ScheppingenClay | 29 | Carlos MoyaClay | 7-6(9) 6-2 | 3 | 85 | 2 | 0 | 49.4% | 70.0% | 61.0% | 1/1 |
| QF | 68 | MARYounes El AynaouiClay | 43 | Hernan GumyClay | 6-4 6-3 | 3 | 81 | 4 | 4 | 73.1% | 71.4% | 33.3% | 4/6 |
| SF | 30 | Francisco ClavetClay | 75 | Adrian VoineaClay | 6-3 6-4 | 3 | 85 | 1 | 0 | 63.6% | 59.5% | 45.8% | 9/12 |
| SF | 68 | MARYounes El AynaouiClay | - | Dennis Van ScheppingenClay | 6-3 6-7(5) 6-2 | 3 | 120 | 14 | 2 | 64.6% | 81.3% | 54.3% | 4/4 |
| F | 30 | Francisco ClavetClay | 68 | MARYounes El AynaouiClay | 7-5 6-1 6-1 | 5 | 126 | 2 | 1 | 69.6% | 65.6% | 53.6% | 6/9 |
